Process for preparing a polymerization inhibitor solution
View Patent ↗The invention relates to a process for preparing concentrated solutions of polymerization inhibitor, that can be used for the production, purification and storage of monomer compositions. This process comprises a step in which at least one polymerization inhibitor in the molten state is mixed with a solvent.
1. A process for preparing a polymerization inhibitor solution, comprising mixing at least one polymerization inhibitor in the molten state with a solvent, wherein the at least one polymerization inhibitor is selected from the group consisting of p-methoxyphenol, 4-tert-butylcatechol, pyrocatechol, hydroquinone, benzoquinone, 2,4-dimethyl-6-tert-butylphenol, phenothiazine, copper dibutyldithiocarbamate, and mixtures thereof and wherein the at least one polymerization inhibitor is kept in the molten state under an inert atmosphere.
2. The process according to claim 1 , wherein said at least one polymerization inhibitor consists of p-methoxyphenol.
3. The process according to claim 1 , wherein said solvent comprises an ethylenically unsaturated monomer.
4. The process according to claim 3 , wherein said solvent is selected from the group consisting of acrylic acid, methacrylic acid, methyl acrylate, ethyl acrylate, methyl methacrylate, acrylonitrile, acrolein, acrylamides, and mixtures thereof.
5. The process according to claim 1 , wherein the temperature of the at least one polymerization inhibitor in the molten state is greater than or equal to T m +10° C. and less than or equal to T m +100° C., wherein T m represents the melting point of the at least one polymerization inhibitor.
6. A process for preparing a polymerization inhibitor solution, comprising mixing at least one polymerization inhibitor in the molten state with a solvent, wherein the at least one polymerization inhibitor is selected from the group consisting of p-methoxyphenol, 4-tert-butylcatechol, pyrocatechol, hydroquinone, benzoquinone, 2,4-dimethyl-6-tert-butylphenol, phenothiazine, copper dibutyldithiocarbamate, and mixtures thereof, and wherein the mixing step comprises the introduction of the at least one polymerization inhibitor in the molten state into the solvent by means of a dip tube.
7. A process for preparing a polymerization inhibitor solution, comprising mixing at least one polymerization inhibitor in the molten state with a solvent, wherein the at least one polymerization inhibitor is selected from the group consisting of p-methoxyphenol, 4-tert-butylcatechol, pyrocatechol, hydroquinone, benzoquinone, 2,4-dimethyl-6-tert-butylphenol, phenothiazine, copper dibutyldithiocarbamate, and mixtures thereof, and wherein the mixing step comprises the online introduction of the at least one polymerization inhibitor in the molten state into a solvent circulation or feed circuit.
8. The process of claim 1 , further comprising, prior to mixing the at least one polymerization inhibitor in the molten state with a solvent, the step of melting the at least one polymerization inhibitor.
9. The process according to claim 8 , wherein the at least one polymerization inhibitor is contained in a container and said container is heated using a heating means until the at least one polymerization inhibitor is molten.
10. The process according to claim 9 , wherein the heating of the container is controlled heating.
11. The process according to claim 1 , wherein the concentration of the at least one polymerization inhibitor in the solution obtained after mixing is between 0.1% and 30% by weight.
12. The process according to claim 11 , wherein the concentration of the at least one polymerization inhibitor in the solution obtained after mixing is between 1% and 30% by weight.
13. The process according to claim 12 , wherein the concentration of the at least one polymerization inhibitor in the solution obtained after mixing is between 2% and 15% by weight.
14. The process according to claim 1 , further comprising: introducing the solution containing the at least one polymerization inhibitor obtained after mixing into an ethylenically unsaturated monomer.
15. The process according to claim 5 , wherein the temperature of the at least one polymerization inhibitor in the molten state is greater than or equal to T m +20° C. and less than or equal to T m +65° C.
16. The process according to claim 14 , wherein the solution containing the at least one polymerization inhibitor obtained is introduced into the ethylenically unsaturated monomer in a distillation device or in a storage means.