METHOD FOR FLUIDIZING COPPER SILICIDE AND PROCESS FOR PREPARING A HALOSILANE USING THE METHOD
A method is useful for maintaining a uniformly fluidized bed in a fluidized bed apparatus. The method includes the steps of charging a mixture of particles including copper silicide particles and fluidization additive particles into the fluidized bed apparatus, and uniformly fluidizing the particles at a temperature of at least 400° C. in the fluidized bed apparatus.
1 . A method maintaining a uniformly fluidized bed in a fluidized bed apparatus comprises:
(A) heating, at a temperature of at least 400° C., a mixture of particles comprising greater than 80 weight % to less than 100% copper silicide particles and greater than 0 to 20 weight % fluidization additive particles in the fluidized bed apparatus, and
(B) feeding a fluid into the fluidized bed apparatus at a velocity sufficient to maintain uniform fluidization.
2 . The method of claim 1 , where the copper silicide particles have a particle size of 10 μm to 150 μm.
3 . The method of claim 1 , where the additive particles are present in an amount of greater than 0 weight % to 10 weight %, based on total weight of the mixture.
4 . The method of claim 1 , where the copper silicide particles are present in an amount of 95 weight % to 98 weight % of the mixture, and the fluidization additive particles are present in an amount of 2 weight % to 5 weight % of the mixture.
5 . The method of claim 1 , where the copper silicide is selected from the group consisting of (i) Cu 7 Si, (ii) Cu 5 Si, (iii) Cu 4 Si, and (iv) Cu 3 Si, and a mixture of two or more of (i), (ii), (iii), (iv).
6 . The method of claim 1 , where the copper silicide comprises Cu 5 Si.
7 . The method of claim 1 , where the copper silicide has empirical formula Cu b Si c Cr d Co e Fe f Ir g Ni h Pd i Pt j Re k Ru m , where subscripts b, c, d, e, f, g, h, i, j, k, and m represent the molar amounts of each element present, and b>0, c>0, d≧0, e≧0, f≧0, g≧0, h≧0, i≧0, j≧0, k≧0, and m≧0; with the provisos that at least one of d, e, f, g, h, l, j, k and m is not 0.
8 . The method of claim 1 , where the fluidization additive particles are selected from the group consisting of silicon particles, silica particles and silicon carbide particles.
9 . The method of claim 8 , where the fluidization additive particles are silica particles.
10 . The method of claim 8 , where the fluidization additive particles are silicon carbide particles.
11 . The method of claim 1 , where the temperature in step (B) is at least 500° C.
12 . The method of claim 11 , where the temperature in step (B) is 500° C. to 750° C.
13 . The method of claim 1 , where the temperature in step (B) is 400° C. to 750° C.
14 . The method of claim 1 , where the method is used in a process for preparing a halosilane.