Positive electrode active material for secondary battery, and secondary battery including the same
View Patent ↗The present invention provides a positive electrode active material for a lithium secondary battery which is capable of preventing the degeneration of a positive electrode active material and the generation of a gas during operating a battery due to humidity, by including a surface treatment layer of an amorphous glass including an alkali metal oxide and an alkaline earth metal oxide on the surface of a core including a lithium composite metal oxide and by decreasing humidity reactivity, and a secondary battery including the same.
1. A positive electrode active material for a lithium secondary battery, the positive electrode active material comprising:
a core comprising a lithium composite metal oxide; and
a surface treatment layer positioned on a surface of the core,
wherein the surface treatment layer comprises an amorphous glass containing an alkali metal oxide and an alkaline earth metal oxide.
2. The positive electrode active material for a lithium secondary battery of claim 1 , wherein the amorphous glass is an alkaline-earth aluminosilicate comprising the alkali metal oxide, the alkaline earth metal oxide, SiO 2 , and Al 2 O 3 .
3. The positive electrode active material for a lithium secondary battery of claim 2 , wherein the alkaline-earth aluminosilicate comprises 1 to 30 parts by weight of the alkali metal oxide and 1 to 30 parts by weight of the alkaline earth metal oxide based on 100 parts by weight of a total amount of SiO 2 and Al 2 O 3 .
4. The positive electrode active material for a lithium secondary battery of claim 2 , wherein the alkaline-earth aluminosilicate comprises at least one selected from the group consisting of a SiO 2 —Al 2 O 3 —Na 2 O—CaO-based glass and a SiO 2 —Al 2 O 3 —Li 2 O—CaO-based glass.
5. The positive electrode active material for a lithium secondary battery of claim 1 , wherein the surface treatment layer comprises the amorphous glass comprising the alkali metal oxide and the alkaline earth metal oxide, the amorphous glass showing lithium ion conductivity of 10 −6 S/cm or more at 25° C.
6. The positive electrode active material for a lithium secondary battery of claim 1 , wherein the surface treatment layer is formed on a surface area of 25% or more and less than 100% among an entire surface area of the core.
7. The positive electrode active material for a lithium secondary battery of claim 1 , wherein the surface treatment layer is formed in an average thickness ratio of 0.01 to 0.1 with respect to a radius of the core.
8. The positive electrode active material for a lithium secondary battery of claim 1 , wherein the core comprises a lithium nickel manganese cobalt oxide.
9. The positive electrode active material for a lithium secondary battery of claim 8 , wherein the lithium nickel manganese cobalt oxide is doped with any one or at least two elements selected from the group consisting of W, Mo, Zr, Ti, Mg, Ta, Al, Fe, V, Cr, Ba, Ca, and Nb.
10. The positive electrode active material for a lithium secondary battery of claim 1 , wherein the core is secondary particles which are obtained by assembling first particles.
11. The positive electrode active material for a lithium secondary battery of claim 1 , wherein the core has an average particle diameter (D 50 ) of 1 μm to 20 μm.
12. The positive electrode active material for a lithium secondary battery of claim 1 , wherein a BET specific surface area is from 0.1 m 2 /g to 1.9 m 2 /g, and a tapped density is 1.5 g/cc or more.
13. A method of preparing the positive electrode active material for a lithium secondary battery according to claim 1 , the method comprising a step of mixing a core comprising a lithium composite metal oxide with an amorphous glass comprising an alkali metal oxide and an alkaline earth metal oxide, and heat treating at a temperature of 500° C. or less.
14. The method of preparing the positive electrode active material for a lithium secondary battery of claim 13 , further comprising a step of preparing the amorphous glass comprising the alkali metal oxide and the alkaline earth metal oxide by heat treating an alkali-aluminosilicate and the alkaline earth metal oxide prior to the step of mixing and heat treating.
15. A positive electrode for a secondary battery, comprising the positive electrode active material according to claim 1 .
16. A lithium secondary battery comprising the positive electrode according to claim 15 .
17. A battery module comprising the lithium secondary battery according to claim 16 as a unit cell.
18. A battery pack comprising the battery module according to claim 17 .
19. The battery pack of claim 18 , wherein the battery pack is used as a power source of a medium and large size device.
20. The battery pack of claim 19 , wherein the medium and large size device is selected from the group consisting of an electric vehicle, a hybrid electric vehicle, a plug-in hybrid electric vehicle and a power storage system.