Engineered composite structure using graphene oxide
This is generally a method of producing dispersed high quality engineered composite structures using flat flakes of graphene/graphene oxides/reduced graphene oxides in a host as the reinforcing additive of the composite.
1. A method of making one or more composite structures using flakes of graphene, graphene oxide and/or reduced graphene oxide; comprising:
obtaining substantially flat graphene, graphene oxide and/or reduced graphene oxide flakes that are not distorted through the graphene/graphite flake production process, with a surface area to thickness ratio of a minimum of 200 Angstroms;
thermally functionalizing the substantially flat graphene, graphene oxide and/or reduced graphene oxide flakes to be compatible a with chemical binding, hydrophobicity, and/or polarity of a host material, to be directly incorporated in the long and short range ordering or bonding of the host material; and
entraining the substantially flat graphene, graphene oxide and/or reduced graphene oxide flakes in the host material.
2. The method of claim 1 , wherein 95% of the substantially flat graphene, graphene oxide and/or reduced graphene oxide flakes have surface area to thickness ratios of more than 200 Angstroms.
3. The method of claim 1 , wherein a thickness of the substantially flat graphene, graphene oxide and/or reduced graphene oxide flakes is 16 nanometers or less.
4. The method of claim 1 , wherein 95% of a thicknesses of the substantially flat graphene, graphene oxide and/or reduced graphene oxide flakes is about 0.8 to 16 nanometers, and the substantially flat graphene, graphene oxide and/or reduced graphene oxide flakes have a surface area to thickness ratios greater than 48400 to 1 Angstroms.
5. The method of claim 1 , wherein the maximum dimension of the substantially flat graphene, graphene oxide and/or reduced graphene oxide flakes varies between 220 Angstroms and 100 microns.
6. The method of claim 1 , further comprising mixing the substantially flat graphene, graphene oxide and/or reduced graphene oxide flakes with an additional powder or multiple powders to achieve uniform distribution, dispersion and/or entrainment of graphene/graphite oxide flake within the host material; and
reacting, casting or otherwise causing the powders to become ordered, by thermal, chemical, electrical or other processes that induce order or bonding to occur between the powders.
7. The method of claim 6 , wherein the substantially flat graphene, graphene oxide and/or reduced graphene oxide flakes by weight are greater than 0.001% and less than 30% of oxidation of the graphene/graphite oxide in the result of the step of mixing.
8. The method of claim 1 , wherein the one or more composite structures are created by forming localized regions of a higher concentration of graphene, graphene oxide and/or reduced graphene oxide in the host material, not to exceed 10% loading by weight.
9. The method of claim 1 , wherein the host material is selected from ordinary Portland cement, polypropylene (PP), polyethylene (PE), Polycarbonate (PC), ceramic powders, ceramic powder is aluminum oxide, zirconium oxide, silica, silicon dioxide, or combination thereof, metal powders, metal powders of titanium, titanium hydride, tantalum, cobalt chrome, niobium, stainless steel, nickel, copper, aluminum, or combinations thereof, a polycrystalline material, polyvinylidene fluoride (PVF), or polyvinylidene difluoride (PVDF), polyurethane, poly(butyleneterephthalate), nylon 11, poly(ethyleneterephthalate), poly(ether ether ketone), poly(phenylene sulfide), polyolefin, an oxide, carbonate or silicate of an element of Groups 2a, 3a, 4a and 4b of the Periodic Table, poly(vinyl chloride) (PVC), poly(methylmethacrylate), polystyrene, polycarbonate/nylon alloy, polycarbonate/polyester alloy, ABS, ABS/nylon alloy, ABS/PVC alloy, acrylic copolymers, polysulfone, polysulfone/ABS alloy, polyetherimides, polyamide-imides, polyarylates, fluoropolymers, polyphenylene oxide/polystyrene blend, or poly(phenylene sulfide).
10. The method of claim 1 , wherein the step of functionalizing is defined further as adding a chemical group selected from at least one of alkyl, alkenyl, alkynyl, phenyl, halo, hydroxyl, carbonyl, aldehyde, carbonate, carboxylate, carboxyl, ester, methoxy, hydroperoxy, ether, hemiacetal or hemiketal, acetal, ketal, orthoester, amide, amine, imine, imide, azide, azo, cyanate, nitrile, nitrite, nitro, nitroso, oxime, pyridine, thiol, sulfide, disulfide, sulfoxide, sulfone, sulfinic, thiocyanate, phosphine, phosphonic, phosphate, and/or bonoric.
