Electrolysis system for carbon dioxide
The present disclosure relates to electrolysis systems and methods. The teachings thereof may be embodied in methods and systems for the utilization of carbon dioxide and production of carbon monoxide. For example, a method may include: passing an electrolyte and carbon dioxide in front of a cathode through a cathode chamber; and removing electrolysis byproducts from an electrolyte/electrolysis product mixture using a catalytic filter system. The cathode may include material to reduce carbon dioxide. The process may generate a hydrocarbon compound or carbon monoxide as the electrolysis product and a formate as an electrolysis byproduct. The filter system may include a functionalized complex or a functionalized support material which catalyzes a cleavage reaction of formates (a) to hydrogen and carbon dioxide, or (b) to water and carbon monoxide.
1. An electrolysis system for carbon dioxide utilization, the system comprising:
an electrolysis cell having an anode in an anode chamber, a cathode in a cathode chamber, and a filter unit;
wherein the cathode chamber takes up an electrolysis reactant comprising carbon dioxide and passes it in front of the cathode;
wherein the cathode comprises an electrode or catalyst material to reduce carbon dioxide to at least one of a hydrocarbon compound, carbon monoxide, or a formate; and
wherein the filter unit comprises a catalytic filter system with a catalyst material at least partially immobilized on a surface of the cathode;
wherein the catalyst material of the catalytic filter system is not electroreductively catalytically active; and
wherein the catalytic filter system includes a functionalized complex or a functionalized support material which catalyzes a cleavage reaction to convert any formate present to: (a) hydrogen and carbon dioxide, or (b) water and carbon monoxide.
2. The electrolysis system as claimed in claim 1 , wherein the reactable formate is of the type R+HCOO−where R+ is a cation selected from the group consisting of: H+, Li+, Na+, K+, NH4+, Cs+, Sr+, Ba+, Mn+, and Cu+.
3. The electrolysis system as claimed in claim 1 , wherein the catalytic filter system comprises transition metal complexes, including a metal from the eighth group of the periodic table or rhodium.
4. The electrolysis system as claimed in claim 1 , wherein the catalytic filter system comprises transition-metal-functionalized activated carbon or alumina as support materials.
5. The electrolysis system as claimed in claim 1 , wherein the catalytic filter system comprises 3-aminopropyltrimethoxysilane-functionalized zeolites.
6. The electrolysis system as claimed in claim 1 , comprising a gas diffusion electrode functioning as a formate filter.
7. The electrolysis system as claimed in claim 1 , wherein the cathode comprises lead.