Method of preparing condensation cross-linked particles

1. A method of preparing condensation cross-linked particles in an emulsion, said method comprising the steps of:

A. providing a first linear reactant having two unsaturated carbon-carbon moieties;

B. providing a second linear reactant having two Si—H moieties;

C. providing a third reactant having at least one condensable reactive group and having up to two unsaturated carbon-carbon moieties or Si—H moieties with the proviso that the third reactant has at least one unsaturated carbon-carbon moiety or Si—H moiety;

D. providing a hydrosilylation catalyst;

E. providing a polar liquid;

F. combining the first, second, and third reactants in the presence of the hydrosilylation catalyst and the polar liquid to form an emulsion wherein the first, second, and third reactants react via a hydrosilylation reaction to form particles in the emulsion that have a linear backbone wherein the condensable reactive group is disposed thereon, and wherein the particles are disposed in the polar liquid; and

G. cross-linking the linear backbone via a condensation reaction to form the condensation cross-linked particles.

2. The method of claim 1 wherein the step of cross-linking is further defined as adding a condensation catalyst to the first, second, and/or third reactants and/or the particles to cross-link the linear backbone of the particles via a condensation reaction of the condensable groups.

3. The method of claim 1 wherein the third reactant is an alkoxysilane having the Si—H moiety.

4. The method of claim 1 wherein the step of combining the first, second, and third reactants further comprises phase inverting the combination of the first, second, and third reactants to form the emulsion.

5. The method of claim 1 wherein the third reactant has the formula:

XR′SiR″ t (OR) 4-t

wherein each of R, R′, R″ is independently an organic radical having 1-12 carbon atoms, X is independently the unsaturated carbon-carbon moiety or the Si—H moiety, and t is 0-2.

6. The method of claim 1 wherein the third reactant is HSi(CH 3 ) 2 OSi(CH 3 ) 2 CH 2 CH 2 Si(OCH 3 ) 3 or H 2 C═CHSi(OCH 3 ) 3 .

7. The method of claim 1 wherein the condensable reactive group is an —Si(OR) group wherein R is an organic radical having 1-12 carbon atoms.

8. The method of claim 1 wherein the first linear reactant is free of silicon such that the linear backbone is further defined as a linear organic backbone.

9. The method of claim 1 wherein the first linear reactant is further defined as a siloxane such that the linear backbone is further defined as a linear silicone backbone.

10. The method of claim 1 wherein the first linear reactant is a polydimethylsiloxane having two terminal unsaturated carbon-carbon moieties, the second linear reactant is a polydimethylsiloxane having two terminal Si—H moieties, and the third reactant is HSi(CH 3 ) 2 OSi(CH 3 ) 2 CH 2 CH 2 Si(OCH 3 ) 3 or H 2 C═CHSi(OCH 3 ) 3 .

11. A cross-linked particle formed from the method of claim 1 .

12. A dispersion comprising:

a polar continuous phase; and

cross-linked particles as set forth in claim 1 .

13. A film comprising the cross-linked particles of claim 1 .

14. A method of forming the film of claim 13 comprising the steps of:

separating the polar liquid from the cross-linked particles; and

forming the film from the cross-linked particles.

15. An emulsion comprising cross-linked particles and a polar liquid formed from the method of claim 1 .

16. A method comprising separating from the emulsion of claim 15 the cross-linked particles from the polar liquid.

17. Cross-linked particles formed in accordance with the method of claim 16 .