Cellulose-based multilayer separator
View Patent ↗The present invention relates to a separator for a secondary battery which is capable of improving a shut-down function of a cellulose-based multilayer separator physically having high strength. The separator for a secondary battery comprises a substrate formed of cellulose-based nanofibers and polyethylene nanoparticles; and a resin layer stacked on one surface or both surfaces of the substrate, the resin being formed from a polyolefin.
1. A separator for a secondary battery, comprising:
a substrate comprising cellulose-based nanofiber and polyethylene nano particles,
wherein the cellulose-based nanofiber and polyethylene nano particles are a homogenous mixture; and
a resin layer stacked on both surfaces of the substrate, the resin being formed from a polyolefin,
wherein the cellulose-based nanofiber and the polyethylene nano particles are present in a weight ratio of 7:3 to 9:1.
2. The separator of claim 1 , wherein the polyolefin is at least one selected from a group consisting of polyethylene, polypropylene, polybutylene and polypentene.
3. The separator of claim 1 , wherein the polyethylene nano particles have a melting point of 80 to 100° C., and the polyolefin resin has a melting point of 100 to 140° C.
4. The separator of claim 1 , wherein the resin layer further comprises inorganic particles and a polymeric binder.
5. The separator of claim 1 , wherein the resin layer is stacked in a lamination method.
6. The separator of claim 1 , wherein the resin layer has a thickness of 3 to 20 μm, and the substrate has a thickness of 5 to 20 μm.
7. The separator of claim 1 , wherein the cellulose-based nanofiber is made of any one selected from a group consisting of cellulose acetate, cellulose triacetate and cellulose butylate.
8. The separator of claim 1 , wherein the cellulose-based nanofiber has a diameter of 10 nm to 500 nm and a length of 1 μm to 10 mm, and the polyethylene nano particle has a particle size of 50 nm to 500 nm.
9. A method of preparing a separator for a secondary battery, the method comprising:
forming a sheet using a homogenous mixture of a cellulose nanofiber and polyethylene nano particles dispersed in a solvent;
removing the solvent to provide a porous substrate; and
stacking a resin layer formed from a polyolefin on both surfaces of the substrate in a lamination method,
wherein the cellulose-based nanofiber and the polyethylene nano particles are present in a weight ratio of 7:3 to 9:1.
10. The method of claim 9 , wherein the solvent comprises a resin for forming pores and at least one selected from a group consisting of water, methyl alcohol, ethyl alcohol, propyl alcohol, acetone, ethyl acetate, methyl ethyl ketone and toluene, to which is added.
11. The method of claim 10 , wherein the resin for forming pores is at least one selected from a group consisting of polyethylene glycol, polyvinyl alcohol and polyvinyl propylene.