Pressure-sensitive adhesive composition
Provided are a pressure-sensitive adhesive composition for an optical film, which has excellent optical compensation and stress relaxation properties without changing main properties such as endurance reliability and workability under a high temperature and/or high humidity condition to minimize a light leakage phenomenon caused by stress concentration of a protective film, and an optical member and a liquid crystal display device which include a pressure-sensitive adhesive layer manufactured using the same.
1. A pressure-sensitive adhesive composition for an optical film, comprising:
a polymer containing 60 to 80 parts by weight of an alkyl (meth)acrylate having an alkyl group having 4 to 12 carbon atoms, 1 to 5 parts by weight of a monomer of Formula 1, 5 to 20 parts by weight of a polymerizable monomer having an aromatic group, 7 to 12 parts by weight of a hydroxyalkyl (meth)acrylate having an alkyl group having 2 or less carbon atoms, 0.1 to 2 parts by weight of a hydroxyalkyl (meth)acrylate having an alkyl group having in the range of 3 to 6 carbon atoms, and 0.01 to 0.5 parts by weight of a carboxyl group-containing polymerizable monomer as polymerization units with respect to a total of 100 parts by weight:
where Q is hydrogen or an alkyl group having 1 to 4 carbon atoms, U is an alkylene group having 1 to 4 carbon atoms, Z is an alkyl group having 1 to 20 carbon atoms, and m is a number in the range of 1 to 3, and
wherein the monomer of Formula 1 is 2-(2-ethoxyethoxy)ethyl (meth)acrylate.
2. The composition of claim 1 , wherein the polymer includes 60 to 75 parts by weight of the alkyl (meth)acrylate having an alkyl group having 4 to 12 carbon atoms as a polymerization unit.
3. The composition of claim 1 , wherein the polymerizable monomer including an aromatic group is represented by Formula 2:
where Q is hydrogen or an alkyl group having 1 to 4 carbon atoms, U is an alkylene group having 1 to 4 carbon atoms, X is a single bond, an oxygen atom, a sulfur atom or an alkylene group having 1 to 4 carbon atoms, n is a number in the range of 0 to 3, and Ar is an aryl group having 6 to 25 carbon atoms.
4. The composition of claim 1 , wherein the polymerizable monomer including an aromatic group is phenoxy ethyl (meth)acrylate, benzyl (meth)acrylate, 2-phenylthio-1-ethyl (meth)acrylate, 2-(1-naphthyloxy)-1-ethyl (meth)acrylate or 2-(2-naphthyloxy)-1-ethyl (meth)acrylate.
5. The composition of claim 1 , wherein the polymer includes 7 to 15 parts by weight of the polymerizable monomer including an aromatic group as a polymerization unit.
6. The composition of claim 1 , wherein the carboxyl group-containing polymerizable monomer is one or more selected from the group consisting of (meth)acrylic acid, 2-(meth)acryloyloxy acetic acid, 3-(meth)acryloyloxy propylic acid, 4-(meth)acryloyloxy butyric acid, an acrylic acid dimer, itaconic acid, maleic acid, and maleic acid anhydride.
7. The composition of claim 1 , wherein the polymer further includes 1 to 5 parts by weight of methyl (meth)acrylate as a polymerization unit.
8. The composition of claim 1 , further comprising:
0.01 to 10 parts by weight of a multifunctional crosslinking agent with respect to 100 parts by weight of the polymer.
9. The composition of claim 8 , wherein the multifunctional crosslinking agent is a multifunctional compound including two or more functional groups selected from the group consisting of an isocyanate group, a carboxyl group, an epoxy group, an acid anhydride group, an aziridinyl group, a carbodiimide group, an amine group and an oxazoline group.
10. The composition of claim 1 , further comprising:
0.01 to 10 parts by weight of an antistatic agent with respect to 100 parts by weight of the polymer.
11. The composition of claim 10 , wherein the antistatic agent is an ionic compound.
12. The composition of claim 11 , wherein the ionic compound is a metal salt or an organic salt.
13. A polarizing plate, comprising:
an optical film; and
a pressure-sensitive adhesive layer formed from the pressure-sensitive adhesive composition for an optical film of claim 1 which is formed on one or both surfaces of the optical film.
14. The polarizing plate of claim 13 , wherein the optical film is a polarizing film.
15. A liquid crystal display device, comprising:
a liquid crystal panel comprising the polarizing plate of claim 13 which is bonded to one or both surfaces of a liquid crystal cell.
16. A liquid crystal display device, comprising:
a liquid crystal panel comprising the polarizing plate of claim 14 which is bonded to one or both surfaces of a liquid crystal cell.