Co-surfactant foam-forming composition for enhanced oil recovery
The present invention includes a foam-forming composition for use in enhanced oil recovery, and a method of using said foam-forming composition for recovering oil. The foam-forming composition of the present invention comprises a nonionic surfactant, in particular an alcohol-alkoxylate, and an anionic surfactant, in particular an alkyl diphenyloxide (di)sulfonate, where the foam-forming composition promotes a formation of a stable foam formed of a CO 2 and water.
1. A foam-forming composition for use in an enhanced oil recovery process consisting essentially of:
a nonionic surfactant and an anionic surfactant,
(i) wherein the nonionic surfactant is one or more alcohol-alkoxylate selected from the group consisting of (C 8 H 17 O)—(C 3 H 6 O) 5 —(C 2 H 4 O) 9 —H, (C 8 H 17 O)—(C 3 H 6 O) 5 —(C 2 H 4 O) 11 —H, (C 8 H 17 O)—(C 3 H 6 O) 5 —(C 2 H 4 O) 14 —H, and mixtures thereof;
(ii) wherein the anionic surfactant is one or more alkyl diphenyloxide (di)sulfonate compound having the formula:
where R 5 is a C 3 to C 20 alkyl radical, and X is H, an alkali metal, alkaline earth metal, or ammonium.
2. A method for recovering oil form a reservoir formation that is penetrated by at least one injection well and one production well, comprising
(a) selecting a foam-forming composition consisting essentially of a nonionic surfactant and an anionic surfactant
(i) wherein the nonionic surfactant is one or more alcohol-alkoxylate selected from the group consisting of (C 8 H 17 O)—(C 3 H 6 O) 5 —(C 2 H 4 O) 9 —H, (C 8 H 17 O)—(C 3 H 6 O) 5 —(C 2 H 4 O) 11 —H, (C 8 H 17 O)—(C 3 H 6 O) 5 —(C 2 H 4 O) 14 —H, and mixtures thereof;
(ii) wherein the anionic surfactant is one or more alkyl diphenyloxide (di)sulfonate compound having the formula:
where R 5 is a C 3 to C 20 alkyl radical, and X is H, an alkali metal, alkaline earth metal, or ammonium
(b) forming a stable foam of CO 2 and water in the reservoir with the surfactant foaming composition;
(c) lowering a viscosity of oil in the reservoir formation; and
(d) producing oil having the lowered viscosity from the reservoir formation.
3. The method of claim 2 , where forming the stable foam includes injecting the surfactant with at least one of CO 2 and water into the reservoir formation via the injection well.
4. The method of claim 3 , where injecting the foam-forming composition includes injecting the nonionic surfactant with CO 2 into the reservoir formation and the anionic surfactant with the water into the reservoir formation.
5. The method of claim 3 , where injecting the foam-forming composition includes injecting the nonionic surfactant and the anionic surfactant with the water into the reservoir formation.
6. The method of claim 3 , where injecting the foam-forming composition includes injecting the nonionic surfactant with both CO 2 and water into the reservoir formation and the anionic surfactant with the water into the reservoir formation.
7. The method of claim 2 wherein the alkyl diphenyloxide (di)sulfonate is selected from the group: butyl diphenyloxide disulfonic acid sodium, hexyl diphenyloxide disulfonic acid sodium, decyl diphenyloxide disulfonic acid sodium, dodecyl diphenyloxide disulfonic acid sodium, hexadecyl diphenyloxide disulfonic acid sodium, dodecyl diphenyloxide disulfonic acid potassium, hexyl diphenyloxide disulfonic acid lithium, decyl diphenyloxide disulfonic acid ammonium, dodecyl diphenyloxide disulfonic acid ammonium, dodecyl diphenyloxide disulfonic acid lithium, and mixtures thereof.
8. The method of claim 2 , where foam-forming composition further includes at least one additive selected from a group consisting of a corrosion inhibitor, a scale inhibitor, and mixtures thereof.