Optical adhesive composition and optical adhesive film
The present invention relates to an optical adhesive composition including: a thermosetting component including an isoprene-based rubber containing a carboxyl group, and a thermal curing agent; and a photo-curable component including an acrylic acid ester-based monomer, and a photoinitiator, in order to exhibit high barrier performance on the basis of a low water vapor transmission rate, and simultaneously, exhibit excellent adhesive performance by being applied to an optical device or a display device. In addition, the present invention provides an optical adhesive film including an adhesive layer including a photo-cured product of the optical adhesive composition, thereby obtaining advantages of ensuring an excellent cutting property and an excellent handling property, and improving a step difference absorbency.
1. An optical adhesive composition comprising:
a thermosetting component comprising an isoprene-based rubber containing a carboxyl group, and a thermal curing agent; and
a photo-curable component comprising an acrylic acid ester-based monomer, and a photoinitiator.
2. The optical adhesive composition of claim 1 , wherein the optical adhesive composition comprises the photo-curable component in an amount of 5 to 70 parts by weight based on 100 parts by weight of the thermosetting component.
3. The optical adhesive composition of claim 1 , wherein the isoprene-based rubber containing a carboxyl group comprises the carboxyl group in an amount of 1 to 15 wt %.
4. The optical adhesive composition of claim 1 , wherein the isoprene-based rubber containing a carboxyl group does not have any photo-curable functional group.
5. The optical adhesive composition of claim 1 , wherein the thermal curing agent comprises at least one selected from the group consisting of an aziridine-based curing agent, an isocyanate-based curing agent, an epoxy-based curing agent, and a combination thereof.
6. The optical adhesive composition of claim 1 , wherein the acrylic acid ester-based monomer comprises at least one selected from the group consisting of dicyclopentadiene (meth)acrylate, isobornyl (meth)acrylate, cyclohexyl (meth)acrylate, stearyl (meth)acrylate, tricyclodecane dimethanol diacrylate, dipentaerythritol pentaacrylate, pentaerythritol tetraacrylate, trimethylolpropane trimethacrylate, nonanediol dimethacrylate, cyclohexanediol dimethacrylate, and a combination thereof.
7. The optical adhesive composition of claim 1 , wherein the photoinitiator comprises at least one selected from the group consisting of benzoin methyl ether, 2,4,6-trimethylbenzoyl diphenylphosphine oxide, bis(2,4,6-trimethylbenzoyl) phenylphosphine oxide, α,α-methoxy-α-hydroxyacetophenone, 2-benzoyl-2-(dimethylamino)-1-[4-(4-morpholinyl) phenyl]-1-butanone, 2,2-dimethoxy-2-phenylacetophenone, 2,2-dimethoxy-1,2-diphenylethan-1-one, 1-hydroxy-cyclohexyl-phenyl ketone, 2-benzyl-2-(dimethylamino)-1-[4-(4-morpholinyl)phenyl]-1-butanone, and a combination thereof.
8. The optical adhesive composition of claim 1 , further comprising:
a tackifier.
9. The optical adhesive composition of claim 8 , wherein the tackifier comprises at least one selected from the group consisting of a hydrogenated dicyclopentadiene-based compound, a hydrogenated terpene-based compound, a hydrogenated rosin-based compound, a hydrogenated aromatic compound, and a combination thereof.
10. The optical adhesive composition of claim 1 , wherein the thermosetting component comprises the thermal curing agent in an amount of 0.05 to 5 parts by weight based on 100 parts by weight of the isoprene-based rubber containing a carboxyl group.
11. The optical adhesive composition of claim 1 , wherein the photo-curable component comprises the photoinitiator in an amount of 0.05 to 1.5 parts by weight based on 100 parts by weight of the acrylic acid ester-based monomer.
12. The optical adhesive composition of claim 1 , wherein the optical adhesive composition is used for an adhesive layer disposed on at least one surface of a base material comprising a metal oxide or a metal nitride.
13. The optical adhesive composition of claim 12 , wherein the metal oxide or the metal nitride comprises at least one selected from the group consisting of silicon nitride, silicon oxide, aluminum nitride, aluminum oxide, zinc oxide, and a combination thereof.
14. An optical adhesive film comprising:
an adhesive layer comprising a photo-cured product of the optical adhesive composition according to claim 1 ; and
a release film disposed on one surface or both surfaces of the adhesive layer.
15. The optical adhesive film of claim 14 , wherein the photo-cured product has a degree of cure of 1% to 30%.
16. The optical adhesive film of claim 14 , wherein the adhesive layer has peel strength of 700 g/in to 2,500 g/in for a base material comprising a metal oxide, after an additional thermal curing.
17. The optical adhesive film of claim 16 , wherein the additional thermal curing is carried out at 40° C. to 100° C.