Grain-oriented electrical steel plate and production method therefor
Provided is an oriented electrical steel sheet including a groove existing on the surface of the electrical steel sheet and a forsterite layer formed on a part or all of the surface of the electrical steel sheet, in which forsterite which is extended from the forsterite layer and penetrates to a base steel sheet in an anchor form is present on the surface of the side of the groove.
1. An oriented electrical steel sheet comprising:
a groove existing on a surface of the electrical steel sheet;
a forsterite layer formed on a part or all of the surface of the electrical steel sheet; and
an insulation coating layer formed on the forsterite layer,
wherein two or more forsterite anchors having a 3D network structure which is formed on a base steel sheet are present within 50 μm from a surface of a side of the groove,
wherein the insulation coating layer is formed directly on an inner surface of the groove,
wherein a width of the forsterite anchor having the 3D network structure which is formed to the base steel sheet is 3.5 μm or less, and
wherein the 3D network structure has a vertical portion and a horizontal portion extended from the vertical portion, and the horizontal portion is in the same direction as the X-Y plane of the forsterite layer, where X is a direction of width of the forsterite layer and Y is length of the forsterite layer.
2. The oriented electrical steel sheet of claim 1 , wherein:
the forsterite anchor having the 3D network structure which is formed to the base steel sheet has a length of ⅓ or more of a mean thickness of the forsterite layer.
3. The oriented electrical steel sheet of claim 2 , wherein:
a length in a thickness direction of the electrical steel sheet of the forsterite anchor having the 3D network structure which is formed to the base steel sheet is 0.3 to 10 μm.
4. The oriented electrical steel sheet of claim 1 , wherein:
when a rolling direction of the electrical steel sheet is referred to as an x axis, a width direction of the electrical steel sheet is referred to as a y axis, a normal direction of an xy plane is referred to as a z axis, and the forsterite anchor having the 3D network structure which is formed to the base steel sheet is observed in an xz plane, the forsterite anchor has a hook shape or an anchor shape.
5. The oriented electrical steel sheet of claim 4 , wherein:
a mean thickness of the forsterite layer is 0.1 μm to 3 μm.
6. The oriented electrical steel sheet of claim 5 , wherein:
the insulation coating layer includes silicate and metal phosphate, and
the insulation coating layer includes 25 wt % or more of Mg or Al based on the weight of the insulation coating layer.
7. The oriented electrical steel sheet of claim 6 , wherein:
a depth of the groove is 3% to 10% of the thickness of the electrical steel sheet.
8. The oriented electrical steel sheet of claim 7 , wherein:
an angle between the groove and a width direction of the steel sheet is parallel or more than 0° and 5° or less.
9. A manufacturing method of an oriented electrical steel sheet according to claim 1 , comprising:
manufacturing a cold-rolled steel sheet by heating at 1300° C. or less, hot-rolling, and then cold-rolling a slab including O: 0.0020 to 0.0080 wt % and a remainder of Fe and impurities based on the entire composition 100 wt % of the slab;
subjecting the cold-rolled steel sheet to primary recrystallization annealing;
applying an annealing separator containing MgO to the steel sheet subjected to the primary recrystallization annealing and subjecting the steel sheet to secondary recrystallization annealing; and
refining a magnetic domain by forming the groove on the steel sheet, wherein the refining of the magnetic domain is performed after the manufacturing of the cold-rolled steel sheet, after the primary recrystallization annealing is completed, or after the secondary recrystallization annealing is completed, and
a weight ratio of SiO 2 /Fe 2 SiO 4 of an oxide layer on the surface of the steel sheet formed in the primary recrystallization annealing process is 0.1 to 1.5,
wherein the forsterite coating and the insulation coating are sequentially formed on the surface of the electrical steel sheet, and the forsterite coating is integrally extended in a lower direction of the electrical steel sheet and penetrates to form the two or more forsterite anchors having the 3D network structure.
10. The manufacturing method of an oriented electrical steel sheet of claim 9 , wherein:
the primary recrystallization annealing is performed in a dew point atmosphere of 60 to 70° C. (50% N 2 +50% H 2 ) in a temperature range of 800 to 890° C.
11. The manufacturing method of an oriented electrical steel sheet of claim 10 , wherein:
an oxygen amount of the oxygen layer on the surface of the steel sheet formed in the primary recrystallization annealing process is in a range of 600 to 1,000 ppm.
12. The manufacturing method of an oriented electrical steel sheet of claim 9 , wherein:
the annealing separator is applied with 2.5 to 12 g/m 2 per side of the steel sheet in a slurry form by containing MgO as a main component and mixing a Ti compound, a Cl compound, a sulfide, a boride, a nitride, or an oxide as a reaction promoter singly or in plural therein,
MgO as the main component of the annealing separator has a mean powder particle diameter of 2.5 μm or less, and
MgO as the main component of the annealing separator having a mean powder particle diameter of 2 μm or less is 10% or more.
13. The manufacturing method of an oriented electrical steel sheet of claim 9 , wherein:
the secondary recrystallization annealing is performed by dividing a primary cracking process at 550 to 750° C. and a secondary cracking process at 1,000 to 1,250° C., and during temperature rising, the temperature rises to 30 to 100° C. per hour in a temperature section of 650 to 950° C. and rises to 45° C. or less per hour in a temperature section of 950 to 1250° C.
14. The manufacturing method of an oriented electrical steel sheet of claim 13 , wherein:
in the secondary recrystallization annealing, the primary cracking time is 10 minutes or more and the secondary cracking time is 8 hours or more.
15. The manufacturing method of an oriented electrical steel sheet of claim 14 , wherein:
the secondary recrystallization annealing is performed in a mixed atmosphere of nitrogen and hydrogen up to the secondary cracking temperature and performed in a hydrogen atmosphere after reaching the secondary cracking temperature.
16. The manufacturing method of an oriented electrical steel sheet of claim 9 , wherein:
the refining of the magnetic domain is performed by irradiating a continuous wave laser in a Gaussian beam form.
17. The manufacturing method of an oriented electrical steel sheet of claim 16 , further comprising:
insulation-coating with an insulation coating solution containing colloidal silica and metal phosphate on the steel sheet after the refining of the magnetic domain,
the metal phosphate in the insulation coating solution is Al phosphate, Mg phosphate, or a combination thereof, and the content of Al, Mg, or a combination thereof with respect to the weight of the insulation coating solution is 15 wt % or more.
18. The manufacturing method of an oriented electrical steel sheet of claim 9 , wherein:
the slab further includes Si: 2.5 to 4.0 wt %, C: 0.02 to 0.10 wt %, Al: 0.02 to 0.04 wt %, Mn: 0.05 to 0.20 wt %, N: 0.002 to 0.012 wt %, S: 0.001 wt % to 0.010 wt % and P: 0.01 to 0.08 wt % based on the entire composition 100 wt % of the slab.