IP Library Granted Patent US 10,435,493
Granted Patent B2
US 10,435,493 · App. 15/540,138 · Granted Oct 8, 2019

Multimodal polyethylene

Inventors: Andrey Buryak (Abu Dhabi, AE); Ashish Kumar (Abu Dhabi, AE); Ibrahim Ali Ahmed (Abu Dhabi, AE)
Assignees: Abu Dhabi Polymers Company Limited (Borouge) LLC; Borealis AG
C08F210/16C08L23/06C08L23/0815H01B3/441H01B7/02C08L2203/202C08L2205/025C08L2314/02H01B11/002H01B11/02H01B11/18
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Quick Facts
Patent No.
US 10,435,493
App. No.
15/540,138
Granted
Oct 8, 2019
Kind
B2
Abstract

A multimodal polyethylene copolymer suitable for use in cable insulation comprising: (III) 45 to 55 wt % of a lower molecular weight component which is an ethylene copolymer of ethylene and at least one C3-12 alpha olefin comonomer, said LMW component having a density of 940 to 962 kg/m 3 and an MFR 2 of 50 to 500 g/10 min; (IV) 55 to 45 wt % of a higher molecular weight ethylene copolymer component of ethylene and at least one C3-12 alpha olefin comonomer; wherein said multimodal polyethylene copolymer has a density of 940 to 950 kg/m 3 , an MFR 2 of 0.05 to 2.0 g/10 min and preferably at least one of crystallization half time>3.0 mins at 120.5° C., a crystallization half time>5.0 mins at 121° C. or a crystallization half time>10.0 mins at 122° C.

Claims (32)

1. A multimodal polyethylene copolymer suitable for use in cable insulation comprising:

(I) 45 to 55 wt % of a lower molecular weight component which is an ethylene copolymer of ethylene and at least one C3-12 alpha olefin comonomer, said LMW component having a density of 940 to 962 kg/m 3 and an MFR 2 of 50 to 500 g/10 min;

(II) 55 to 45 wt % of a higher molecular weight ethylene copolymer component of ethylene and at least one C3-12 alpha olefin comonomer;

wherein said multimodal polyethylene copolymer has a density of 940 to 950 kg/m 3 , an MFR 2 of 0.05 to 2.0 g/10 min and at least one of a crystallization half time>3.0 mins at 120.5° C., a crystallization half time>5.0 mins at 121° C. or a crystallization half time>10.0 mins at 122° C., when measured according to ISO 11357-7.

2. A multimodal polyethylene copolymer as claimed in claim 1 having a density of 942 to 948 kg/m 3 .

3. A multimodal polyethylene copolymer as claimed in claim 1 having an MFR 2 of 0.2 to 2.0 g/10 min.

4. A multimodal polyethylene copolymer as claimed in claim 1 prepared using a Ziegler Natta catalyst.

5. A multimodal polyethylene copolymer as claimed in claim 1 wherein said HMW copolymer component comprises at least one of 1-butene, 1-hexene and 1-octene.

6. A multimodal polyethylene copolymer as claimed in claim 1 having 47 to 53 wt % of a HMW component (II) and 53 to 47 wt % LMW component (I).

7. A multimodal polyethylene copolymer as claimed in claim 1 having a shear thinning index (SHI 5.0/300) in the range of 20.0 to 50.0.

8. A multimodal polyethylene copolymer as claimed in claim 1 wherein said LMW polymer is a copolymer with the comonomer 1-butene.

9. A multimodal polyethylene copolymer as claimed in claim 1 having at least two of

(i) a crystallization half time>3.0 mins at 120.5° C.,

(ii) a crystallization half time>5.0 mins at 121° C. or

(iii) a crystallization half time>10.0 mins at 122° C.

10. A multimodal polyethylene copolymer as claimed in any preceding claim having wherein the LMW component has an MFR 2 of 200 to 400 g/10 min.

11. A multimodal polyethylene copolymer as claimed in claim 1 wherein the LMW component has a density of 950 to 962 kg/m 3 .

12. A multimodal polyethylene copolymer as claimed in claim 1 wherein the copolymer has a petroleum jelly adsorption of 5.0 to 9.0 wt %.

13. A cable comprising a conductor surrounded by an insulation layer comprising a copolymer as claimed in claim 1 .

14. A cable as claimed in claim 13 further comprising at least one filler.

15. A cable as claimed in claim 13 which is a data cable or telecommunications cable.

16. A multimodal polyethylene copolymer as claimed in claim 1 having a density of 943 to 947 kg/m 3 .

17. A multimodal polyethylene copolymer as claimed in claim 1 having an MFR 2 of 0.5 to 1.5 g/10 min.

18. A multimodal polyethylene copolymer as claimed in claim 1 having a shear thinning index (SHI 5.0/300) in the range of 25.0 to 45.0.

19. A multimodal polyethylene copolymer as claimed in claim 9 having all of

(i) a crystallization half time>3.0 mins at 120.5° C.,

(ii) a crystallization half time>5.0 mins at 121° C. or

(iii) a crystallization half time>10.0 mins at 122° C.

20. A multimodal polyethylene copolymer as claimed in claim 9 having a crystallization half time>11.5 mins at 122° C.

21. A multimodal polyethylene copolymer as claimed in claim 1 wherein the copolymer has a petroleum jelly adsorption of 5.5 to 8.5 wt %.

22. A cable as claimed in claim 13 , wherein said insulation layer is adjacent said conductor.

23. A cable as claimed in claim 14 wherein said filler is petroleum jelly.

Assignments (3)
CHANGE OF ADDRESS Recorded Feb 23, 2022
From: BOREALIS AG
To: BOREALIS AG
Reel/Frame 059219/0949 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 8, 2017
From: BURYAK, ANDREY; KUMAR, ASHISH; AHMED, IBRAHIM ALI
To: ABU DHABI POLYMERS COMPANY LIMITED (BOROUGE) LLC
Reel/Frame 043234/0007 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 8, 2017
From: BURYAK, ANDREY; KUMAR, ASHISH; AHMED, IBRAHIM ALI
To: BOREALIS AG
Reel/Frame 043234/0106 →
Priority Claims (1)
EP 14200665 · Dec 30, 2014 · regional
Continuity (1)
Related Publication 20170349685A1 · Dec 7, 2017