Thermally conductive sheet
A thermally conductive sheet is obtained by stacking a carbon fiber oriented thermally conductive layer and an electrically insulating thermally conductive layer, the carbon fiber oriented thermally conductive layer containing a carbon fiber powder, which has a fiber axis oriented in a sheet thickness direction and is contained in a polymer matrix, the electrically insulating thermally conductive layer having a heat conducting property and an electrical insulation property and containing an electrically insulating thermally conductive filler dispersed in a polymer matrix. This thermally conductive sheet has both a high heat conducting property and an electrical insulating property, is easy to be fixed to an object to be attached, and has excellent handleability.
1. A thermally conductive sheet obtained by stacking a carbon fiber oriented thermally conductive layer and an electrically insulating thermally conductive layer,
the carbon fiber oriented thermally conductive layer containing a carbon fiber powder, which has a fiber axis oriented in a sheet thickness direction and is contained in a polymer matrix,
the electrically insulating thermally conductive layer having a heat conducting property and an electrical insulation property and containing an electrically insulating thermally conductive filler dispersed in a polymer matrix, and
wherein a thermal conductivity (W) (unit: W/m·K) and a thickness (T) (unit: mm) of the electrically insulating thermally conductive layer satisfy a relationship represented by formula (1) below:
0< T≤ 0.20 W−0.19 formula (1).
2. The thermally conductive sheet according to claim 1 , wherein the polymer matrix is formed of a cured body of a main agent and a curing agent of a liquid silicone.
3. The thermally conductive sheet according to claim 1 , wherein an E-hardness of the carbon fiber oriented thermally conductive layer measured with a type E durometer in accordance with Japanese Industrial Standards, JIS K 6253, is 5 to 60, and
the electrically insulating thermally conductive layer is harder than the carbon fiber oriented thermally conductive layer, has an E-hardness of 70 or less, and has a thickness of 0.15 to 1.5 mm.
4. The thermally conductive sheet according to claim 1 , wherein a thermal conductivity of the carbon fiber oriented thermally conductive layer in the sheet thickness direction is 7 W/m·K or more and 30 W/m·K or less, a thermal conductivity of the electrically insulating thermally conductive layer is 2 W/m·K or more and less than 7 W/m·K, and the thermal conductivity of the carbon fiber oriented thermally conductive layer in the thickness direction is set to be higher than the thermal conductivity of the electrically insulating thermally conductive layer.
5. The thermally conductive sheet according to claim 1 , wherein the electrically insulating thermally conductive layer is thinner the carbon fiber oriented thermally conductive layer.
6. The thermally conductive sheet according to claim 1 , wherein a thermal conductivity of the electrically insulating thermally conductive layer is 5 W/m·K or more.
7. The thermally conductive sheet according claim 1 , wherein the electrically insulating thermally conductive layer has a hardness of 20 or more in terms of E-hardness.
8. The thermally conductive sheet according to claim 1 , wherein the carbon fiber oriented thermally conductive layer contains a thermally conductive filler having an aspect ratio of 2 or less.
9. The thermally conductive sheet according to claim 1 , wherein the electrically insulating thermally conductive layer is made of only one single sheet.
10. The thermally conductive sheet according to claim 1 , wherein the electrically insulating thermally conductive layer is formed by curing a mixed composition in which an electrically insulating thermally conductive filler is blended to a liquid polymer composition that forms a polymer matrix.