Rare-earth magnet comprising holmium and tungsten
Disclosed is a Ho and W-containing rare-earth magnet. The rare-earth magnet comprises a R 2 Fe 14 B type principal phase, and comprises the following raw material components: R: 28 wt % to 33 wt %, wherein R is a raw-earth element comprising Nd and Ho, and the content of Ho is 0.3 wt % to 5 wt %; B: 0.8 wt % to 1.3 wt %; W: 0.005 wt % to 0.3 wt %, and the balance of T and inevitable purities, wherein T is an element mainly comprising Fe and/or Co. The rare-earth magnet mainly consists of a W-rich grain boundary phase and a Ho-rich principal phase; crystal grain growth of the Ho-containing magnet in a sintering process is constrained by the trace of W, thereby preventing AGG from occurring on the Ho-containing magnet, and obtaining a magnet with high coercivity and high heat resistance.
1. A rare-earth magnet comprising a main phase of R 2 Fe 14 B, wherein:
the rare-earth magnet comprises the following raw material components:
R: 28 wt % to 33 wt %, where R is a rare-earth element comprising Nd and Ho, and a content of Ho ranging from 0.3 wt % to 5 wt %;
B: 0.8 wt % to 1.3 wt %;
W: 0.0005 wt % to 0.03 wt %; and
a balance being T and inevitable impurities, where T mainly comprises Fe and further comprises 0 wt % to 18 wt % of Co,
a grain boundary of the rare-earth magnet comprises a W-rich region in which a content of W is greater than or equal to 40 ppm and less than or equal to 3000 ppm, and
the W-rich region occupies at least 50% of a volume of the grain boundary.
2. The rare-earth magnet according to claim 1 , wherein T comprises at least one element with a content less than or equal to 2.0 wt % selected from Sn, Sb, Hf, Bi, V, Zr, Mo, Zn, Ga, Nb, Ni, Ti, Cr, Si, Mn, S, or P; Cu with a content less than or equal to 0.8 wt %; Al with a content less than 0.8 wt %; and a balance being Fe.
3. The rare-earth magnet according to claim 2 , wherein the rare-earth magnet is manufactured by:
preparing an alloy for the rare-earth magnet from a melt of the raw material components of the rare-earth magnet;
performing coarse grinding on the alloy for the rare-earth magnet to manufacture coarse powder;
performing fine grinding on the coarse powder to manufacture fine powder;
subjecting the fine powder to a magnetic field shaping process to obtain a shaped body; and
sintering the shaped body in a vacuum or an inert gas to obtain a sintered rare-earth magnet with an oxygen content less than or equal to 1000 ppm.
4. The rare-earth magnet according to claim 3 , wherein:
the preparing the alloy comprises cooling the melt of the raw material components at a cooling speed greater than or equal to 10 2 ° C./s and less than or equal to 10 4 ° C./s with a strip casting process,
the coarse grinding comprises performing hydrogen decrepitation on the alloy for the rare-earth magnet, and
the fine grinding comprises performing jet milling on the coarse powder.
5. The rare-earth magnet according to claim 1 , wherein the rare-earth magnet is a Nd—Fe—B based sintered magnet.
6. The rare-earth magnet according to claim 5 , wherein T comprises Cu with a content ranging from 0.1 wt % to 0.8 wt %.
7. The rare-earth magnet according to claim 5 , wherein T comprises Al with a content ranging from 0.1 wt % to 0.8 wt %.
8. The rare-earth magnet according to claim 5 , wherein T comprises at least one element selected from Sn, Sb, Hf, Bi, V, Zr, Mo, Zn, Ga, Nb, Ni, Ti, Cr, Si, Mn, S, or P, and a total content of the at least one element ranges from 0.1 wt % to 2.0 wt % of the raw material components of the rare-earth magnet.
9. The rare-earth magnet according to claim 1 , wherein the rare-earth magnet comprises at least two phases, wherein the at least two phases are a W-rich grain boundary phase and a Ho-rich major phase, wherein the Ho-rich major phase corresponds to the main phase of R 2 Fe 14 B.
10. The rare-earth magnet according to claim 1 , wherein the content of W ranges from 0.0005 wt % to 0.01 wt %.
11. The rare-earth magnet according to claim 2 , wherein the rare-earth magnet is a Nd—Fe—B based sintered magnet.
12. The rare-earth magnet according to claim 11 , wherein T comprises Cu with a content ranging from 0.1 wt % to 0.8 wt %.
13. The rare-earth magnet according to claim 11 , wherein T comprises Al with a content ranging from 0.1 wt % to 0.8 wt %.
14. The rare-earth magnet according to claim 11 , wherein T comprises at least one element selected from Sn, Sb, Hf, Bi, V, Zr, Mo, Zn, Ga, Nb, Ni, Ti, Cr, Si, Mn, S, or P, and a total content of the at least one element ranges from 0.1 wt % to 2.0 wt % of the raw material components of the rare-earth magnet.
15. The rare-earth magnet according to claim 1 , wherein a number of abnormal grain growths in the rare-earth magnet is between 0-2.
16. The rare-earth magnet according to claim 1 , wherein a BH(max) of the rare-earth magnet is at least than 45.
17. The rare-earth magnet according to claim 1 , wherein an oxygen content of the rare-earth magnet is 1000 ppm or less.
18. The rare-earth magnet according to claim 1 , wherein T comprises Cu with a content ranging from 0.1 wt % to 0.8 wt % and Al with a content ranging from 0.1 wt % to 0.8 wt %.
19. The rare-earth magnet according to claim 18 , wherein the content of W ranges from 0.0005 wt % to 0.01 wt %.
20. The rare-earth magnet according to claim 1 , wherein:
T comprises at least one of Cu with a content ranging from 0.1 wt % to 0.8 wt % or Al with a content ranging from 0.1 wt % to 0.8 wt %, and
the content of W ranges from 0.0005 wt % to 0.01 wt %.