Sintering material, and powder for manufacturing sintering material
The present invention is a sintering material including a granule, the sintering material having an apparent tap density of 1.0 to 2.5 g/cm 3 , a 50% cumulative volume particle diameter (D 50N ) of 10 to 100 μm as measured before ultrasonication by laser diffraction/scattering particle size distribution analysis, a 50% cumulative volume particle diameter (D 50D ) of 0.1 to 1.5 μm as measured after ultrasonication at 300 W for 15 minutes by laser diffraction/scattering particle size distribution analysis, and an X-ray diffraction pattern in which the maximum peak observed in the 2θ angle range of from 20° to 40° is assigned to a rare earth oxyfluoride of the form LnOF when analyzed by X-ray diffractometry using Cu—Kα or Cu—Kα 1 rays.
1. A sintering material comprising a granule containing a rare earth oxyfluoride (Ln-O—F),
and having an apparent tap density of 1.0 to 2.5 g/cm 3 , a 50% cumulative volume particle diameter (D 50N ) of 10 to 100 am as measured before ultrasonication by laser diffraction/scattering particle size distribution analysis, a 50% cumulative volume particle diameter (D 50D ) of 0.1 to 1.5 μm as measured after ultrasonication at 300 W for 15 minutes by laser diffraction/scattering particle size distribution analysis, and an X-ray diffraction pattern in which the maximum peak observed in the 2θ angle range of from 20° to 40° is assigned to a rare earth oxyfluoride of the form LnOF when analyzed by X-ray diffractometry using Cu-Kα or Cu-Kα 1 rays, and
the sintering material having a ratio of the number of moles of oxygen (O) to the number of moles of the rare earth element (Ln) per kg of the sintering material, O/Ln molar ratio, of 0.85 to 1.10.
2. The sintering material according to claim 1 , further comprising an organic polymer binder.
3. The sintering material according to claim 2 , having a carbon content of 0.1 to 3 mass %.
4. The sintering material according to claim 1 , having a loss-on-drying of 0.1 to 1.0 mass % when dried at 120° C. for 1 hour.
5. The sintering material according to claim 2 , wherein the organic polymer binder contains at least one of a hydroxy group, a carbonyl group, and an ether linkage.
6. The sintering material according to claim 2 , wherein the organic polymer binder comprises one or more selected from the group consisting of polyvinyl alcohol, polyvinyl butyral, methyl cellulose, carboxymethyl cellulose, an acrylic binder, polyethylene glycol, and polyvinylpyrrolidone.
7. The sintering material according to claim 1 , wherein the rare earth element (Ln) is at least one of yttrium (Y), cerium (Ce), samarium (Sm), gadolinium (Gd), dysprosium (Dy), erbium (Er), and ytterbium (Yb).
8. The sintering material according to claim 7 , wherein the rare earth element (Ln) is yttrium (Y).
9. The sintering material according to claim 8 , having a ratio of the peak intensity (S 2 ) assigned to yttrium oxyfluoride of the form Y 5 O 4 F 7 observed in the 2θ angle range of from 31.8° to 32.8° to the maximum peak intensity (S 1 ) assigned to yttrium oxyfluoride of the form LnOF observed in the 2θ angle range of from 20° to 40°, S 2 /S 1 , of 0.2 or smaller in X-ray diffractometry using Cu-Kα or Cu-Kα 1 rays.
10. The sintering material according to claim 8 , having a ratio of the peak intensity (S 0 ) of yttrium oxide (Y 2 O 3 ) observed in the 2θ angle range of from 20.1° to 21.0° to the maximum peak intensity (S 1 ) of yttrium oxyfluoride of the YOF form observed in the 2θ angle range of from 20° to 40°, S 0 /S 1 , of 0.1 or less in X-ray diffractometry using Cu-Kα or Cu-Kα 1 rays.
11. A method for producing a sintered body, comprising sintering a granule containing a rare earth oxyfluoride (Ln-O—F),
the granule having an apparent tap density of 1.0 to 2.5 g/cm 3 , a 50% cumulative volume particle diameter (D 50N ) of 10 to 100 μm as measured before ultrasonication by laser diffraction/scattering particle size distribution analysis, a 50% cumulative volume particle diameter (D 50D ) of 0.1 to 1.5 μm as measured after ultrasonication at 300 W for 15 minutes by laser diffraction/scattering particle size distribution analysis, and an X-ray diffraction pattern in which the maximum peak observed in the 2θ angle range of from 20° to 40° is assigned to a rare earth oxyfluoride of the form LnOF when analyzed by X-ray diffractometry using Cu-Kα or Cu-Kα 1 rays, and
the granule having a ratio of the number of moles of oxygen (O) to the number of moles of the rare earth element (Ln) per kg of the granule, O/Ln molar ratio, of 0.85 to 1.10.