Siloxane coordination polymers
View Patent ↗A functionalized siloxane includes a ligand capable of coordinating a metal. The functionalized siloxane includes a pyridine-containing ligand attached to a siloxane polymer. The functionalized siloxanes can be employed to provide complexes including a metal that may impart a desired property to the polymer. In one embodiment, the polymer can complex lanthanide metals that are capable of phosphorescing upon exposure to UV irradiation. Such polymers can be employed to provide functional materials such as, for example, luminescent films, coatings, etc.
1. A siloxane polymer of the formula:
MD x D′ y M′; or
M′D x D′ x M′
where M is R′R 2 R 3 SiO 1/2 , M′ is R 4 R 5 R 6 SiO 1/2 ; D is (R 7 ) 2 SiO; and D′ is (R 8 )R 9 SiO, x and y are independently an integer chosen from 0 to 120; each of R 1 , R 2 , R 3 , R 4 , and R 5 is independently chosen from a hydrocarbon radical, an alkoxy radical, an aryl radical, or an alkenyloxy radical; R 7 and R 9 are independently chosen from a hydrocarbon radical, a substituted hydrocarbon radical, an unsaturated radical, an aryl radical, an alkoxy radical, or an alkenyloxy radical; R 6 and R 8 are independently chosen from a hydrocarbon radical or a monovalent radical bearing a lanthanide salt complex of a pyridine-containing ligand and having the general formula -A-L m Mt n , wherein A is a spacing group having at least one spacing atom chosen from a divalent hydrocarbon optionally substituted with a heteroatom, hydrocarbonoxy group, urethane group, amide group and oxyalkylene group, where the siloxane polymer includes at least one R 6 group and/or at least one R 8 group chosen from the pyridine-containing ligand of the formula -A-L m Mt n ; L is a ligand comprising one or more heteroatoms and capable of complexing a metal, where L is a pyridine-containing ligand chosen from a substituted or unsubstituted bidentate pyridine ligand, a substituted or unsubstituted tridentate pyridine ligand, a substituted or unsubstituted multidentate pyridine ligand or a combination of two or more thereof; Mt is at least one metal ion or a metal salt, m is an integer from 1 to 6, n is an integer from 1 to 6, and Mt is selected from the group consisting of a metal ion and/or a salt of yttrium, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, zinc, nickel, copper, cobalt, iron, titanium, zirconium, aluminum, germanium, tantalum, niobium, hafnium, tin, indium, vanadium, tungsten, chromium, magnesium, strontium, silver, or a combination of two or more thereof.
2. The siloxane polymer of claim 1 , wherein the pyridine-containing ligand is derived from a terpyridine compound of the formula:
where R 10 -R 20 are independently chosen from hydrogen, an alkyl, a substituted alkyl, an aryl, a substituted aryl, a polyether, a substituted polyether, a siloxane, and an inert functional group, optionally any two of R 10 -R 20 vicinal to one another, R 10 /R 20 and/or R 12 /R 13 taken together may form a ring being a substituted or unsubstituted, saturated, or unsaturated cyclic structure.
3. The siloxane polymer of claim 1 , wherein Mt is chosen from a salt of europium, terbium, dysprosium, or a combination of two or more thereof.
4. The siloxane polymer of claim 1 , wherein the metal Mt is chosen from at least two different metals or metal salts.
5. The siloxane polymer of claim 1 , wherein at least one of R 1 , R 2 , R 3 , R 4 and/or R 5 is a C 1 to C 12 alkyl radical.
6. The siloxane polymer of claim 5 , wherein the C 1 to C 12 alkyl radical is independently chosen from methyl, ethyl, propyl, butyl, isopentyl, n-hexyl, and decyl.
7. The siloxane polymer of claim 1 , wherein each of R 1 , R 2 , R 3 , R 4 and R 5 is independently chosen from a C 1 to C 12 alkyl radical.
8. The siloxane polymer of claim 7 , wherein the C 1 -C 12 alkyl radical is independently chosen from methyl, ethyl, propyl, butyl, isopentyl, n-hexyl, or decyl.
