Polypropylene films with improved sealing behaviour, especially in view of improved sealing properties
View Patent ↗The present invention relates to a polymer blend and the film of the polymer blend or the film layers of the polymer blend as a surface layer or coating. More particularly, the invention relates to a polymer blend which may be extruded as such or extruded onto one or both sides of packaging film to give a sealing surface(s) which exhibits surprisingly heat sealability suitable for form-fill-and-seal-packaging. The present invention also relates the use of ethylene based plastomer to reduce sealability of films comprising polypropylene.
1. A polypropylene-plastomer-blend comprising 80-93 wt. % of a polypropylene random copolymer and 7-20 wt. % of an ethylene-based plastomer, based on the sum of the amount of the polypropylene random copolymer and the ethylene-based plastomer, wherein
the polypropylene random copolymer comprises at least 1.5 wt % ethylene as a comonomer, and the polypropylene random copolymer does not comprise an elastomeric polymer phase dispersed therein,
the ethylene based plastomer has an MFR190/2.16 according to ISO 1133 of at least 2.5 g/10 min, and
the ethylene based plastomer is a copolymer of ethylene and 1-hexene with an ethylene content of from 50 to 95 wt % or the ethylene based plastomer is a copolymer of ethylene and 1-octene with an ethylene content of from 50 to 95 wt %.
2. The polypropylene-plastomer-blend according to claim 1 , wherein the ethylene based plastomer has a density ISO 1183D of 0.915 g/cm 3 or below.
3. The polypropylene-plastomer-blend according to claim 1 , wherein the MFR(230/2.16) of the polypropylene-plastomer-blend according to ISO 1133 is from 2.5 to 15 g/10 min.
4. A film comprising the polypropylene-plastomer blend according to claim 1 .
5. The film according to claim 4 , wherein the film is produced via blown film or cast film production and wherein the blown or cast film has a Sealing Initiation Temperature (SIT) of at most 140° C.
6. A container comprising the polypropylene-plastomer blend according to claim 1 .
7. A process for the production of films having reduced Sealing Initiation Temperature (SIT), the process comprising the steps of:
a. providing a polypropylene-plastomer-blend by blending 80-93 wt. % of a polypropylene random copolymer and 7-20 wt % of an ethylene-based plastomer, based on the sum of the amount of the polypropylene random copolymer and the ethylene based plastomer, wherein
the polypropylene random copolymer comprises at least 1.5 wt % ethylene as a comonomer, and the polypropylene random copolymer does not comprise an elastomeric polymer phase dispersed therein,
the ethylene based plastomer has a an MFR190/2.16 of at least 2.5 g/10 min, and
the ethylene based plastomer is a copolymer of ethylene and 1-hexene with an ethylene content of from 50 to 95 wt % or the ethylene based plastomer is a copolymer of ethylene and 1-octene with an ethylene content of from 50 to 95 wt %; and
b. forming a film out of the polypropylene-plastomer-blend resulting from step (a).
8. A process for the production of containers comprising a film having a reduced Sealing Initiation Temperature (SIT), wherein the process comprises the steps of
a. providing the polypropylene-plastomer-blend of claim 1 by blending 80-93 wt. % of the polypropylene random copolymer and 7-20 wt. % of the ethylene-based plastomer,
b. forming a film out of the polypropylene-plastomer-blend resulting from step (a), and
c. converting the film from step (b) on a horizontal or vertical form-fill-and-seal line (FFS-line) into a filled container.
9. A method of use of ethylene based plastomers having a density less than 0.915 g/cm 3 and an MFR190/2.16 of at least 2.5 g/10 min to reduce the sealing initiation temperature (SIT) of films comprising polypropylene.