Extended isenthalpic and/or isothermal flash calculation for hydrocarbon components that are soluble in oil, gas and water

1. A method of determining distribution of a plurality of components among a plurality of phases for a multi-component, multi-phase system including a multi-component, multi-phase fluid, the method comprising:

determining a plurality of phase boundaries of the multi-component, multi-phase fluid and a vapor-liquid equilibrium (VLE) based on a plurality of geophysical parameters associated with an oilfield and using one or more computer processors, including determining hydrocarbon partitioning in a water phase, based in part on applying empirical equilibrium multi-phase mole fraction ratios (K-values) of the multi-component, multi-phase system that are functions of temperature and pressure only, wherein applying empirical equilibrium multi-phase mole fraction ratios of the multi-component, multi-phase system that are functions of temperature and pressure only includes, for a first hydrocarbon component in the multi-component, multi-phase fluid that is soluble in liquid, water and vapor phases:

applying a first empirical equilibrium multi-phase mole fraction ratio (K-value) for equilibrium between the liquid (L) and vapor (V) phases of the first hydrocarbon component; and

applying a second empirical equilibrium multi-phase mole fraction ratio (K-value) for equilibrium between the water (A) and vapor (V) phases of the first hydrocarbon component; and

predicting an amount of at least one fluid component distributed in a plurality of phases of the multi-component, multi-phase system by solving a set of flash equations with the one or more computer processors based on the plurality of phase boundaries.

2. The method of claim 1 , further comprising performing an oilfield operation based upon the predicted amount.

3. The method of claim 1 , further comprising modeling an oilfield operation using at least one computer-implemented simulator, wherein at least a portion of the oilfield is represented by a plurality of grid blocks in the simulator, wherein the plurality of phase boundaries are determined and the amount of the at least one fluid component distributed in the plurality of phases is predicted for each of the plurality of grid blocks.

4. The method of claim 3 , further comprising determining phase states, phase splits, and phase mole fractions associated with each of the plurality of grid blocks.

5. The method of claim 1 , wherein determining hydrocarbon partitioning is based in part on phase behavior and enthalpy of water described by a steam table that is a function of temperature and pressure.

6. The method of claim 1 , wherein the plurality of geophysical parameters includes geophysical parameters selected from the group consisting of global mole fractions of one or more volatile hydrocarbon (VHC) components of oil, global mole fractions of one or more non-volatile hydrocarbon (NVHC) components of oil, global mole fractions of one or more non-condensable hydrocarbon (NCHC) components of oil, global mole fractions of one or more water components, a pressure of the inlaid-component, multi-phase fluid, an enthalpy of the multi-component, multi-phase fluid, a temperature of the multi-component, multi-phase fluid, a fluid phase saturation, a fluid phase density, a component density, and a component fraction by volume or mole in a particular phase.

7. The method of claim 1 , wherein determining the plurality of phase boundaries includes:

determining at least one first temperature at which a first liquid phase associated with the plurality of phase boundaries disappears;

determining at least one second temperature at which a second liquid phase associated with the plurality of phase boundaries disappears; and

determining at least one third temperature at which the gaseous phase appears.

8. The method of claim 7 , wherein the first liquid phase is present when the second liquid phase disappears, wherein the second temperature is determined based on the first temperature and is lower than or equal to the first temperature, wherein the third temperature is determined based on the second temperature and is lower than or equal to the second temperature, and wherein the at least one first, at least one second, and at least one third temperatures are determined in part by using pressure and temperature dependent empirical equilibrium multi-phase mole fraction ratios (K-values) of the multi-component, multi-phase system.

9. The method of claim 7 , wherein determining the plurality of phase boundaries includes determining a succession of temperatures where a liquid phase may disappear and/or reappear one or more times.

10. The method of claim 7 , further comprising one or both of determining at least one temperature at which an additional liquid phase disappears or determining at least one temperature at which an additional gaseous phase appears.

11. The method of claim 7 , wherein determining the at least one first temperature at which the first liquid phase disappears includes determining the at least one first temperature at which oil disappears before water.

12. The method of claim 7 , wherein determining the at least one first temperature at which the first liquid phase disappears includes determining the at least one first temperature at which water disappears before oil.

13. The method of claim 1 , wherein predicting the amount of an at least one fluid component distributed in a plurality of phases of the multi-component, multi-phase system includes predicting the amount of a hydrocarbon component in liquid, water and gas phases.

14. An apparatus, comprising:

one or more computer processors; and

a memory having instructions that when executed by the one or more computer processors determine distribution of a plurality of components among a plurality of phases for a multi-component, multi-phase system including a multi-component, multi-phase fluid, the instructions including:

instructions to determine a plurality of phase boundaries of the multi-component, multi-phase fluid and a vapor-liquid equilibrium (VLE) based on a plurality of geophysical parameters associated with an oilfield, including instructions to determine hydrocarbon partitioning in a water phase, based in part on applying empirical equilibrium multi-phase mole fraction ratios (K-values) of the multi-component, multi-phase system that are functions of temperature and pressure only, wherein applying empirical equilibrium multi-phase mole fraction ratios of the multi-component, multi-phase system that are functions of temperature and pressure only includes, for a first hydrocarbon component in the multi-component, multi-phase fluid that is soluble in liquid, water and vapor phase;

applying a first empirical equilibrium multi-phase mole fraction ratio (K-value) for equilibrium between the liquid (L) and vapor (V) phases of the first hydrocarbon component; and

applying a second empirical equilibrium multi-phase mole fraction ratio (K-value) for equilibrium between the water (A) and vapor (V) phases of the first hydrocarbon component; and

instructions to predict an amount of at least one fluid component distributed in a plurality of phases of the multi-component, multi-phase system by solving a set of flash equations based on the plurality of phase boundaries.