11. A method of making a composite structure using flakes of graphene, graphene oxide and/or reduced graphene oxide; comprising:
obtaining substantially flat graphene, graphene oxide and/or reduced graphene oxide flakes that are not distorted through the graphene/graphite flake production process, with a surface area to thickness ratio of a minimum of 200 Angstroms;
thermally functionalizing the substantially flat graphene, graphene oxide and/or reduced graphene oxide flakes to be compatible a with chemical binding, hydrophobicity, and/or polarity of a host material, to be directly incorporated in the long and short range ordering or bonding of the host material;
entraining the substantially flat graphene, graphene oxide and/or reduced graphene oxide flakes in the host material; and
forming a composite material with the substantially flat graphene, graphene oxide and/or reduced graphene oxide flakes in the host material.
12. The method of claim 11 , wherein 95% of the substantially flat graphene, graphene oxide and/or reduced graphene oxide flakes have surface area to thickness ratios of more than 200 Angstroms.
13. The method of claim 11 , wherein a thickness of the substantially flat graphene, graphene oxide and/or reduced graphene oxide flakes is 16 nanometers or less.
14. The method of claim 11 , wherein 95% of a thicknesses of the substantially flat graphene, graphene oxide and/or reduced graphene oxide flakes is about 0.8 to 16 nanometers, and the substantially flat graphene, graphene oxide and/or reduced graphene oxide flakes have a surface area to thickness ratios greater than 48400 to 1 Angstroms.
15. The method of claim 11 , wherein the maximum dimension of the substantially flat graphene, graphene oxide and/or reduced graphene oxide flakes varies between 220 Angstroms and 100 microns.
16. The method of claim 11 , further comprising mixing the substantially flat graphene, graphene oxide and/or reduced graphene oxide flakes with an additional powder or multiple powders to achieve uniform distribution, dispersion and/or entrainment of graphene/graphite oxide flake within the host material; and
reacting, casting or otherwise causing the powders to become ordered, by thermal, chemical, electrical or other processes that induce order or bonding to occur between the powders.
17. The method of claim 16 , wherein the substantially flat graphene, graphene oxide and/or reduced graphene oxide flakes by weight are greater than 0.001% and less than 30% of oxidation of the graphene/graphite oxide in the result of the step of mixing.
18. The method of claim 11 , wherein the composite material comprises localized regions of a higher concentration of graphene oxide and/or reduced graphene oxide in the host material, not to exceed 10% loading by weight.
19. The method of claim 11 , wherein the host material is selected from ordinary Portland cement, polypropylene (PP), polyethylene (PE), Polycarbonate (PC), ceramic powders, ceramic powder is aluminum oxide, zirconium oxide, silica, silicon dioxide, or combination thereof, metal powders, metal powders of titanium, titanium hydride, tantalum, cobalt chrome, niobium, stainless steel, nickel, copper, aluminum, or combinations thereof, a polycrystalline material, polyvinylidene fluoride (PVF), or polyvinylidene difluoride (PVDF), polyurethane, poly(butyleneterephthalate), nylon 11, poly(ethyleneterephthalate), poly(ether ether ketone), poly(phenylene sulfide), polyolefin, an oxide, carbonate or silicate of an element of Groups 2a, 3a, 4a and 4b of the Periodic Table, poly(vinyl chloride) (PVC), poly(methylmethacrylate), polystyrene, polycarbonate/nylon alloy, polycarbonate/polyester alloy, ABS, ABS/nylon alloy, ABS/PVC alloy, acrylic copolymers, polysulfone, polysulfone/ABS alloy, polyetherimides, polyamide-imides, polyarylates, fluoropolymers, polyphenylene oxide/polystyrene blend, or poly(phenylene sulfide).
20. The method of claim 11 , wherein the step of functionalizing is defined further as adding a chemical groups selected from at least one of alkyl, alkenyl, alkynyl, phenyl, halo, hydroxyl, carbonyl, aldehyde, carbonate, carboxylate, carboxyl, ester, methoxy, hydroperoxy, ether, hemiacetal or hemiketal, acetal, ketal, orthoester, amide, amine, imine, imide, azide, azo, cyanate, nitrile, nitrite, nitro, nitroso, oxime, pyridine, thiol, sulfide, disulfide, sulfoxide, sulfone, sulfinic, thiocyanate, phosphine, phosphonic, phosphate, and/or boronic.