Reinforced polycarbonate compositions
View Patent ↗The disclosure concerns blended thermoplastic compositions comprising (a) from about 50 wt % to about 80 wt % of a polycarbonate component; (b) from greater than 0 wt % to about 12 wt % of an impact modifier component; (c) from about 10 wt % to about 40 wt % of a filler; and (d) from about 5 wt % to about 15 wt % of a flame retardant component comprising an oligomeric phosphate ester, wherein the oligomeric phosphate ester is a free flowing powder at 23° C.; wherein the blended thermoplastic composition has a ductility of 100% at 10° C. when measured by a Notched Izod Impact test performed according to ASTM D256; wherein the combined weight percent value of all components does not exceed 100 wt %; and wherein all weight percent values are based on the total weight of the composition.
1. A blended thermoplastic composition comprising:
a) from about 50 wt % to about 80 wt % of a polycarbonate component;
b) from greater than 0 wt % to about 12 wt % of an impact modifier component;
c) from about 10 wt % to about 40 wt % of a filler;
d) from about 5 wt % to about 15 wt % of a flame retardant component comprising an oligomeric phosphate ester, wherein the oligomeric phosphate ester is a free flowing powder at 23° C.; and
e) from about 1 wt % to about 10 wt % of a second flame retardant component that is a phosphate ester that is a liquid at 23° C.,
wherein the combined weight percent value of all components does not exceed 100 wt %, and
wherein all weight percent values are based on the total weight of the composition.
2. The composition of claim 1 , wherein the blended thermoplastic composition has a ductility of 100% at 10° C. when measured by a Notched Izod Impact test performed according to ASTM D256.
3. The composition of claim 1 , wherein the polycarbonate component comprises at least one bisphenol A polycarbonate and at least one polycarbonate-polysiloxane copolymer.
4. The composition of claim 1 , wherein the polycarbonate component comprises a polycarbonate having a weight average molecular weight from about 18,000 to about 40,000 grams/mole, as measured by gel permeation chromatography using BPA polycarbonate standards.
5. The composition of claim 1 , wherein the polycarbonate component comprises a blend of at least two polycarbonate polymers including a first polycarbonate polymer component and a second polycarbonate polymer component.
6. The composition of claim 5 , wherein the first polycarbonate polymer component is a polycarbonate having a melt flow rate (MFR) from about 20 g/10 min to about 30 g/10 min when measured at 300° C. and under a load of 1.2 kg according to ASTM D1238, and wherein the second polycarbonate polymer component is a polycarbonate having a MFR from about 4.0 g/10 min to about 10.0 g/10 min when measured at 300° C. and under a load of 1.2 kg according to ASTM D1238.
7. The composition of claim 5 , wherein the first polycarbonate component is present in an amount from about 20 wt % to about 70 wt %; and wherein the second polycarbonate component is present in an amount from about 5 wt % to about 40 wt % based on the total weight of the composition.
8. The composition of claim 5 , further comprising a third polycarbonate polymer component.
9. The composition of claim 8 , wherein the third polycarbonate polymer component is a polycarbonate-polysiloxane copolymer.
10. The composition of claim 1 , wherein the composition is capable of achieving a UL 94 V0 rating at a thickness of 1.5 mm or less.
11. The composition of claim 1 , wherein the impact modifier component comprises at least one of acrylonitrile-butadiene-styrene (ABS), polymer methyl methacrylate-butadiene-styrene (MBS), methyl methacrylate-butadiene (MB) polymer, and silicone-acrylic-based rubber.
12. The composition of claim 11 , wherein the impact modifier is present in an amount from about 1 wt % to about 8 wt %.
13. An article comprising the composition of claim 1 .
14. A method of preparing a composition, comprising the step of combining:
a) from about 50 wt % to about 80 wt % of a polycarbonate component;
b) from greater than 0 wt % to about 12 wt % of an impact modifier component;
c) from about 10 wt % to about 40 wt % of a filler;
d) from about 5 wt % to about 15 wt % of a flame retardant component comprising an oligomeric phosphate ester, wherein the oligomeric phosphate ester is a free flowing powder at 23° C.; and
e) from about 1 wt % to about 10 wt % of a second flame retardant component that is a phosphate ester that is a liquid at 23° C.,
wherein the combined weight percent value of all components does not exceed 100 wt %; and
wherein all weight percent values are based on the total weight of the composition.
15. The method of claim 14 , wherein the composition has a ductility of 100% at 10° C. when measured by a Notched Izod Impact test performed according to ASTM D256.
16. The method of claim 14 , wherein the polycarbonate component comprises at least one bisphenol A polycarbonate and at least one polycarbonate-polysiloxane copolymer.
17. The method of claim 14 , wherein the combining comprises extrusion blending.
18. The method of claim 14 , further comprising molding the composition into a molded article.