Ziegler-natta catalyst and preparation thereof
View Patent ↗This invention relates to a solid MgCl 2 based Natta catalyst component for producing olefin polymers and preparation of said catalyst component. Further the invention relates to a Ziegler Natta catalyst comprising said solid catalyst component, Group 13 metal compound as cocatalyst and optionally external additives. The invention further relates to the use of said catalyst component in producing olefin polymers, especially ethylene polymers with desired properties.
1. A method for producing solid MgCl 2 supported catalyst component comprising the steps
a) providing solid carrier particles of MgCl 2 *mROH adduct;
b) pre-treating the solid carrier particles of step a) with a compound of Group 13 metal;
c) treating the pre-treated solid carried particles of step b) with a transition metal compound of Group 4 to 6;
d) recovering the solid catalyst component;
wherein the solid carrier particles are contacted with an internal organic compound of formula (I) or isomers or mixtures therefrom before treating the solid carrier particles in step c)
wherein in the formula (I)
R 1 to R 5 are the same or different and are hydrogen, a linear or branched C 1 to C 8 -alkyl group, or a C 3 -C 8 -alkylene group, or two or more of R 1 to R 5 can form a ring, the two oxygen-containing rings are individually saturated or partially unsaturated or unsaturated, and R in the adduct MgCl 2 *mROH is a linear or branched alkyl group with 1 to 12 C atoms, and m is 0 to 6; and
wherein the solid catalyst component has Mg/Ti mol/mol ratio of 1 to 10, Al/Ti mol/mol ratio of 0.01 to 1, and Cl/Ti mol/mol ratio of 5 to 20.
2. A method according to claim 1 , wherein the solid carrier particles are contacted with the internal organic compound of formula (I) or isomers or mixtures therefrom before the pre-treating step b).
3. A method according to claim 1 , wherein the solid carrier particles are contacted with the internal organic compound of formula (I) or isomers or mixtures therefrom simultaneously with the pre-treating step b) or after the pre-treating step b) but before the treating step c).
4. A method according to claim 1 wherein in the formula (I) of the internal organic compound the two R 1 are the same and are a linear C 1 to C 4 -alkyl groups, or the two R 1 form with the carbon atom they are attached to a ring with 3 to 7C-atoms, R 2 to R 5 are the same or different, or two or more of R 2 to R 5 residues can form a ring.
5. A method according to claim 1 wherein in the formula (I) of the internal organic compound both R 1 are the same and are methyl or ethyl groups and the residues R 2 to R 5 are the same or different and are H or a C 1 to C 2 -alkyl groups.
6. A method according to claim 1 wherein the internal organic compound is 2,2-di(2-tetrahydrofuryl) propane or 2,2-di-(2-furan)-propane.
7. A method according to claim 1 wherein the R in MgCl 2 *mROH adduct is a linear or branched alkyl group containing 1 to 8 C atoms and m is 1 to 4.
8. A method according to claim 1 wherein the Group 13 metal compound is an aluminum compound of the formula Al(alkyl) x X 3-x (II), wherein each alkyl is independently a linear, branched or cyclic alkyl group of 1 to 12C-atoms, X is halogen and 1<x≤3.
9. A method according to claim 1 wherein the Group 13 metal compound is selected from the group consisting of dialkyl aluminium chlorides, trialkyl aluminium, and mixtures therefrom.
10. A method according to claim 1 wherein no Mg compounds are used in catalyst preparation other than the MgCl 2 *mROH adduct.
11. A solid MgCl 2 supported catalyst component prepared by the method of claim 1 .
12. A catalyst comprising the solid MgCl 2 supported catalyst component of claim 11 and a cocatalyst of Group 13 metal compound.
13. A process of producing an ethylene polymer comprising polymerising ethylene in the presence of the solid MgCl 2 supported catalyst component of claim 11 .
14. A process for producing ethylene polymer in a polymerisation process comprising polymerisation of ethylene in the presence of the Ziegler-Natta catalyst of claim 12 under polymerisation conditions in at least one polymerisation stage carried out in a solution, slurry or gas phase reactor or combinations thereof.
15. A method according to claim 4 wherein in the formula (I) of the internal organic compound, the two R 1 form with the carbon atom they are attached to a cyclopentyl or cyclohexyl ring.
16. A method according to claim 4 wherein in the formula (I) of the internal organic compound, R 3 and R 4 residues form a ring and/or R 4 and R 5 residues form a ring.
17. A method according to claim 5 wherein in the formula (I) of the internal organic compound at most two of the residues R 2 to R 5 are a methyl, the others are H.
18. A method according to claim 6 wherein the internal organic compound is 2,2-di(2-tetrahydrofuryl) propane.
19. A process according to claim 13 further comprising polymerising ethylene with comonomers.
20. A method according to claim 14 further comprising polymerisation of ethylene with comonomers selected from C 3 -C 20 -alpha-olefins.