High efficiency diffusion lighting coverings
The invention relates to high efficiency diffusion lighting coverings useful in LED lighting applications. The diffusing lighting coverings are made of organic diffusing particles homogeneously dispersed in a transparent polymer matrix. The primary organic diffusing particles are refractive index mis-matched to the matrix polymer. The refractive index contrast between the polymer matrix and diffusion particles, and particle size are selected to provide a high efficiency (minimized particle loading). The high efficiency diffusion coverings provides excellent light diffusion, high hiding properties and high light transmission. The secondary diffusion particles may optionally be added to further improve selected target properties of the covering. Nano-sized ZnO inorganic particles may also function as diffusion particles and optical brighteners as well UV stabilizers. Articles made of this translucent composition are useful in commercial and residential lighting, motor vehicle illumination (lights, panels), street lighting, displays and signs, desktop monitors, and LCD/LED TVs.
1. A translucent, light-diffusing thermoplastic article comprising a blend composition of
a) a thermoplastic acrylic polymer matrix material, wherein said acrylic polymer comprises from 80 to 99.5 weight percent of methyl methacrylate monomer units,
b) from 0.01 to 5.8 weight percent of organic polymer diffusing particles that are refractive index (R.I.) mis-matched to the matrix polymer, wherein the absolute difference between the matrix polymer R.I. and the diffusing organic polymer particles R.I. is from greater than 0.02 to 0.15,
c) optionally from 0 to 8 weight percent of inorganic diffusing particles,
wherein said weight percentage is based on the weight of the total light-diffusing composition,
wherein, when said article comprising said blend composition is a sheet or film, said sheet of film has a luminous transmission of greater than 40%, an optical haze of greater than 95% and a diffuse light scattering of greater than 85%,
and wherein the organic particles are selected to provide a calculated transmittance (I/I 0 ) of less than 0.5 calculated for a sample of 3 mm thickness and a λ=550 nm.
2. The translucent, light diffusing article of claim 1 , wherein the calculated transmittance (I/I 0 ) is less than 0.4.
3. The translucent, light diffusing article of claim 1 , wherein the absolute difference between the refractive index of said matrix polymer and refractive index of said organic diffusing particles is from 0.03 to 0.12.
4. The translucent, light diffusing article of claim 1 , wherein said polymer matrix further comprises from 5 to 45 weight percent of one or more impact modifiers.
5. The translucent, light diffusing article of claim 1 , wherein said organic diffusing particles have an average particle size of from 0.6 to 40 microns.
6. The translucent, light diffusing article of claim 4 , wherein said organic diffusing particles have an average particle size of from 1 to 25 microns.
7. The translucent, light diffusing article of claim 1 , wherein the correlated color temperature of the light transmitted from said translucent, light-diffusing thermoplastic article is in the range of 3500-5200 Kelvin when the LED light source possess the CCT of 4420 Kelvin.
8. The translucent, light diffusing article of claim 1 , wherein the correlated color temperature of the light transmitted from said translucent, light-diffusing thermoplastic article is in the range of 3900-4800 Kelvin when the LED light source possess the CCT of 4420 Kelvin.
9. The translucent, light diffusing article of claim 1 , wherein said composition comprises from 0.001 to 15 weight percent of inorganic diffusing particles, based on the weight of the blend composition.
10. The translucent, light diffusing article of claim 9 , wherein said composition comprises from 0.1 to 5 weight percent of organic polymer diffusing particles, and from 0.001 to 15 weight percent of inorganic diffusing particles.
11. The translucent, light diffusing article of claim 1 , wherein said inorganic diffusing particles have an average particle size from 10 nm to 25 microns.
12. The translucent, light diffusing article of claim 1 , wherein said inorganic diffusing particles are selected from the group consisting of barium sulfate, silicon dioxide, calcium carbonate, aluminum oxide, titanium dioxide, zinc oxide, silicates, natural and synthetic clays and mixtures thereof.
13. The translucent, light diffusing article of claim 1 , wherein said composition further comprises from 0.00001 to 1 weight percent of one or more optical brighteners.
14. The translucent, light diffusing article of claim 1 , wherein said composition further comprises from 0.001 to 0.1 weight percent of one or more optical brighteners.
15. The translucent, light diffusing article of claim 13 , wherein said optical brighteners are selected from nano-sized zinc oxide compounds and zinc borate.
16. The translucent, light diffusing article of claim 1 , wherein said composition further comprises from 0.0001 to 1 weight percent of one or more optical brighteners and 0.01 to 15 weight percent of inorganic diffusing particles.
17. The translucent, light diffusing article of claim 1 , wherein said article is a light-diffusing covering as part of an interior lighting fixture, an advertising display, a sign, automotive lighting, desktop monitors, and LCD TVs.
18. The translucent, light diffusing article of claim 1 , wherein said article has a thickness of 0.075 to 15 mm.
19. The translucent, light diffusing article of claim 1 , wherein the particle size distribution is narrow, with 90 percent of the particles being within +/−50% of the mean particle size.