IP Library Granted Patent US 10,717,947
Granted Patent B2
US 10,717,947 · App. 15/538,057 · Granted Jul 21, 2020

Solid composition comprising a quaternary ammonium compound and polysaccharide, the process and use thereof

Inventors: Hai Zhou Zhang (Singapore, SG); Nikolay Christov (Singapore, SG); Da Wei Jin (Singapore, SG); Lin He (Singapore, SG)
Assignee: Rhodia Operations
C11D1/62C08K5/19C11D3/222C11D3/227C11D3/43D06M13/46D06M15/03D06M23/08D06M2200/50
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Quick Facts
Patent No.
US 10,717,947
App. No.
15/538,057
Granted
Jul 21, 2020
Kind
B2
Abstract

The present invention provides a solid composition comprising (a) a quaternary ammonium compound and (b) between 9 wt % and 77 wt % of a polysaccharide based on the total weight of the solid composition. The solid composition showed excellent stability. The present invention also provides a process for preparing the solid composition and a liquid composition comprising said solid composition, and methods for conditioning a fabric by using the solid composition and the liquid composition as well.

Claims (41)

1. A solid composition comprising:

(a) between 50 wt. % and 91 wt. % of a quaternary ammonium compound; and

(b) between 9 wt. % and 50 wt. % of a polysaccharide based on the total weight of the solid composition;

wherein the solid composition comprises less than 0.1 wt. % of water and the quaternary ammonium compound has the general formula (III):

[N + ((CH 2 ) n -T-R 8 ) 2 (R 8 )(R 9 )] y X −   (III)

wherein:

R 9 group is independently selected from a C 1 -C 4 alkyl or hydroxylalkyl group;

R 8 group is independently selected from a C 1 -C 30 alkyl or alkenyl group;

T is C(═O)—O— or O—C(═O)—;

n is an integer from 0 to 5;

X is an anion; and

y is the valence of X.

2. The solid composition according to claim 1 , wherein the solid composition does not comprise any carrier material.

3. The solid composition according to claim 1 , wherein the quaternary ammonium compound has the general formula (IV):

N + (C 2 H 4 —OOCR 10 ) 2 (CH 3 )(C 2 H 4 —OH)(CH 3 ) z SO 4 −   (IV)

wherein R 10 is a C 12 -C 20 alkyl group; and

z is 1.

4. The solid composition according to claim 1 , wherein the polysaccharide is a cationic polysaccharide and a nonionic polysaccharide.

5. The solid composition according to claim 1 , wherein the polysaccharide is a cationic guar and a nonionic guar.

6. The solid composition according to claim 1 , wherein the polysaccharide is selected from at least one cationic polysaccharide, at least one nonionic polysaccharide, at least one ampholytic polysaccharide, or combinations thereof.

7. The solid composition according to claim 6 , wherein the at least one cationic polysaccharide is at least one cationic guar.

8. The solid composition according to claim 7 , wherein the at least one cationic guar is selected from guar hydroxypropyltrimonium chloride, hydroxypropyl guar hydroxypropyltrimonium chloride, and combinations thereof.

9. The solid composition according to claim 6 , wherein the at least one nonionic polysaccharide is at least one nonionic guar.

10. A process for preparing a liquid composition, comprising the step of mixing the solid composition according to claim 1 with a solvent selected from water, an organic solvent, or a mixture thereof.

11. A method for conditioning a fabric, comprising the step of contacting the fabric with the solid composition according to claim 1 during a drying cycle of a dryer.

12. A process for preparing a solid composition comprising the steps of:

(i) combining a polysaccharide with a quaternary ammonium compound in liquid form to obtain a mixture; and

(ii) solidifying the mixture;

wherein the solid composition comprises:

(a) between 50 wt. % and 91 wt. % of a quaternary ammonium compound; and

(b) between 9 wt. % and 50 wt. % of a polysaccharide based on the total weight of the solid composition;

wherein the solid composition comprises less than 0.1 wt. % of water and the quaternary ammonium compound has the general formula (III):

[N + ((CH 2 ) n -T-R 8 ) 2 (R 8 )(R 9 )] y X −   (III)

wherein:

R 9 group is independently selected from a C 1 -C 4 alkyl or hydroxylalkyl group;

R 8 group is independently selected from a C 1 -C 30 alkyl or alkenyl group;

T is —C(═O)—O— or —O—C(═O)—;

n is an integer from 0 to 5;

X is an anion; and

y is the valence of X.

13. The process according to claim 12 , wherein the quaternary ammonium compound is melted to form the quaternary ammonium compound in liquid form, and the mixture is solidified by cooling the mixture.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 26, 2024
From: RHODIA OPERATIONS
To: SPECIALTY OPERATIONS FRANCE
Reel/Frame 066374/0642 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 7, 2017
From: ZHANG, HAI ZHOU; CHRISTOV, NIKOLAY; JIN, DA WEI; HE, LIN
To: RHODIA OPERATIONS
Reel/Frame 043524/0792 →
Priority Claims (1)
WO PCT/EP2014/079039 · Dec 22, 2014 · international
Continuity (1)
Related Publication 20170349859A1 · Dec 7, 2017
Cited By (1)
US 12,661,311