IP Library Granted Patent US 10,364,187
Granted Patent B2
US 10,364,187 · App. 15/555,102 · Granted Jul 30, 2019

Jamb spray mixes including fused silica and methods of utilizing the mixes

Inventors: Thomas H. Gisewhite (Warren, OH); Mark C. Langenohl (Venetia, PA); Lynn G. McGregor (Brunswick, OH)
Assignee: Resco Products, Inc.
C04B28/344C10B29/06F27D1/1636C04B2111/00146C04B2111/00551C21C5/44
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Quick Facts
Patent No.
US 10,364,187
App. No.
15/555,102
Granted
Jul 30, 2019
Kind
B2
Abstract

A jamb spray mix comprising: 0.1% to 10% phosphate by weight based on total weight of dry ingredients in the mix, 5% to 15% plasticizer by weight based on total weight of dry ingredients in the mix, the balance of dry ingredients including fused silica particles and impurities, and at least 20% water by weight based on total weight of the mix. In certain non-limiting embodiments, a coating of the jamb spray mix is applied to a refractory brick surface region in a coke oven using an air pressurized applicator and associated nozzle.

Claims (58)

1. A jamb spray mix comprising:

0.1% to 10% phosphate by weight based on total weight of dry ingredients in the mix;

5% to 15% plasticizer based on total weight of dry ingredients in the mix;

the balance of dry ingredients including fused silica particles and impurities; and

at least 20% water by weight based on total weight of the mix.

2. The jamb spray mix of claim 1 , wherein the mix comprises 60% to 95% fused silica particles by weight based on total weight of dry ingredients in the mix.

3. The jamb spray mix of claim 1 , wherein the mix comprises 70% to 90% fused silica particles by weight based on total weight of dry ingredients in the mix.

4. The jamb spray mix of claim 1 , wherein the mix comprises 80% to 90% fused silica particles by weight based on total weight of dry ingredients in the mix.

5. The jamb spray mix of claim 1 , wherein the fused silica particles comprise at least two fused silica particle fractions with different particle size distributions.

6. The jamb spray mix of claim 5 , wherein the fused silica particle fractions include at least two fused silica particle fractions selected from a first fused silica particle fraction sized −30 mesh to +50 mesh, a second fused silica particle fraction sized −50 mesh to +100 mesh, and a third fused silica particle fraction sized −120 mesh.

7. The jamb spray mix of claim 1 , wherein the fused silica particles include a first fused silica particle fraction sized −30 mesh to +50 mesh, a second fused silica particle fraction sized −50 mesh to +100 mesh, and a third fused silica particle fraction sized −120 mesh.

8. The jamb spray mix of claim 1 , wherein the mix includes, by weight based on total weight of dry ingredients in the mix, at least one fused silica particle fraction selected from:

15% to 30% of fused silica particles sized −30 mesh to +50 mesh;

25% to 45% of fused silica particles sized −50 mesh to +100 mesh; and

18% to 35% of fused silica particles sized −120 mesh.

9. The jamb spray mix of claim 1 , wherein the mix includes, by weight based on total weight of dry ingredients in the mix, at least one fused silica particle fraction selected from:

18% to 28% of fused silica particles sized −30 mesh to +50 mesh;

28% to 40% of fused silica particles sized −50 mesh to +100 mesh; and

21% to 31% of fused silica particles sized −120 mesh.

10. The jamb spray mix of claim 1 , wherein the mix includes, by weight based on total weight of dry ingredients in the mix, at least one fused silica particle fraction selected from:

20% to 25% of fused silica particles sized −30 mesh to +50 mesh;

32% to 38% of fused silica particles sized −50 mesh to +100 mesh; and

24% to 28% of fused silica particles sized −120 mesh.

11. The jamb spray mix of claim 1 , wherein the phosphate comprises sodium phosphate.

12. The jamb spray mix of claim 1 , wherein the mix comprises 2% to 5% of phosphate, by weight based on total weight of dry ingredients in the mix.

13. The jamb spray mix of claim 1 , wherein the plasticizer comprises a refractory clay selected from a ball clay and bentonite.

14. The jamb spray mix of claim 1 , wherein the dry ingredients in the mix further comprise boric acid.

15. The jamb spray mix of claim 1 , wherein the mix further comprises 0.1% to 10% of powdered boric acid by weight based on total weight of dry ingredients in the mix.

16. The jamb spray mix of claim 1 , wherein the water content is at least 30% by weight based on total weight of the mix.

