Process for the separation of glycols

1. A process for the separation of MEG from a glycol stream comprising MEG and 1,2-BDO, said process comprising the steps of: (a) providing the glycol stream and an azeotrope-forming agent to a distillation column, (b) subjecting the glycol stream and the azeotrope-forming agent to distillation at a distillation temperature and a distillation pressure; (c) obtaining a first overhead stream comprising an azeotrope of MEG and the azeotrope-forming agent and a first bottoms stream comprising 1,2-BDO; and (d) subjecting the first overhead stream to phase separation in the presence of water to obtain an MEG-rich aqueous stream and an azeotrope-forming agent rich stream, wherein the azeotrope-forming agent is an N,N-dimethylcyclohexylamine that forms a homogeneous azeotrope with MEG and does not form an azeotrope with 1,2-BDO at the distillation temperature and pressure.

2. A process according to claim 1 , wherein the glycol stream also comprises MPG.

3. A process according to claim 1 , wherein the glycol stream is the reaction product stream from a process for the hydrogenolysis of a saccharide-containing feedstock or is derived therefrom.

4. A process according to claim 1 , wherein the amount of azeotrope-forming agent provided to the distillation column is such that the molar ratio of azeotrope-forming agent to MEG is at most 10:1 and at least 1:1.

5. A process according to claim 1 , wherein the distillation temperature is in the range of from 20 to 250° C.

6. A process according to claim 1 , wherein the distillation pressure is in the range of from 0.1 to 350 kPa.

7. A process according to claim 1 , wherein the phase separation of the first overheads stream is carried out at a water to azeotrope-forming agent molar ratio in the range of from 1:50 to 1:1.

8. A process according to claim 1 , wherein the phase separation is carried out a temperature of at least 60° C.