Laser welding member, and molded article
A laser welding member that has a high laser transmittance at a welding region and exhibits an excellent laser welding processability, and a molded article obtained by laser welding using this laser welding member. The laser welding member is obtained by injection molding of a thermoplastic polyester resin material, wherein a region to be laser welded in the member is at a location separated by a distance of at least 15 mm from a gate of an injection molding mold and has at least 30% of a light transmittance of laser light with a wavelength of 940 nm.
1. A method of producing a laser-welded molded article, the method comprising:
laser welding a first laser welding member obtained by injection molding a thermoplastic polyester resin material, with a second member comprising a laser-absorptive resin material by irradiation with laser light from a side of the first laser welding member,
wherein
the thermoplastic polyester resin material of the first laser welding member comprises a polybutylene terephthalate resin, polystyrene and/or butadiene rubber-containing polystyrene, and a polycarbonate resin, and a content of the polybutylene terephthalate resin is from 30 to 90 mass %, a content of the polystyrene and/or butadiene rubber-containing polystyrene is from 1 to 50 mass %, and a content of the polycarbonate resin is from 1 to 50 mass %, based on 100 mass % for a total of the polybutylene terephthalate resin, the polystyrene and/or butadiene rubber-containing polystyrene, and the polycarbonate resin,
the second member comprises a thermoplastic polyester resin composition comprising a carbon black or a laser light-absorbing dye,
a region to be laser welded in the first member is at a location separated by a distance of at least 15 mm from a gate of an injection molding mold and has at least 50% of a light transmittance of laser light with a wavelength of 940 nm, and
a crystallization temperature (Tc) of the region to be laser welded in the first member is not more than 188° C.
2. The method according to claim 1 , wherein the thermoplastic polyester resin composition of the second member comprises a thermoplastic polyester resin, and at least 50 mass % of the thermoplastic polyester resin is a polybutylene terephthalate resin.
3. The method according to claim 1 , wherein the thermoplastic polyester resin material of the first member and the second member further comprise a glass fiber.
4. The method according to claim 1 , wherein the thermoplastic polyester resin material of the first laser welding member is injection molded under a condition of 10 to 300 cm 3 /sec for an injection ratio, wherein the injection ratio is defined as a volume of a resin material injected per unit time into a mold cavity from an output nozzle of an injection molding machine.
5. The method according to claim 4 , wherein the thermoplastic polyester resin material of the first laser welding member is injection molded under a condition of 100 to 1200 cm 3 /sec·cm for a surface advance coefficient, wherein the surface advance coefficient is defined as a value obtained by dividing the injection ratio by a thickness of the mold cavity into which the resin material is injected.
6. The method according to claim 1 , wherein a melt volume rate, measured under a condition of 250° C. and a load of 5 kg, of the thermoplastic polyester resin material of the first laser welding member is at least 10 cm 3 /10 min.
7. The method according to claim 1 , wherein the gate is a film gate.