IP Library Granted Patent US 10,549,264
Granted Patent B2
US 10,549,264 · App. 15/566,047 · Granted Feb 4, 2020

Method of regenerating used denitration catalyst

Inventors: Keiichiro Kai (Yokohama, JP); Yasuyoshi Kato (Yokohama, JP); Naomi Imada (Yokohama, JP)
Assignee: MITSUBISHI HITACHI POWER SYSTEMS, LTD.
B01J21/20B01D53/8621B01D53/96B01J21/04B01J23/34B01J23/92B01J35/0006B01J38/485B01D2255/20707B01J21/063B01J38/64
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Quick Facts
Patent No.
US 10,549,264
App. No.
15/566,047
Granted
Feb 4, 2020
Kind
B2
Abstract

A used denitration catalyst is regenerated by means of a method comprising bringing the used denitration catalyst comprising titanium oxide as an essential ingredient into contact with a suspension of particles comprising manganese oxide, subjecting the resulting product to a liquid draining, and subjecting the liquid-drained product to a drying process, additionally, further comprising impregnating a solution comprising a compound containing at least one element selected from the group consisting of vanadium, molybdenum and tungsten into the denitration catalyst after the drying process, and subjecting the impregnated product to a drying treatment.

Claims (13)

1. A method for regenerating used denitration catalyst, comprising:

bringing a used denitration catalyst, to which arsenic and phosphorus coming from an exhaust gas adhere, comprising titanium oxide as an essential ingredient into contact with a suspension comprising a suspensoid composed of particles comprising manganese oxide,

wherein the particles comprising manganese oxide are manganese oxide-supported on aluminum oxide particles or manganese oxide-supported on titanium oxide particles,

subjecting the resulting product to a removal of the suspensoid and a liquid draining, and

subjecting the suspensoid-removed and liquid-drained product to a drying process,

whereby the arsenic and phosphorus are removed from the used denitration catalyst.

2. The method for regenerating used denitration catalyst according to claim 1 , wherein the manganese oxide is MnO or Mn 3 O 4 .

3. The method for regenerating used denitration catalyst according to claim 1 , further comprising:

impregnating a solution comprising a compound containing at least one element selected from the group consisting of vanadium, molybdenum and tungsten into the denitration catalyst after the drying process, and

subjecting the impregnated product to a drying treatment.

4. The method for regenerating used denitration catalyst according to claim 3 , wherein the manganese oxide is MnO or Mn 3 O 4 .

5. The method according to claim 1 , wherein the used denitration catalyst is a honeycomb shaped catalyst comprising a catalytic active substance, or a catalyst comprising a plate-shaped substrate and a catalytic active substance supported on the plate-shaped substrate, wherein the titanium oxide is employed as the catalytic active substance.

6. The method according to claim 3 , wherein the used denitration catalyst is a honeycomb shaped catalyst comprising a catalytic active substance, or a catalyst comprising a plate-shaped substrate and a catalytic active substance supported on the plate-shaped substrate, wherein the titanium oxide is employed as the catalytic active substance.

Assignments (3)
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVING PATENT APPLICATION NUMBER 11921683 PREVIOUSLY RECORDED AT REEL: 054975 FRAME: 0438. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded May 26, 2023
From: MITSUBISHI HITACHI POWER SYSTEMS, LTD.
To: MITSUBISHI POWER, LTD.
Reel/Frame 063787/0867 →
CHANGE OF NAME Recorded Jan 13, 2021
From: MITSUBISHI HITACHI POWER SYSTEMS, LTD.
To: MITSUBISHI POWER, LTD.
Reel/Frame 054975/0438 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 12, 2017
From: KAI, KEIICHIRO; KATO, YASUYOSHI; IMADA, NAOMI
To: MITSUBISHI HITACHI POWER SYSTEMS, LTD.
Reel/Frame 043851/0796 →
Priority Claims (1)
JP 2015-085472 · Apr 17, 2015 · national
Continuity (1)
Related Publication 20180133691A1 · May 17, 2018