Integrated electrode assembly and electrochemical device comprising same
The present disclosure relates to an integrated electrode assembly, wherein a positive electrode, a first binder polymer layer, an inorganic coating layer comprising a plurality of inorganic layers and a second binder polymer, a third binder polymer layer, and a negative electrode are sequentially stacked and combined, each configurative element forming the electrode assembly is stacked and combined with excellent adhesion, and the durability of the inorganic coating layer preventing the internal short circuit of the electrode is excellent, and thus a lithium secondary battery using the integrated electrode assembly according to the present disclosure may have excellent cycle characteristics.
1. A method for manufacturing an integrated electrode assembly, the method comprising:
coating an a first binder polymer solution on a release film, wherein the first binder polymer solution consists of a first binder polymer and a solvent;
drying the first binder polymer solution to form a first binder polymer layer on the release film;
coating a slurry on the first binder polymer layer, wherein the slurry including a plurality of inorganic particles and a second binder polymer;
drying the slurry to form an inorganic coating layer on the first binder polymer layer, wherein the inorganic coating layer includes interstitial volumes formed between the inorganic particles, and wherein the plurality of inorganic particles are bound to each other by the second binder polymer in the inorganic coating layer;
coating a third binder solution on the inorganic coating layer, wherein the third binder polymer solution includes a third binder polymer and a solvent;
drying the third binder solution to form a third binder polymer layer on the inorganic coating layer;
laminating the third binder polymer layer to a first electrode active material layer of a first electrode, the first electrode including the first electrode active material layer disposed on a first current collector; and
removing the release film attached to the first binder polymer layer; and
laminating the first binder polymer layer to a second active material layer of a second electrode, the second electrode including the second electrode active material layer disposed on a second current collector,
where the solvent of the first and third binder solution is selected from the group consisting of acetone, tetrahydrofuran, methylene chloride, chloroform, dimethylformamide, N-methyl-2-pyrrolidone (NMP), cyclohexane, water, or a mixture thereof.
2. A method for manufacturing a separator integrated electrode assembly, the method comprising:
coating a slurry on a release film, wherein the slurry consists of a plurality of inorganic particles, a second binder polymer, and a solvent;
drying the slurry to form an inorganic coating layer on the release film, wherein the inorganic coating layer includes interstitial volumes formed between the inorganic particles, and wherein the plurality of inorganic particles are bound to each other by the second binder polymer in the inorganic coating layer;
removing the release film from the inorganic coating layer;
coating a first binder polymer solution on a first surface of the inorganic coating layer, wherein the first binder polymer solution includes a first binder polymer and a solvent;
drying the first binder polymer solution to form a first binder polymer layer on the first surface of the inorganic coating layer;
coating a third binder polymer solution on a second surface of the inorganic coating layer, wherein the second surface is opposite of the first surface, and wherein the third binder polymer solution includes a third binder polymer and a solvent;
drying the third binder polymer solution to form a third binder polymer layer on the second surface of the inorganic coating layer;
laminating the first binder polymer layer to a first active material layer of a first electrode, the first electrode including the first electrode active material layer disposed on a first current collector; and
laminating the third binder polymer layer to a second electrode active material layer of a second electrode, the second electrode including the second electrode active material layer disposed on a second current collector,
where the solvent of the first and third binder solution is selected from the group consisting of acetone, tetrahydrofuran, methylene chloride, chloroform, dimethylformamide, N-methyl-2-pyrrolidone (NMP), cyclohexane, water, or a mixture thereof.
3. The method for manufacturing a separator integrated electrode assembly of claim 2 , wherein the first binder polymer solution and the third binder polymer solution are the same solution, and wherein the coating of the first and second surfaces of the inorganic coating layer is performed simultaneously by dip coating.
4. The method of claim 2 , where the solvent of the slurry is water.
5. The method of claim 2 , wherein the first binder polymer solution consists of the first binder polymer and the solvent, and wherein the third binder polymer solution consists of the third binder polymer and the solvent.
6. The method of claim 1 , wherein the third binder polymer solution consists of third binder polymer solution and the solvent.