Fluoroalkyl-containing curable organopolysiloxane composition, cured object obtained therefrom, and electronic component or display device including said cured object
View Patent ↗A curable organopolysiloxane composition containing a fluoroalkyl group is disclosed. The composition comprises: (A) an organopolysiloxane containing a fluoroalkyl group, having at least two alkenyl groups in a molecule, where 10 mol % or more of all substitution groups on the silicon atoms is a fluoroalkyl group, and the average degree of polymerization is less than 150; (B) an organohydrogen polysiloxane having at least two silicon-bonded hydrogen atoms in a molecule at an amount where the silicon-bonded hydrogen atoms in the component is 0.1 to 1.0 mol with regard to a total of 1 mol of the alkenyl groups in component (A); (C) an effective amount of a hydrosilylation reaction catalyst; and optionally, (D) a solvent. The composition generally has a high dielectric constant and favorable transparency. A cured product and applications of the composition and the cured product thereof are also disclosed.
1. A touch panel comprising:
a substrate where a conductive layer is formed on one surface; and
a film-shaped or sheet-shaped cured layer formed by curing a curable organopolysiloxane composition containing a fluoroalkyl group, adhered to the conductive layer of the substrate or a surface on an opposite side thereof; wherein the curable organopolysiloxane composition containing a fluoroalkyl group comprises:
(A) 100 parts by mass of an organopolysiloxane containing a fluoroalkyl group, having at least two alkenyl groups with 2 to 12 carbon atoms in a molecule, where 10 mol % or more of all substitution groups on the silicon atoms is a fluoroalkyl group as expressed by (C p F 2p+1 )—R— where R represents an alkylene group with 1 to 10 carbon atoms, and p represents an integer from 1 to 8, and the average degree of polymerization is less than 150;
(B) an organohydrogen polysiloxane having at least two silicon-bonded hydrogen atoms in a molecule at an amount where the silicon-bonded hydrogen atoms in the component is 0.1 to 1.0 mol with regard to a total of 1 mol of the alkenyl groups in component (A);
(C) an effective amount of a hydrosilylation reaction catalyst; and
(D) 0 to 2,000 parts by mass of a solvent, with regard to a total of 100 parts by mass of components (A) to (C).
2. The touch panel according to claim 1 , wherein component (A) is an organopolysiloxane as expressed by the following average unit formula (I):
R 1 R 2 2 Si(OSiR 1 R 2 ) e1 (OSiR 2 2 ) e2 OSiR 1 R 2 2 (I)
where R 1 represents the fluoroalkyl group as expressed by (C p F 2p+1 )—R— or an alkenyl group with 2 to 12 carbon atoms, R 2 independently represents an alkyl group with 1 to 12 carbon atoms, an aryl group with 6 to 20 carbon atoms, an aralkyl group with 7 to 20 carbon atoms, a hydroxyl group, or an alkoxy group with 1 to 6 carbon atoms, where of all R 1 s, at least two are alkenyl groups with 2 to 12 carbon atoms, and of all R 1 s and R 2 s, 10 mol % or more are the fluoroalkyl group; and e1 and e2 represent 0 or a positive number, and are numbers that satisfy 5<e1+e2<148.
3. The touch panel according to claim 1 , wherein component (A) is an organopolysiloxane as expressed by the following average unit formula (II):
R Vi R 2 2 Si(OSiR 2 R 3 ) e OSiR Vi R 2 2 (II)
where R Vi represents an alkenyl group with 2 to 12 carbon atoms, R 2 independently represents an alkyl group with 1 to 12 carbon atoms, an aryl group with 6 to 20 carbon atoms, an aralkyl group with 7 to 20 carbon atoms, a hydroxyl group, or an alkoxy group with 1 to 6 carbon atoms, R 3 represents the fluoroalkyl group as expressed by (C p F 2p+1 )—R—, and e is a number that satisfies 5<e<148.
4. The touch panel according to claim 1 , wherein the fluoroalkyl group as expressed by (C p F 2p+1 )—R— in component (A) is a trifluoropropyl group.
5. The touch panel according to claim 1 , wherein component (B) is an organohydrogen polysiloxane having a group containing fluorine.
6. The touch panel according to claim 1 , wherein component (B) is an organohydrogen polysiloxane having a fluoroalkyl group as expressed by (C p F 2p+1 )—R— where R represents an alkylene group with 1 to 10 carbon atoms, and p represents an integer from 1 to 8.
7. The touch panel according to claim 1 , wherein component (B) is an organohydrogen polysiloxane having a trifluoroalkyl group in a molecule.
8. The touch panel according to claim 1 , wherein component (B) is an organohydrogen polysiloxane as expressed by the following average unit formula (III) or (IV):
R 2 3 Si(OSiR 4 R 2 ) f1 (OSiR 2 2 ) f2 OSiR 2 3 (III)
where R 4 represents a fluoroalkyl group as expressed by (C p F 2p+1 )—R— where R represents an alkylene group with 1 to 10 carbon atoms, and p represents an integer from 1 to 8, or a silicon-bonded hydrogen atom, R 2 independently represents an alkyl group with 1 to 12 carbon atoms, an aryl group with 6 to 20 carbon atoms, an aralkyl group with 7 to 20 carbon atoms, a hydroxyl group, or an alkoxy group with 1 to 6 carbon atoms, where of all R 4 s, at least two are silicon-bonded hydrogen atoms, and f1 and f2 represent 0 or a positive number, and are numbers that satisfy 5<f1+f2<150;
(HR 2 2 SiO 1/2 ) f3 (R 5 SiO 3/2 ) f4 (IV)
where R 5 represents a fluoroalkyl group as expressed by (C p F 2p+1 )—R— where R represents the same group as above, and p represents the same number as above, R 2 represents the same group as above, f3 and f4 represent a positive number, and f3+f4 is a number where the weight average molecular weight of the organohydrogen polysiloxane as expressed by formula (IV) is within a range of 400 to 10,000.
9. The touch panel according to claim 1 , wherein component (A) is the following component (A1) or component (A2):
(A1) an organopolysiloxane having at least two alkenyl groups with 2 to 12 carbon atoms in a molecule, where 10 mol % or more of all substitution groups on the silicon atoms is the fluoroalkyl group as expressed by (C p F 2p+1 )—R—, the average degree of polymerization is less than 150, and the volume content rate of organopolysiloxane having a degree of polymerization of 250 or more is less than 10%; and
(A2) an organopolysiloxane containing a fluoroalkyl group, containing the following component (a1) and component (a2) with different molecular weight distribution, where the average degree of polymerization of the entire mixture is less than 150:
(a1) an organopolysiloxane having at least two alkenyl groups with 2 to 12 carbon atoms in a molecule, where 10 mol % or more of all substitution groups on the silicon atoms is the fluoroalkyl group as expressed by (C p F 2p+1 )—R—, and the average degree of polymerization is 200 or more; and
(a2) an organopolysiloxane having at least two alkenyl groups with 2 to 12 carbon atoms in a molecule, where 10 mol % or more of all substitution groups on the silicon atoms is the fluoroalkyl group as expressed by (C p F 2p+1 )—R—, and the average degree of polymerization is 50 or less.
10. The touch panel according to claim 1 , wherein the substrate on which the conductive layer is formed is a resin film or glass plate on which an ITO layer is formed on one surface.