IP Library Granted Patent US 10,584,275
Granted Patent B2
US 10,584,275 · App. 15/560,033 · Granted Mar 10, 2020

Compositions, systems, and methods for removing iron sulfide scale from oilfield components using methyl acrylate

Inventors: Yang Peng (Kingwood, TX); Zhiwei Yue (Sugar Land, TX); Funian Zhao (Tomball, TX); Liu Shi (Houston, TX); Ronald Larry Hoppe (Calgary, CA); Liangwei Qu (Spring, TX); Chunfang Fan (Houston, TX)
Assignee: Multi-Chem Group, LLC
C09K8/532C08L33/08C23G1/24C01G49/12C09K2208/20
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Quick Facts
Patent No.
US 10,584,275
App. No.
15/560,033
Granted
Mar 10, 2020
Kind
B2
Abstract

The present disclosure relates to compositions, systems and methods for removing iron sulfide scale from a solid object, such as an oilfield component. The compositions include a carbon-carbon (C—C) double bond with an electron withdrawing group bonded to at least one of the double-bonded carbons.

Claims (22)

1. A method of removing iron sulfide scale from an oilfield component with iron sulfide scale, the method comprising applying to the oilfield component a removal material comprising a methyl-acrylate containing composition of the general structural formula:

in an amount and for a time sufficient to remove iron sulfide scale from the oilfield component.

2. The method of claim 1 , wherein the removal material further comprises a polar solvent.

3. The method of claim 1 , wherein the removal material further comprises an additional composition able to remove iron sulfide scale from the oilfield component.

4. The method of claim 1 , wherein at least 80% of the iron sulfide scale is removed from the oilfield component.

5. The method of claim 1 , wherein applying occurs in a sealed container.

6. The method of claim 1 , further comprising recovering the removal material.

7. The method of claim 1 , wherein the oilfield component comprises a perforation, a casing, a production tubular, a valve, a pump, or downhole completion equipment with iron sulfide scale.

8. A system for removing iron sulfide scale from an oilfield component with iron sulfide scale, the system comprising:

a removal material comprising a methyl-acrylate containing composition of the general structural formula:

and

a system for applying the removal material to the oilfield component in an amount and for a time sufficient to remove iron sulfide scale from the oilfield component.

9. The system of claim 8 , wherein the removal material further comprises a polar solvent.

10. The system of claim 8 , wherein the removal material further comprises an additional composition able to remove iron sulfide scale from the oilfield component.

11. The system of claim 8 , wherein at least 80% of the iron sulfide scale is removed from the oilfield component.

12. The system of claim 8 , wherein the system for applying the removal material comprises a sealed container.

13. The system of claim 8 , wherein the system for applying the removal material further comprises a subsystem for recovering the removal material.

14. The system of claim 8 , wherein the oilfield component comprises a perforation, a casing, a production tubular, a valve, a pump, or downhole completion equipment with iron sulfide scale.

15. The system of claim 8 , wherein the oilfield component comprises a tubular and the system for applying the removal material to the oilfield component comprises a container to house the removal material and a connector to supply the removal material to the tubular.

16. The system of claim 15 , wherein the container is a pressurized container.

17. The system of claim 8 , wherein the oilfield component is placeable in a container and the system for applying the removal material to the oilfield component comprises a sealed container in which the oilfield component is placed, a container housing the removal material, and a connector to supply the removal material to the sealed container.

18. The system of claim 17 , wherein the container housing the removal material is a pressurized container.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 10, 2021
From: MULTI-CHEM GROUP, LLC
To: HALLIBURTON ENERGY SERVICES, INC.
Reel/Frame 056681/0849 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 20, 2019
From: HALLIBURTON ENERGY SERVICES, INC.
To: MULTI-CHEM GROUP, LLC
Reel/Frame 048385/0203 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 20, 2017
From: PENG, YANG; YUE, ZHIWEI; ZHAO, FUNIAN; SHI, LIU; HOPPE, RONALD LARRY; QU, LIANGWEI; FAN, CHUNFANG
To: HALLIBURTON ENERGY SERVICES, INC.
Reel/Frame 043641/0645 →
Continuity (1)
Related Publication 20180072940A1 · Mar 15, 2018