IP Library Granted Patent US 10,465,142
Granted Patent B2
US 10,465,142 · App. 15/534,072 · Granted Nov 5, 2019

Lubricating oil composition for internal combustion engines

Inventors: Mao Ueda (Aikou, JP); Kiyoshi Hanyuda (Aikou, JP); Kouichi Kubo (Aikou, JP)
Assignee: SHELL OIL COMPANY
C10M169/04C10M101/00C10M133/44C10M139/00C10M141/12C10M163/00C10M169/045C10M2203/003C10M2203/1006C10M2203/1025C10M2205/04C10M2205/173C10M2207/26C10M2207/262C10M2207/289C10M2209/084C10M2215/064C10M2215/28C10M2215/30C10M2219/046C10M2223/045C10M2227/06C10M2227/061C10M2227/062C10M2229/02C10N2220/022C10N2220/023C10N2230/04C10N2230/06C10N2230/08C10N2230/10C10N2230/12C10N2230/52C10N2230/74C10N2240/10
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Quick Facts
Patent No.
US 10,465,142
App. No.
15/534,072
Granted
Nov 5, 2019
Kind
B2
Abstract

A lubricating oil composition for internal combustion engines is disclosed. The composition exhibits a lower coefficient of friction and improved cleaning properties without causing a deterioration in thermal and oxidation stability.

Claims (12)

1. A lubricating oil composition for internal combustion engines, which comprises the following components:

(a) a lubricant base oil having a kinematic viscosity at 100° C. of from 2 to 12mm 2 /s, which is a single API group 2 or group 3 base oil having a viscosity index of 95 or higher, a sulfur content of 0.03 mass % or lower and % CA value of 1 or lower,

(b) a nitrogen-containing ashless dispersing agent at a quantity of 0.01-0.3 mass % in terms of nitrogen content relative to the overall composition, wherein a weight average molecular weight of the nitrogen-containing ashless dispersing agent ranges between 1,000 to 20,000,

(c) a metal-containing detergent, which contains calcium as an alkaline earth metal, at a quantity of 0.05-0.3 mass % in terms of alkaline earth metal content relative to the overall composition,

(d) a zinc dialkyldithiophosphate at a quantity of 0.05-0.13 mass % in terms of phosphorus content relative to the overall composition, and

(e) an oil-soluble semi-polar organic boron glycerol ester compound represented by chemical formula 1,

at a quantity of 0.015-0.040 mass % in terms of boron content relative to the overall composition, wherein R denotes a straight chain or branched chain alkyl group or straight chain or branched chain alkenyl group having 7-20 carbon atoms; and

wherein the lubricating oil composition comprises less than a ±10% change in kinematic viscosity at 40° C., a 1.5 mg KOH/g or less increase in total acid value, and a less than 100 ppm in an eluted copper (Cu) concentration.

2. A lubricating oil composition for internal combustion engines according to claim 1 , wherein the nitrogen-containing ashless dispersing agent contains an additive selected from among the group consisting of a boronated or non-boronated alkylsuccinimide or alkenylsuccinimide, a boronated or non-boronated alkylsuccinic acid ester or alkenylsuccinic acid ester, a boronated or non-boronated alkylsuccinic acid imide or alkenylsuccinic acid imide, a boronated or non-boronated alkylsuccinic acid amide or alkenylsuccinic acid amide, or an arbitrary combination thereof.

3. A lubricating oil composition for internal combustion engines according to claim 1 , wherein the metal-containing detergent contains a salicylate, a carboxylate or a sulfonate as a primary component.

4. A lubricating oil composition for internal combustion engines according to claim 1 , wherein the zinc dialkyldithiophosphate comprises a primary or secondary alkyl group having 3-8 carbon atoms.

5. A lubricating oil composition for internal combustion engines according to claim 1 , wherein the semi-polar organic boron glycerol ester compound is glycerol monooleyl glycerol borate, as represented by chemical formula 2

Assignments (2)
CHANGE OF NAME Recorded Mar 7, 2022
From: SHELL OIL COMPANY
To: SHELL USA, INC.
Reel/Frame 059694/0819 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 16, 2017
From: UEDA, MAO; HANYUDA, KIYOSHI; KUBO, KOUICHI
To: SHELL OIL COMPANY
Reel/Frame 043304/0115 →
Cited By (1)
US 12,662,646