IP Library Granted Patent US 10,103,347
Granted Patent B2
US 10,103,347 · App. 15/555,390 · Granted Oct 16, 2018

Transparent electrode, method for manufacturing same, and organic electroluminescent element

Inventors: Shigeru Kojima (Hino, JP); Kazuhiro Yoshida (Tachikawa, JP); Shun Furukawa (Sagamihara, JP); Takeshi Hakii (Sagamihara, JP)
Assignee: KONICA MINOLTA, INC.
H01L51/5215B32B7/02B32B15/04C23C18/31H01B5/14H01L51/0022H05B33/28H05K1/0274B32B2307/202B32B2307/412B32B2457/206C23C18/38C25D3/12C25D3/38C25D3/46C25D5/12H01L2251/303H01L2251/305H05K1/097H05K3/246H05K2201/0108H05K2201/0329H05K2201/09681H05K2203/121
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Quick Facts
Patent No.
US 10,103,347
App. No.
15/555,390
Granted
Oct 16, 2018
Kind
B2
Abstract

A transparent electrode includes: a substrate; and a conductive metal layer on the substrate. The conductive metal layer has a thin metal wire and a plating layer. The plating layer covers the thin metal wire. The transparent electrode further includes a transparent conductive layer on a surface of the substrate on a side on which the thin metal wire is formed. The transparent conductive layer covers the substrate and the conductive metal layer. The thin metal wire is formed using a metal nanoparticle ink or a metal complex ink.

Claims (26)

1. A transparent electrode comprising:

a substrate; and

a conductive metal layer on the substrate, wherein

the conductive metal layer has a thin metal wire and a plating layer covering the thin metal wire,

the transparent electrode further comprises a transparent conductive layer on a surface of the substrate on a side on which the thin metal wire is formed, the transparent conductive layer covering the substrate and the conductive metal layer, and

the thin metal wire is formed using a metal nanoparticle ink or a metal complex ink, and the metal nanoparticle ink and the metal complex ink comprise at least one metal selected from the group consisting of gold, silver, copper, iron, cobalt, nickel, chromium, and alloys thereof.

2. The transparent electrode according to claim 1 , wherein the thin metal wire is formed by printing.

3. The transparent electrode according to claim 1 , wherein the thin metal wire is formed using an inkjet parallel line drawing method.

4. The transparent electrode according to claim 1 , wherein the transparent conductive layer contains a conductive polymer.

5. The transparent electrode according to claim 1 , wherein the transparent conductive layer contains a metal oxide.

6. An organic electroluminescent element comprising the transparent electrode according to claim 1 .

7. The transparent electrode according to claim 1 , wherein the metal nanoparticle ink and the metal complex ink comprise at least one metal selected from the group consisting of gold, silver, and copper.

8. The transparent electrode according to claim 1 , wherein the metal nanoparticle ink and the metal complex ink comprise silver.

9. The transparent electrode according to claim 1 , wherein the plating layer is formed by an electrolytic plating.

10. The transparent electrode according to claim 1 , wherein the metal nanoparticle ink contains metal nanoparticles, and the metal nanoparticles have an average particle size of 1 to 100 nm.

11. The transparent electrode according to claim 1 , wherein the metal nanoparticle ink contains metal nanoparticles, and the metal nanoparticles are observable as circles, ovals, or substantial circles or substantial ovals with an electron microscope.

12. A method for manufacturing a transparent electrode, comprising:

forming a thin metal wire on a substrate using a metal nanoparticle ink or a metal complex ink, wherein the metal nanoparticle ink and the metal complex ink comprise at least one metal selected from the group consisting of gold, silver, copper, iron, cobalt nickel, chromium, and alloys thereof;

plating the thin metal wire; and

forming a transparent conductive layer on the plated thin metal wire and a surface of the substrate on a side on which the thin metal wire is formed.

13. The transparent electrode according to claim 12 , wherein the metal nanoparticle ink and the metal complex ink comprise at least one metal selected from the group consisting of gold, silver, and copper.

14. The transparent electrode according to claim 12 , wherein the metal nanoparticle ink and the metal complex ink comprise silver.

15. The transparent electrode according to claim 12 , wherein the thin metal wire is plated by an electrolytic plating.

16. The transparent electrode according to claim 12 , wherein the metal nanoparticle ink contains metal nanoparticles, and the metal nanoparticles have an average particle size of 1 to 100 nm.

17. The transparent electrode according to claim 12 , wherein the metal nanoparticle ink contains metal nanoparticles, and the metal nanoparticles are observable as circles, ovals, or substantial circles or substantial ovals with an electron microscope.

18. The transparent electrode according to claim 12 , wherein the thin metal wire is heated before plating the thin metal wire.

Assignments (3)
NUNC PRO TUNC ASSIGNMENT Recorded Oct 7, 2021
From: KONICA MINOLTA INC
To: MERCK PERFORMANCE MATERIALS GERMANY GMBH
Reel/Frame 057748/0075 →
NUNC PRO TUNC ASSIGNMENT Recorded Oct 7, 2021
From: MERCK PERFORMANCE MATERIALS GERMANY GMBH
To: MERCK PATENT GMBH
Reel/Frame 057748/0146 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 1, 2017
From: KOJIMA, SHIGERU; YOSHIDA, KAZUHIRO; FURUKAWA, SHUN; HAKII, TAKESHI
To: KONICA MINOLTA, INC.
Reel/Frame 043474/0041 →
Priority Claims (1)
JP 2015-044506 · Mar 6, 2015 · national
Continuity (1)
Related Publication 20180040846A1 · Feb 8, 2018