Aqueous polymer emulsion
The present invention relates to an aqueous polymer emulsion comprising at least 30 wt. % of a vinyl copolymer (A), said vinyl copolymer comprising: (I) from 10 to 90 wt. % of 2-octyl acrylate monomer; (II) from 10 to 90 wt. % of at least one itaconate ester monomer according to formula (1) in which A and B may be different or the same and A and B are independently an alkyl group or an aryl group; and (III) from 0 to 80 wt. % of ethylenically unsaturated monomer other than (I) and (II); whereby the summed amount of (I), (II) and (III) is 100 wt. % and whereby the amount of vinyl copolymer (A) is given relative to the total weight amount of the polymers present in the emulsion.
1. A coating formed of a dried residue of a coating or paint composition comprised of an aqueous polymer emulsion comprising at least 70 wt. % of a vinyl copolymer (A) relative to the total weight amount of polymers present in the emulsion, wherein the vinyl copolymer (A) comprises:
(I) from 25 to 55 wt. % of 2-octyl acrylate monomer;
(II) from 20 to 65 wt. % of dimethyl itaconate monomer; and
(III) from 0 to 55 wt. % of ethylenically unsaturated monomer other than the monomers (I) and (II), wherein
the summed amount of monomers (I), (II) and (III) is 100 wt. %, and wherein the monomer (III) comprises:
(IIIa) from 0.1 to 15 wt. % of carboxylic acid functional olefinically unsaturated monomer;
(IIIb) from 0 to 5 wt. % of olefinically unsaturated crosslinkable monomer, different from (IIIa), (IIIc) and (IIId);
(IIIc) from 0 to 5 wt. % of olefinically unsaturated wet adhesion promotor monomer, different from (IIIa), (IIIb) and (IIId);
(IIId) from 0 to 54.9 wt. % of olefinically unsaturated monomer, different from (IIIa), (IIIb) and (IIIc); wherein
wherein the amounts of (IIIa), (IIIb), (IIIc) and (IIId) are given relative to the total amount of (I), (II) and (III), and wherein
the coating exhibits improved water resistance as compared to an identical coating where a 2-ethylhexyl acrylate monomer is employed instead of the 2-octyl acrylate monomer.
2. The coating according to claim 1 , wherein the monomer (IIIa) is acrylic acid and/or methacrylic acid.
3. The coating according to claim 1 , wherein the monomers (IIIb), (IIIc) and (IIId) are selected from the group consisting of acrylates, methacrylates, arylalkylenes and mixtures thereof.
4. The coating according to claim 1 , wherein the monomers (IIId) are selected from the group consisting of methyl (meth)acrylate, ethyl (meth)acrylate, butyl (meth)acrylate, styrene and combinations thereof.
5. The coating according to claim 1 , wherein the vinyl copolymer (A) does not contain the monomer (IIIb) and/or the monomer (IIIc).
6. The coating according to claim 1 , wherein the coating or paint composition further comprises at least one additional component selected from the group consisting of solvents, pigments, dyes, heat stabilisers, defoamers, fillers, matting agents, UV absorbers and antioxidants.
7. The coating according to claim 6 , wherein the coating or paint composition is a one-component, non-crosslinkable composition.
8. A method of coating or painting a substrate comprising applying the coating of the coating or paint composition according to claim 6 to a substrate and causing or allowing an aqueous carrier medium of the emulsion to be removed.
9. The method according to claim 8 , wherein the substrate is selected from the group consisting of wood optionally containing a primer and a midcoat, metal, plastic, leather, glass, paper and combinations thereof.
10. A coated or painted substrate obtained by the method of claim 9 .
11. The aqueous polymer emulsion according to claim 1 , wherein the vinyl copolymer comprises at least 30 wt. % of the 2-octyl acrylate monomer (I).