17. A method of treating a refractory brick surface region in a coke oven, the method comprising:

mixing with water a composition comprising 0.1% to 10% phosphate by weight based on total dry weight of the composition, 5% to 15% plasticizer by weight based on total dry weight of the composition, and the balance of dry ingredients including fused silica particles and impurities, thereby forming a jamb spray mix comprising at least 20% by weight water based on total weight of the mix; and

applying a coating of the jamb spray mix to the refractory brick surface region using an air pressurized applicator and associated nozzle.

18. The method of claim 17 , wherein water is not added to the jamb spray mix at the nozzle.

19. The method of claim 17 , wherein a thickness of the coating is 0.5 mm to 50 mm.

20. The method of claim 17 , wherein the mix comprises 60% to 95% fused silica particles by weight based on total dry weight of the composition.

21. The method of claim 17 , wherein the mix comprises 70% to 90% fused silica particles by weight based on total dry weight of the composition.

22. The method of claim 17 , wherein the mix comprises 80% to 90% fused silica particles by weight based on total dry weight of the composition.

23. The method of claim 17 , wherein the fused silica particles comprise at least two fused silica particle fractions with different particle size distributions.

24. The method of claim 23 , wherein the fused silica particle fractions include at least fused silica particle fractions selected from a first fused silica particle fraction sized −30 mesh to +50 mesh, a second fused silica particle fraction sized −50 mesh to +100 mesh, and a third fused silica particle fraction sized −120 mesh.

25. The method of claim 17 , wherein the fused silica particles include a first fused silica particle fraction sized −30 mesh to +50 mesh, a second fused silica particle fraction sized −50 mesh to +100 mesh, and a third fused silica particle fraction sized −120 mesh.

26. The method of claim 17 , wherein the mix includes, by weight based on total dry weight of the composition, at least one fused silica particle fraction selected from:

15% to 30% of fused silica particles sized −30 mesh to +50 mesh;

25% to 45% of fused silica particles sized −50 mesh to +100 mesh; and

18% to 35% of fused silica particles sized −120 mesh.

27. The method of claim 17 , wherein the mix includes, by weight based on total dry weight of the composition, at least one fused silica particle fraction selected from:

18% to 28% of fused silica particles sized −30 mesh to +50 mesh;

28% to 40% of fused silica particles sized −50 mesh to +100 mesh; and

21% to 31% of fused silica particles sized −120 mesh.

28. The method of claim 17 , wherein the mix includes, by weight based on total dry weight of the composition, at least one fused silica particle fraction selected from:

20% to 25% of fused silica particles sized −30 mesh to +50 mesh;

32% to 38% of fused silica particles sized −50 mesh to +100 mesh; and

24% to 28% of fused silica particles sized −120 mesh.

29. The method of claim 17 , wherein the phosphate comprises sodium phosphate.

30. The method of claim 17 , wherein the mix comprises 2% to 5% of phosphate, by weight based on total dry weight of the composition.

31. The method of claim 17 , wherein the plasticizer comprises a refractory clay selected from a ball clay and bentonite.

32. The method of claim 17 , wherein the dry ingredients in the mix further comprise boric acid.

33. The method of claim 17 , wherein the mix further comprises 0.1% to 10% of powdered boric acid by weight based on total dry weight of the composition.

34. The method of claim 17 , wherein the water content is at least 20% by weight based on total dry weight of the composition.

Assignments (6)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 29, 2026
From: RESCO PRODUCTS, INC.
To: RHI MAGNESITA GMBH
Reel/Frame 075438/0012 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 29, 2026
From: RHI MAGNESITA GMBH
To: REFRACTORY INTELLECTUAL PROPERTY GMBH & CO. KG
Reel/Frame 075438/0222 →
RELEASE OF SECURITY INTEREST Recorded Jan 31, 2025
From: TCW ASSET MANAGEMENT COMPANY LLC, AS AGENT
To: RESCO PRODUCTS, INC.
Reel/Frame 070075/0819 →
RELEASE OF SECURITY INTEREST Recorded Jan 31, 2025
From: BANK OF AMERICA, N.A., A NATIONAL BANKING ASSOCIATION
To: RESCO PRODUCTS, INC
Reel/Frame 070076/0184 →
SECURITY INTEREST Recorded Mar 7, 2022
From: RESCO PRODUCTS, INC.
To: TCW ASSET MANAGEMENT COMPANY LLC, AS COLLATERAL AGENT
Reel/Frame 059183/0122 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 28, 2019
From: GISEWHITE, THOMAS H.; LANGENOHL, MARK C.; MCGREGOR, LYNN G.
To: RESCO PRODUCTS, INC.
Reel/Frame 049622/0250 →
Continuity (2)
Provisional Application 62362125 · Jul 14, 2016
Related Publication 20190119164A1 · Apr 25, 2019