Polyamide mixture having improved fluidity
The invention relates to a thermoplastic composition having improved fluidity in the molten state, comprising at least: (a) a polyamide that has a melt viscosity greater than or equal to 50 Pa·s, and (b) a non-evolutive polyamide having a melt viscosity lower than the melt viscosity of said polyamide (a), above 0.8 Pa·s, and having a number-average molecular weight Mn lower than that of said polyamide (a), said composition having a melt viscosity that is stabilized at a value below the melt viscosity of said polyamide (a), said polyamide (b) having: a concentration of amine end groups (AEG) and/or of carboxyl end groups (CEG) less than or equal to 20 meq/kg, or a concentration of amine end groups (AEG) greater than or equal to 25 meq/kg; a concentration of acid end groups (CEG) greater than or equal to 25 meq/kg; and a concentration of blocked end groups (BEG) greater than or equal to 25 meq/kg.
1. A thermoplastic composition having improved fluidity in the molten state, comprising at least:
(a) a polyamide that has a melt viscosity greater than or equal to 50 Pa·s, and
(b) a non-evolutive polyamide having a melt viscosity lower than the melt viscosity of said polyamide (a), above 0.8 Pa·s, and having a number-average molecular weight Mn lower than that of said polyamide (a),
said composition having a melt viscosity that is stabilized at a value below the melt viscosity of said polyamide (a),
said polyamide (b) having:
a concentration of amine end groups (AEG) and/or of carboxyl end groups (CEG) less than or equal to 20 meq/kg, or
a concentration of amine end groups (AEG) greater than or equal to 25 meq/kg; a concentration of acid end groups (CEG) greater than or equal to 25 meq/kg; and a concentration of blocked end groups (BEG) greater than or equal to 25 meq/kg,
wherein the content of the polyamide (b) is from 5 to 20 wt % relative to the total weight of the composition, and
wherein said polyamides (a) and (b) being selected independently of one another from the group consisting of: PA 66, PA 6.10, PA 6.12, PA 12.12, PA 4.6, PA 6, PA 7, PA 9T, PA 10T, PA 11, PA 12, PA 6T/61, PA 6T/61/66, copolyamides thereof, and mixtures thereof.
2. The composition as claimed in claim 1 , in which the content of polyamide (b) is from 5 to 12 wt % relative to the total weight of the composition.
3. The composition as claimed in claim 1 , in which polyamides (a) and (b) are structurally similar to one another, or are derived from the same polyamide, and the melting point of polyamide (b) being less than or equal to that of polyamide (a).
4. The composition as claimed in claim 1 having a melt viscosity below 50% of the melt viscosity of said polyamide (a).
5. The composition as claimed in claim 1 , having a melt viscosity that increases, at most by 25%, relative to its initial value for a time of at least 15 minutes, at constant temperature and pressure under an inert atmosphere.
6. The composition as claimed in claim 1 , said polyamide (b) having a melt viscosity below 50 Pa·s.
7. The composition as claimed in claim 1 , in which said polyamide (b) has a concentration of amine end groups (AEG) and/or of carboxyl end groups (CEG) less than or equal to 15 meq/kg.
8. The composition as claimed in claim 1 , said polyamide (b) having a number-average molecular weight Mn between 5000 and 8500 g/mol.
9. The composition as claimed in claim 1 , said polyamide (a) having a melt viscosity ranging from 50 to 2000 Pa·s.
10. The composition as claimed in claim 1 , said polyamide (a) having a number-average molecular weight Mn between 8000 and 40000 g/mol.
11. The composition as claimed in claim 1 , in which said polyamides (a) and (b) are selected independently of one another from the polyamides resulting from the polycondensation of at least one aliphatic dicarboxylic acid with an aliphatic or cyclic diamine, the polyamides resulting from polycondensation of at least one aromatic dicarboxylic acid and an aliphatic or aromatic diamine, the polyamides obtained by polycondensation of at least one amino acid or lactam with itself, or mixtures thereof and (co)polyamides.
12. A thermoplastic composition having improved fluidity in the molten state, comprising:
(a) a polyamide that has a melt viscosity greater than or equal to 50 Pa·s, and
(b) a non-evolutive polyamide having a melt viscosity lower than the melt viscosity of said polyamide (a), above 0.8 Pa·s, and having a number-average molecular weight Mn lower than that of said polyamide (a),
said composition having a melt viscosity that is stabilized at a value below the melt viscosity of said polyamide (a),
said polyamide (b) having:
a concentration of amine end groups (AEG) and/or of carboxyl end groups (CEG) less than or equal to 20 meq/kg, or
a concentration of amine end groups (AEG) greater than or equal to 25 meq/kg; a concentration of acid end groups (CEG) greater than or equal to 25 meq/kg; and a concentration of blocked end groups (BEG) greater than or equal to 25 meq/kg,
wherein said polyamides (a) and (b) comprising, independently of one another, hydroxyaromatic units bound chemically to the chain of the polyamide.
13. A method for manufacturing a composite comprising at least one step of impregnation of a reinforcing fabric with a composition as claimed in claim 1 in the molten state.
14. A composite article obtained by the method as claimed in claim 13 .