Separator comprising adhesive coating parts having different tack strengths and electrode assembly comprising the same

1. A jelly-roll type electrode assembly, comprising:

a positive electrode in a sheet-like form;

a negative electrode in a sheet-like form; and

a separator which is interposed between the positive electrode and the negative electrode, and which comprises a first adhesive coating part and a second adhesive coating part formed on a first surface of a sheet-like porous substrate, and a third adhesive coating part formed on a second surface which is the opposite surface to the first surface,

wherein a first pressure sensitive adhesive used as the first adhesive coating part and a second pressure sensitive adhesive used as the second adhesive coating part have different tack strengths from each other,

wherein the adhesive in the first pressure sensitive adhesive and the adhesive in the second pressure sensitive adhesive are different from each other, and

wherein the adhesive in the first pressure sensitive adhesive is an acrylate-based pressure sensitive adhesive, and the adhesive in the second pressure sensitive adhesive is a fluorine-based pressure sensitive adhesive.

2. The electrode assembly according to claim 1 , wherein a surface area of the separator facing the positive electrode is larger than a surface area of the positive electrode facing the separator and a surface area of the separator facing the negative electrode is larger than a surface area of the negative electrode facing the separator.

3. The electrode assembly according to claim 1 , wherein the first adhesive coating part is wound in a state of being adhered on the surface opposite to the negative electrode, and the second adhesive coating part is wound by the separator itself while forming a winding tip of the electrode assembly.

4. The electrode assembly according to claim 1 , wherein the third adhesive coating part is wound in a state of being adhered onto the surface opposite to the positive electrode.

5. The electrode assembly according to claim 1 , wherein the electrode assembly is wound so that, based on the separator, the negative electrode is positioned on the inner surface side of the separator.

6. The electrode assembly according to claim 1 , wherein the first adhesive coating part has a higher tack strength as compared with the second adhesive coating part.

7. The electrode assembly according to claim 1 , wherein the fluorine-based pressure sensitive adhesive is polyvinylidene fluoride (PVdF).

8. The electrode assembly according to claim 1 , wherein the third adhesive coating part comprises a third pressure sensitive adhesive, and the third pressure sensitive adhesive is an acrylate-based pressure sensitive adhesive.

9. The electrode assembly according to claim 8 , wherein the third pressure sensitive adhesive is the same as the first pressure sensitive adhesive.

10. The electrode assembly according to claim 1 , wherein the first adhesive coating part, the second adhesive coating part, and the third adhesive coating part comprise inorganic particles and a pressure sensitive adhesive.

11. The electrode assembly according to claim 10 , wherein the first adhesive coating part, the second adhesive coating part, and the third adhesive coating part comprise 10 to 90% by weight of inorganic particles, based on the total weight of the respective parts.

12. The electrode assembly according to claim 1 , wherein the second adhesive coating part has a higher content of the inorganic particles as compared with the first adhesive coating part.

13. The electrode assembly according to claim 10 , wherein the inorganic particles comprises at least one selected from the group consisting of inorganic particles having piezoelectricity and inorganic particles having lithium ion transferring capability.

14. A secondary battery in which the electrode assembly according to claim 1 is embedded in a battery case together with an electrolytic solution.

15. A battery pack comprising the secondary battery according to claim 14 as a unit cell.

16. A device comprising the battery pack according to claim 15 as a power source.

17. A jelly-roll type electrode assembly, comprising:

a positive electrode in a sheet-like form;

a negative electrode in a sheet-like form; and

a separator which is interposed between the positive electrode and the negative electrode, and which comprises a first adhesive coating part and a second adhesive coating part formed on a first surface of a sheet-like porous substrate, and a third adhesive coating part formed on a second surface which is the opposite surface to the first surface,

wherein the first adhesive coating part and the second adhesive coating part have different tack strengths from each other,

wherein the first pressure sensitive adhesive is an acrylate-based pressure sensitive adhesive which is a polymer of a monomer mixture comprising i) 50 to 90% by weight of a (meth)acrylic acid ester monomer having an alkyl group having 1 to 14 carbon atoms, ii) 1 to 40% by weight of one or more monomers selected from the group consisting of allyl esters, vinyl esters, unsaturated acetate and unsaturated nitrile, and iii) 0.5 to 20% by weight of one or more monomers selected from the group consisting of unsaturated carboxylic acids, based on the total weight of the monomer mixture.

18. The electrode assembly according to claim 17 , wherein the monomer mixture further comprises a crosslinking agent, and the crosslinking agent is comprised in an amount of from 0.1 to 3% by weight based on the total weight of the monomer mixture.

19. A separator for a jelly-roll type electrode assembly, the separator comprising a first adhesive coating part and a second adhesive coating part formed on a first surface of a sheet-like porous substrate; and a third adhesive coating part formed on a second surface which is the opposite surface to the first surface,

wherein a first pressure sensitive adhesive used as the first adhesive coating part and a second pressure sensitive adhesive used as the second adhesive coating part have different tack strengths from each other,

wherein the adhesive in the first pressure sensitive adhesive and the adhesive in the second pressure sensitive adhesive are different from each other, and

wherein the adhesive in the first pressure sensitive adhesive is an acrylate-based pressure sensitive adhesive, and the adhesive in the second pressure sensitive adhesive is a fluorine-based pressure sensitive adhesive.

20. A method of preparing a jelly-roll type electrode assembly, comprising:

(a) a step of preparing a separator comprising a first adhesive coating part and a second adhesive coating part formed on a first surface of a sheet-like porous substrate, and a third adhesive coating part formed on a second surface which is the opposite surface to the first surface, wherein a first pressure sensitive adhesive used as the first adhesive coating part and a second pressure sensitive adhesive used as the second adhesive coating part with different tack strengths from each other,

wherein the adhesive in the first pressure sensitive adhesive and the adhesive in the second pressure sensitive adhesive are different from each other, and

wherein the adhesive in the first pressure sensitive adhesive is an acrylate-based pressure sensitive adhesive, and the adhesive in the second pressure sensitive adhesive is a fluorine-based pressure sensitive adhesive;

(b) a step of stacking a positive electrode, a separator and a negative electrode so that the first adhesive coating part is positioned to face the negative electrode and the third adhesive coating part is positioned to face the positive electrode through a winding process;

(c) winding the second adhesive coating part with a winding core brought in contact with the second adhesive coating part; and

(d) separating the jelly-roll type electrode assembly from the winding core.