Process for purifying monooctylin trichloride
View Patent ↗The present invention provides a process for producing monooctyltin trichloride comprising very low levels of dioctyltin and trioctyltin compounds, said process comprising the following steps: (1) Contacting an organotin chloride mixture comprising monooctyltin chloride with an aqueous phase containing halide ions, said step optionally being carried out in the presence of organic solvent; (2) separating the resulting aqueous phase which is rich in monooctyltin chloride from the organic phase containing most of the dioctyltin and trioctyltin compounds; (3) optionally purifying said aqueous phase comprising monooctyltin trichloride from undesired side products by washing said aqueous phase with an organic solvent; and (4) recovering monooctyltin trichloride from said aqueous phase comprising monooctyltin trichloride.
1. A process for producing monooctyltin trichloride comprising very low levels of dioctyltin and trioctyltin compounds, the process comprising:
i) contacting an organotin chloride mixture comprising monooctyltin chloride, which organotin chloride mixture also comprises dioctyltin compounds and/or trioctyltin compounds, with an aqueous phase containing halide salts, optionally in the presence of organic solvent, resulting in an aqueous phase comprising monooctyltin chloride, and an organic phase containing most of the dioctyltin trioctyltin and/or trioctyltin compounds;
ii) separating the aqueous phase from the organic phase;
iii) purifying the aqueous phase from undesired side products by washing the aqueous phase with an organic solvent; and
iv) recovering monooctyltin trichloride from the aqueous phase.
2. The process according to claim 1 , wherein i), contacting the organotin chloride mixture with the aqueous phase containing halide salts, is carried out in the presence of an organic solvent.
3. The process according to claim 2 , wherein the organic solvent present during i), contacting the organotin chloride mixture with the aqueous phase containing halide salts, is selected from the group consisting of n-hexane, n-heptane and di-n-butyl ether.
4. The process according to claim 3 , wherein the organic solvent used in iii) to wash the aqueous phase is selected from the group consisting of n-hexane and n-heptane.
5. The process according to claim 4 , wherein i), contacting the organotin chloride mixture with the aqueous phase containing halide salts in the presence of an organic solvent selected from the group consisting of n-hexane, n-heptane and di-n-butyl ether, is carried out at a temperature of 20 to 50° C.
6. The process according to claim 5 , wherein iii), washing the aqueous phase with an organic solvent, is carried out at a temperature of 20 to 50° C.
7. The process according to claim 3 , wherein i), contacting the organotin chloride mixture with the aqueous phase containing halide salts in the presence of an organic solvent selected from the group consisting of n-hexane, n-heptane and di-n-butyl ether, is carried out at a temperature of 20 to 50° C.
8. The process according to claim 2 , wherein the organic solvent used in iii) to wash the aqueous phase is selected from the group consisting of n-hexane and n-heptane.
9. The process according to claim 2 , wherein i), contacting the organotin chloride mixture with the aqueous phase containing halide salts in the presence of an organic solvent, is carried out at a temperature of 20 to 50° C.
10. The process according to claim 2 , wherein iii), washing the aqueous phase with an organic solvent, is carried out at a temperature of 20 to 50° C.
11. The process according to claim 1 , wherein the organic solvent used in iii) to wash the aqueous phase is selected from the group consisting of n-hexane and n-heptane.
12. The process according to claim 11 , wherein i), contacting the organotin chloride mixture with the aqueous phase containing halide salts, is carried out at a temperature of 20 to 50° C.
13. The process according to claim 12 , wherein iii), washing the aqueous phase with an organic solvent, is carried out at a temperature of 20 to 50° C.
14. The process according to claim 11 , wherein i), contacting the organotin chloride mixture with the aqueous phase containing halide salts, is carried out at a temperature of 20 to 50° C.
15. The process according to claim 1 , wherein i), contacting the organotin chloride mixture with the aqueous phase containing halide salts, is carried out at a temperature of 20 to 50° C.
16. The process according to claim 1 , wherein iii), washing the aqueous phase with an organic solvent, is carried out at a temperature of 20 to 50° C.
17. The process according to claim 1 , wherein the monooctyltin trichloride produced by the process comprises less than 0.3% of dioctyltin dichloride and less than 0.1% trioctyltin chloride.