Styrene-free coating compositions for packaging articles such as food and beverage containers
View Patent ↗A method of forming a coating on a food or beverage container, which includes spraying a coating composition onto an interior surface of the food or beverage container, where the coating composition includes an emulsion-polymerized latex copolymer having copolymer chains of one or more ethylenically-unsaturated monomers and one or more styrene offset monomers. Preferably, the coating composition is substantially free of BPA, PVC, and styrene. The method may also include curing the sprayed coating composition, thereby providing the coating on the interior surface of the food or beverage container.
1. A method of forming a coating on a food or beverage container, the method comprising:
receiving a coating composition having an emulsion-polymerized latex copolymer dispersed in an aqueous carrier, wherein the emulsion-polymerized latex copolymer is a reaction product of monomers comprising:
one or more first ethylenically-unsaturated monomers each having one or more ethylenically-unsaturated groups; and
one or more styrene offset monomers comprising:
(i) one or more ethylenically-unsaturated, polycyclic monomers;
(ii) one or more ethylenically-unsaturated, monocyclic monomers each having a ring structure with 3-5 atoms in the ring; or
combinations thereof,
wherein a combined concentration of (i) and (ii) constitutes at least about 10% by weight of the monomers used to produce the emulsion-polymerized latex copolymer;
wherein the monomers used to produce the emulsion-polymerized latex copolymer are substantially free of BPA, PVC, halogenated monomers, and styrene; and
applying the coating composition to a substrate prior to or after forming the substrate into a food or beverage container, or a portion thereof.
2. The method of claim 1 , wherein applying the coating composition to the substrate comprises:
spraying the coating composition onto an interior surface of the food or beverage container; and
curing the sprayed coating composition to substantially remove the aqueous carrier, and provide the coating on the interior surface of the food or beverage container.
3. The method of claim 2 , wherein the average viscosity of the coating composition ranges from about 15 seconds to about 25 seconds, pursuant to the Viscosity Test.
4. The method of claim 2 , wherein the one or more first ethylenically-unsaturated monomers are each substantially free of cyclic groups.
5. The method of claim 2 , wherein the one or more first ethylenically-unsaturated monomers comprise:
one or more ethylenically-unsaturated, acid-functional monomers;
one or more non-cyclic (meth)acrylates; or
combinations thereof.
6. The method of claim 5 , wherein the one or more ethylenically-unsaturated, acid-functional monomers constitute at least 3% by weight of the emulsion-polymerized latex copolymer, based on the total weight of the monomers used to produce the emulsion-polymerized latex copolymer.
7. The method of claim 5 , wherein the one or more non-cyclic (meth)acrylates have a concentration ranging from 10% by weight to 70% by weight, based on the total weight of the monomers used to produce the emulsion-polymerized latex copolymer.
8. The method of claim 7 , wherein the concentration of the one or more non-cyclic (meth)acrylates ranges from about 20% by weight to about 60% by weight, based on the total weight of the monomers used to produce the emulsion-polymerized latex copolymer.
9. The method of claim 8 , wherein the concentration of the one or more non-cyclic (meth)acrylates ranges from about 30% by weight to about 50% by weight, based on the total weight of the monomers used to produce the emulsion-polymerized latex copolymer.
10. The method of claim 2 , wherein the one or more first ethylenically-unsaturated monomers further comprise one or more polymerizable surfactants.
11. The method of claim 2 , wherein the one or more first ethylenically-unsaturated monomers further comprise one or more multi-functional monomers having two or more ethylenically-unsaturated groups.
12. The method of claim 2 , wherein the one or more ethylenically-unsaturated, polycyclic monomers constitute at least 10% by weight of the monomers used to produce the emulsion-polymerized latex copolymer.
13. The method of claim 2 , wherein the one or more ethylenically-unsaturated, monocyclic monomers constitute at least 10% by weight of the monomers used to produce the emulsion-polymerized latex copolymer.