15. A program product, comprising:

a non-transitory computer readable medium; and

program code stored on the non-transitory computer readable medium and configured upon execution by one or more computer processors to determine distribution of a plurality of components among a plurality of phases for a multi-component, multi-phase system including a multi-component, multi-phase fluid, the program code including:

instructions to determine a plurality of phase boundaries of the multi-component, multi-phase fluid and a vapor-liquid equilibrium (VLE) based on a plurality of geophysical parameters associated with an oilfield, including instructions to determine hydrocarbon partitioning in a water phase, based in part on applying empirical equilibrium multi-phase mole fraction ratios (K-values) of the multi-component, multi-phase system that are functions of temperature and pressure only, wherein applying empirical equilibrium multi-phase mole fraction ratios of the multi-component, multi-phase system that are functions of temperature and pressure only includes, for a first hydrocarbon component in the multi-component, multi-phase fluid that is soluble in liquid, water and vapor phases;

applying a first empirical equilibrium multi-phase mole fraction ratio (K-value) for equilibrium between the liquid (L) and vapor (V) phases of the first hydrocarbon component; and

applying a second empirical equilibrium multi-phase mole fraction ratio (K-value) for equilibrium between the water (A) and vapor (V) phases of the first hydrocarbon component; and

instructions to predict an amount of at least one fluid component distributed in a plurality of phases of the multi-component, multi-phase system by solving a set of flash equations based on the plurality of phase boundaries.

16. The apparatus of claim 14 , wherein the instructions include instructions to model an oilfield operation using at least one computer-implemented simulator, wherein at least a portion of the oilfield is represented by a plurality of grid blocks in the simulator, wherein the plurality of phase boundaries are determined and the amount of the at least one fluid component distributed in the plurality of phases is predicted for each of the plurality of grid blocks, and wherein the instructions include instructions to determine phase states, phase splits, and phase mole fractions associated with each of the plurality of grid blocks.

17. The apparatus of claim 14 , wherein the instructions determine hydrocarbon partitioning based in part on phase behavior and enthalpy of water described by a steam table that is a function of temperature and pressure.

18. The apparatus of claim 14 , wherein the plurality of geophysical parameters includes geophysical parameters selected from the group consisting of global mole fractions of one or more volatile hydrocarbon (VHC) components of oil, global mole fractions of one or more non-volatile hydrocarbon (NVHC) components of oil, global mole fractions of one or more non-condensable hydrocarbon (NCHC) components of oil, global mole fractions of one or more water components, a pressure of the multi-component, multi-phase fluid, an enthalpy of the multi-component, multi-phase fluid, a temperature of the multi-component, multi-phase fluid, a fluid phase saturation, a fluid phase density, a component density, and a component fraction by volume or mole in a particular phase.

19. The apparatus of claim 14 , wherein the instructions to determine the plurality of phase boundaries include instructions to:

determine at least one first temperature at which a first liquid phase associated with the plurality of phase boundaries disappears;

determine at least one second temperature at which a second liquid phase associated with the plurality of phase boundaries disappears; and

determine at least one third temperature at which the gaseous phase appears.

20. The apparatus of claim 19 , wherein the first liquid phase is present when the second liquid phase disappears, wherein the second temperature is determined based on the first temperature and is lower than or equal to the first temperature, wherein the third temperature is determined based on the second temperature and is lower than or equal to the second temperature, and wherein the at least one first, at least one second, and at least one third temperatures are determined in part by using pressure and temperature dependent empirical equilibrium multi-phase mole fraction ratios (K-values) of the multi-component, multi-phase system.

21. The apparatus of claim 19 , wherein the instructions to determine the plurality of phase boundaries include instructions to determine a succession of temperatures here a liquid phase may disappear and/or reappear one or more times.

22. The apparatus of claim 19 , wherein the instructions include one or both of instructions to determine at least one temperature at which an additional liquid phase disappears or instructions to determine at least one temperature at which an additional gaseous phase appears.

23. The apparatus of claim 19 , wherein the instructions to determine the at least one first temperature at which the first liquid phase disappears include instructions to determine the at least one first temperature at which oil disappears before water.

24. The apparatus of claim 19 , wherein the instructions to determine the at least one first temperature at which the first liquid phase disappears include instructions to determine the at least one first temperature at which water disappears before oil.

25. The apparatus of claim 14 , wherein the instructions to predict the amount of an at least one fluid component distributed in a plurality of phases of the multi-component, multi-phase system include instructions to predict the amount of a hydrocarbon component in liquid, water and gas phases.