Porous molding, gel molding and filter
To provide a porous molding that can be used as a molding that has sufficient strength to be self-supportable even when the dimensions change due to absorbing water and that can be suitably used as a filter for removing impurities in a liquid or gas. A porous molding is achieved by sintering a mixed powder including a dried gel powder and a thermoplastic resin powder, wherein the ratio of average particle diameter d 1 of the thermoplastic resin powder to the average particle diameter d 2 of the dried gel powder d 2 /d 1 is 1.3 or greater, and the difference ratio of average particle diameter d 1 of the thermoplastic resin powder to the average particle diameter d 2 of the dried gel powder and the average particle diameter d 3 of the dried gel powder when absorbing water and swelling is (d 3 −d 2 )/d 1 is 4.0 or less.
1. A porous molding that is achieved by sintering a mixed powder including dried gel powder and thermoplastic resin powder, wherein:
a ratio of an average particle diameter d 2 of the dried gel powder to an average particle diameter di of the thermoplastic resin powder d 2 /d 1 is 1.3 or more, and
d 3 is an average particle diameter of the dried gel powder when absorbing water and swelling, wherein (d 3 -d 2 )/d 1 is 4.0 or less, and wherein the porous molding is self-supportable before and after the dried gel powder absorbs water and swells.
2. The porous molding according to claim 1 , wherein the coefficient of water absorption of the dried gel powder ranges from 30% mass to 90% mass.
3. The porous molding according to claim 1 , wherein the average particle diameter d 1 of the thermoplastic resin powder ranges from 0.1 μm to 100 μm.
4. The porous molding according to claim 1 , wherein the average particle diameter d 2 of the dried gel powder ranges from 50 μm to 250 μm.
5. The porous molding according to claim 1 , wherein the thermoplastic resin powder includes ultra-high molecular weight polyethylene or polyamide.
6. The porous molding according to claim 1 , wherein
the thermoplastic resin powder includes ultra-high molecular weight polyethylene,
and the weight-average molecular weight of the ultra-high molecular weight polyethylene ranges from 1.5×10 6 g/mol to 1.2×10 7 g/mol.
7. The porous molding according to claim 1 , wherein the thermoplastic resin powder is non-spherical.
8. The porous molding according to claim 1 , wherein the dried gel powder has at least one type of functional group selected from a group consisting of an ion exchange group and a chelate group.
9. A method for removing metal ion from a processing liquid, comprising
a step for passing the processing liquid through a filter including a gel molding achieved by the porous molding according to claim 8 swelling with water.
10. A gel molding achieved by the porous molding according to claim 1 being caused to swell with water.
11. A filter including the porous molding according to claim 1 .
12. A method for removing moisture from a processing liquid, comprising a step for passing the processing liquid through a filter including the porous molding according to claim 1 .
13. The porous molding according to claim 1 , wherein the dried gel powder is fixed by the thermoplastic resin forming the self-supportable molding.
14. The porous molding according to claim 1 , wherein the self-supportable molding has a shape with first dimensions before the dried gel powder absorbs water and swells and has the same shape with second, different dimensions after the dried gel powder absorbs water and swells.
15. The porous molding according to claim 1 , wherein the self-supportable molding is a molding having a maximum bending stress of at least 5 kgf/cm 2 after the dried gel powder absorbs water and swells.