Method for preparing (meth)acrylate group-containing benzophenone for optical adhesive use and optical adhesive composition
The present invention relates to a method for preparing a (meth)acrylate group-containing benzophenone for an optical adhesive use, the method including: preparing a raw material composition by mixing a hydroxy group-containing benzophenone-based compound and a (meth)acrylate-based compound; and carrying out a reaction of the hydroxy group-containing benzophenone-based compound and the (meth)acrylate-based compound by introducing an enzyme catalyst into the raw material composition. Further, the present invention provides an optical adhesive composition including a (meth)acrylate group-containing benzophenone prepared by the preparation method and a derivative thereof.
1. A method for preparing a (meth)acrylate group-containing benzophenone for an optical adhesive use, the method comprising:
preparing a raw material composition by mixing a hydroxy group-containing benzophenone-based compound and a (meth)acrylate-based compound; and
carrying out a reaction of the hydroxy group-containing benzophenone-based compound and the (meth)acrylate-based compound by introducing an enzyme catalyst into the raw material composition,
wherein the hydroxy group-containing benzophenone-based compound comprises one selected from the group consisting of 2-hydroxybenzophenone, 3-hydroxybenzophenone, 4-hydroxybenzophenone, 2-hydroxymethylbenzophenone, 3-hydroxymethylbenzophenone, 4-hydroxymethylbenzophenone, 2-hydroxyethylbenzophenone, 3-hydroxyethylbenzophenone, 4-hydroxyethylbenzophenone, 3-(1-hydroxyethyl)benzophenone, 4-(1-hydroxyethyl)benzophenone, and a combination thereof, and
wherein the raw material composition further includes one selected from the group consisting of an antioxidant, a polymerization inhibitor, and a combination thereof.
2. The method of claim 1 , wherein the (meth)acrylate-based compound comprises one selected from the group consisting of vinyl(meth)acrylate, allyl(meth)acrylate, alkyl(meth)acrylate, cycloalkyl(meth)acrylate, and a combination thereof.
3. The method of claim 1 , wherein the enzyme catalyst comprises lipase.
4. The method of claim 3 , wherein the enzyme catalyst comprises one selected from the group consisting of Candida antarctica B (CALB), Candida antarctica A (CALA), Candida rugosa lipase (CRL), Porcine pancreatic lipase (PPL), Pseudomonas cepacia lipase (PCL), Rhizomucor miehei lipase (RML), and a combination thereof.
5. The method of claim 1 , wherein the raw material composition comprises the (meth)acrylate-based compound in an amount of 1 mol to 1.5 mol based on 1 mol of the hydroxy group-containing benzophenone-based compound.
6. The method of claim 1 , wherein the enzyme catalyst is introduced in an amount of 0.1 part by weight to 10 parts by weight based on 100 parts by weight of the raw material composition.
7. The method of claim 1 , wherein the reaction is carried out at 30° C. to 90° C.
8. The method of claim 7 , wherein the reaction is carried out for 1 hour to 24 hours.
9. The method of claim 1 , wherein the reaction is carried out in the absence of a solvent other than the (meth)acrylate-based compound.