Polycrystalline diamond cutters having non-catalytic material addition and methods of making the same
View Patent ↗Polycrystalline diamond cutters for rotary drill bits and methods of making the same are disclosed. Polycrystalline diamond cutters include a support substrate and a polycrystalline diamond body coupled to the support substrate. The polycrystalline diamond body includes a plurality of diamond grains exhibiting inter-diamond bonding therebetween and defining a plurality of interstitial regions, a non-catalytic material distributed throughout the polycrystalline diamond body in a detectable amount, and a catalytic material distributed throughout the polycrystalline diamond body in a detectable amount.
1. A method of producing a polycrystalline diamond cutter, comprising:
combining diamond particles with a non-catalytic material to distribute the non-catalytic material with the diamond particles;
assembling a cell assembly comprising
diamond particles and non-catalytic material positioned within a cup,
a catalytic material source, the catalytic material source positioned proximate to the diamond particles and the non-catalytic material, and
pressure transferring medium surrounding the cup and the catalytic material source;
subjecting the formation cell assembly and its contents to a first high pressure high temperature process to sinter the diamond particles in inter-diamond bonds and to form a polycrystalline diamond body having entrained non-catalytic material attached to the catalytic material source;
de-attaching the catalytic material source from the polycrystalline diamond body;
leaching substantially all accessible catalytic material from the polycrystalline diamond body such that after leaching the polycrystalline diamond body exhibits a gradient of the non-catalytic material between opposing sides of the polycrystalline diamond body;
providing a support substrate that optionally comprises the catalytic material source; and
subjecting the support substrate and the polycrystalline diamond body to a second high pressure high temperature process to bond the polycrystalline diamond body to the support substrate such that the polycrystalline diamond body is attached to the support substrate at a side of the polycrystalline diamond body having a higher concentration of the non-catalytic material.
2. The method of claim 1 , wherein the non-catalytic material combined with the diamond particles is provided in a powdered form.
3. The method of claim 1 , wherein the non-catalytic material is present in the cell assembly in an amount from 0.09 vol. % to 11.1 vol. % of the diamond particles.
4. The method of claim 1 , wherein following the first high pressure high temperature process and prior to the leaching process, the non-catalytic material is present in the polycrystalline diamond body in an amount from 0.09 vol. % to 1.1 vol. % of the polycrystalline diamond body, and the catalytic material is present in an amount from 3.6 vol. % to 11 vol. % of the polycrystalline diamond body.
5. The method of claim 1 , wherein following the leaching process, the non-catalytic material is present in the polycrystalline diamond body in an amount from 0.09 vol. % to 1.1 vol. % of the polycrystalline diamond body, and the catalytic material is present in an amount from 0.9 vol. % to 3.3 vol. % of the polycrystalline diamond body.
6. The method of claim 1 , wherein the first high pressure high temperature conditions are in a range from 3.6 GPa to 11 GPa and in a range from 900° C. to 1760° C.
7. The method of claim 1 , wherein the support substrate comprises cemented tungsten carbide having an intergranular phase liquidus temperature below 1300° C. at high pressure conditions.
8. The method of claim 1 , wherein after the second high pressure high temperature process when the polycrystalline diamond body is sintered to the support substrate, the polycrystalline diamond body is partially infiltrated with additional catalytic material from the support substrate.
9. The method of claim 1 , further comprising leaching accessible non-catalytic material from the polycrystalline diamond body, wherein non-accessible catalytic material and non-accessible non-catalytic material are present after leaching.