14. The method of claim 2 , wherein the coating has a glass transition temperature greater than 50° C.
15. The method of claim 2 , wherein the coating gives a global extraction of less than 10 parts-per-million, pursuant to the Global Extraction test, and wherein the coating composition is substantially free of halogenated compounds.
16. The method of claim 2 , wherein the coating composition is spray applied onto an interior surface of an aluminum beverage can including a body portion and a bottom end portion, and where the cured coating has a coating thickness ranging of from about 0.7 milligrams/square-inch (mg/inch 2 ) to about 2.5 mg/inch 2 .
17. The method of claim 1 , wherein the coating composition has a resin solids content ranging from about 10% by weight to about 30% by weight, based on a total weight of the coating composition.
18. The method of claim 1 , wherein the concentration of the one or more ethylenically-unsaturated, acid-functional monomers ranges from 5% by weight to 20% by weight, based on the total weight of the monomers used to produce the emulsion-polymerized latex copolymer.
19. The method of claim 1 , wherein the combined concentration of (i) and (ii) constitutes at least 30% by weight of the monomers used to produce the emulsion-polymerized latex copolymer.
20. The method of claim 1 , wherein the one or more ethylenically-unsaturated, polycyclic monomers constitute at least 30% by weight of the monomers used to produce the emulsion-polymerized latex copolymer.
21. The method of claim 1 , wherein the one or more ethylenically-unsaturated, polycyclic monomers are selected from the group consisting of isobornyl (meth)acrylate), norbornane (meth)acrylate, norbornene (meth)acrylate, norbornadiene, tricyclodecenyl (meth)acrylate, isosorbide (meth)acrylate, tricyclodecane (meth)acrylate, bicyclo[4.4.0]decane (meth)acrylate, vinyl variations thereof, and mixtures thereof.
22. The method of claim 1 , wherein the glass transition temperature of the coating ranges from about 60° C. to about 120° C.
23. The method of claim 1 , wherein the coating composition exhibits a change in viscosity, if any, of less than about 25% pursuant to the Pot Life Stability test.
24. An article comprising a food or beverage container, or a portion thereof, including:
a metal substrate; and
an inside spray coating disposed on at least a portion of the metal substrate, wherein the coating is produced from an inside-spray coating composition having an emulsion-polymerized latex copolymer that is a reaction product of monomers comprising:
one or more first ethylenically-unsaturated monomers each having one or more ethylenically-unsaturated groups; and
one or more styrene offset monomers comprising:
(i) one or more ethylenically-unsaturated, polycyclic monomers;
(ii) one or more ethylenically-unsaturated, monocyclic monomers each having a ring structure with 3-5 atoms in the ring; or
combinations thereof,
wherein a combined concentration of (i) and (ii) constitutes at least about 10% by weight of the monomers used to produce the emulsion-polymerized latex copolymer;
wherein the monomers used to produce the emulsion-polymerized latex copolymer are substantially free of BPA, PVC, halogenated monomers, and styrene.
25. An inside spray coating composition comprising:
an aqueous carrier; and
an emulsion-polymerized latex copolymer dispersed in the aqueous carrier, and comprising:
one or more ethylenically-unsaturated monomers each having one or more ethylenically-unsaturated groups; and
one or more styrene offset monomers comprising:
(i) one or more ethylenically-unsaturated, polycyclic monomers;
(ii) one or more ethylenically-unsaturated, monocyclic monomers each having a ring structure with 3-5 atoms in the ring; or
combinations thereof,
wherein a combined concentration of (i) and (ii) constitutes at least about 10% by weight of the monomers used to produce the emulsion-polymerized latex copolymer;
wherein the monomers used to produce the emulsion-polymerized latex copolymer are substantially free of BPA, PVC, halogenated monomers, and styrene;
wherein the coating composition has an average viscosity ranging from about 5 seconds to about 40 seconds, pursuant to the Viscosity Test; and
wherein the coating composition has a resin solids content ranging from about 10% by weight to about 30% by weight, based on a total weight of the coating composition.