9. The siloxane polymer of claim 1 , wherein each of R 1 , R 2 , R 3 , R 4 and R 5 is independently chosen from a C 5 -C 12 cycloaliphatic radical, an arylalkyl radical, or an aryl radical.
10. The siloxane of claim 9 , wherein each of R 1 , R 2 , R 3 , R 4 and R 5 is independently chosen from a cyclohexyl, cyclooctyl, phenylethyl, tolyl, or xylyl.
11. The siloxane polymer of claim 1 , wherein at least one of R 1 , R 2 , R 3 , R 4 and R 5 is a cycloaliphatic radical selected from the group consisting of cyclohexyl, cyclooctyl, phenylethyl, tolyl, and xylyl.
12. The siloxane polymer of claim 1 , wherein each of R 1 , R 2 , R 3 , R 4 and R 5 is independently chosen from a C 1 to C 12 alkoxy radical.
13. The siloxane polymer of claim 12 , wherein the C 1 to C 12 alkoxy radical is selected from the group consisting of methoxy, ethoxy, propoxy, butoxy, and decyloxy.
14. A siloxane polymer of the formula:
R 10 -R 20 where R are independently chosen from hydrogen, an alkyl, a substituted alkyl, an aryl, a substituted aryl, a siloxane, or an inert functional group, optionally any two of R 10 -R 20 vicinal to one another, R 10 /R 20 , and/or R 12 /R 13 taken together may form a ring being a substituted or unsubstituted, saturated, or unsaturated cyclic structure, o and p are independently an integer selected from 0 to 5, and x is an integer selected from 0 to 120, or a siloxane polymer of the formula:
where R 10 -R 20 are independently chosen from hydrogen, an alkyl, a substituted alkyl, an aryl, a substituted aryl, a siloxane, or an inert functional group, optionally any two of R 10 -R 20 vicinal to one another, R 10 /R 20 , and/or R 12 /R 13 taken together may form a ring being substituted or unsubstituted, saturated, or unsaturated cyclic structure, o and p are independently 1 to 5, and x and x′ are independently 1 to 120,
the siloxane polymers above optionally complexing a metal Mt n where Mt is at least one metal ion or a metal salt, and n is an integer from 0 to 2.
15. The siloxane polymer of claim 1 , wherein the polymer is a complex chosen from:
16. A composition comprising the polymer of claim 1 .
17. The composition of claim 16 , wherein the composition is chosen from a film-forming composition, a coating composition, an adhesive composition, an emulsion composition, a molding composition, a sealant composition, an encapsulant composition, or a combination of two or more thereof.
18. The composition of claim 16 comprising the polymer of any one of claims 1 - 15 and a co-monomer.
19. A network comprising a plurality of the polymer of claim 1 .
20. An article comprising a coating on at least a portion of the surface thereof, wherein the coating is formed from the composition of claim 16 .
21. A curable composition comprising (A) a siloxane polymer of claim 1 , (B) a siloxane compound independently having at least one carbon-carbon double bond per molecule or at least one hydroxy group per molecule or at least one alkoxy group per molecule, (C) a siloxane compound independently containing at least one SiH groups per molecule or an alkoxysilane crosslinker or at least one hydroxy group, (D) a hydrosilylation catalyst or a condensation catalyst or a reaction initiator, and (E) optional organic/inorganic filler, additives and pigments.
22. A process for forming a functionalized siloxane comprising:
reacting a hydride, hydroxyl, and/or amine functional siloxane polymer with a pyridine-containing ligand via a hydrosilylation reaction, a condensation reaction, and/or a urethane/urea formation reaction to form a siloxane polymer comprising a pyridine-containing ligand attached to the siloxane polymer; and
complexing the siloxane polymer comprising the pyridine-containing ligand with a lanthanide metal ion, a salt of a lanthanide metal, or a combination of two or more thereof.
23. The process of claim 22 , wherein the pyridine-containing ligand comprises terpyridine.