IP Library Granted Patent US 10,968,323
Granted Patent B2
US 10,968,323 · App. 15/568,216 · Granted Apr 6, 2021

Natural fiber composite and method of production

Inventors: Blake Teipel (College Station, TX); Elisa Teipel (College Station, TX); Matt Kirby (College Station, TX); Ryan Vano (College Station, TX)
Assignee: ESSENTIUM, INC.
C08J5/045B29C70/021C08B37/0024C08L23/10C08L51/06C08L97/02C08L2205/02C08L2205/16
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Quick Facts
Patent No.
US 10,968,323
App. No.
15/568,216
Granted
Apr 6, 2021
Kind
B2
Abstract

A reinforced polymer composite includes a polymer matrix, a strengthening agent, and a dispersing agent. The strengthening agent is a natural fiber having an aspect ratio between 6 and 12 and is included in the composite in amounts up to 30 wt %. The dispersing agent is coconut shell powder having an aspect ratio between 1 and 3 and is included in the composite in amounts up to 10 wt %.

Claims (56)

1. A reinforced polymer composite, the reinforced polymer composite comprising:

a polymer matrix;

a strengthening agent, the strengthening agent including a natural fiber having a first aspect ratio;

a dispersing agent, the dispersing agent including a coconut shell powder wherein the coconut shell powder has a low aspect ratio as compared to the first aspect ratio of the natural fiber; and

a solid phase grafted MAPP in the amount up to 3.0 wt %,

wherein the strengthening agent is homogenously dispersed in the polymer matrix.

2. The polymer composite material of claim 1 , wherein the natural fiber is a bast fiber included in the reinforced polymer composite in an amount up to about 40.0 wt %.

3. The polymer composite material of claim 2 , wherein the bast fiber is included in the amount of about 25.0 wt %.

4. The polymer composite material of claim 2 , wherein the bast fiber is included in the amount of about 20.0 wt %.

5. The polymer composite material of claim 1 , wherein the coconut shell powder is included in the reinforced polymer composite in the amount up to 10.0 wt %.

6. The polymer composite material of claim 5 , wherein the coconut shell powder is included in the reinforced polymer composite in the amount of about 5.0 wt %.

7. The polymer composite material of claim 1 , wherein the low aspect ratio of the coconut shell powder is between 1 and 3.

8. The polymer composite material of claim 1 , wherein the first aspect ratio of the natural fiber is between 6 and 12.

9. The polymer composite material of claim 1 , further including a scrubbing agent in the amount up to 2.0 wt %.

10. An injection molded reinforced polymer composite part, the reinforced polymer composite comprising:

a polymer matrix;

a strengthening agent, the strengthening agent including a natural fiber having a first aspect ratio in the amount up to 40.0 wt %;

a dispersing agent, the dispersing agent including a coconut shell powder in the amount up to 10.0 wt %, and wherein the coconut shell powder exhibits a low aspect ratio compared to the first aspect ratio;

a scrubbing agent in the amount up to 2.0 wt %, and

a solid phase grafted MAPP in the amount up to 2.0 wt %; and

wherein the strengthening agent is homogenously dispersed in the polymer matrix.

11. The polymer composite material of claim 10 , wherein the natural fiber is a bast fiber included in the reinforced polymer composite in the amount of about 25.0 wt % and the coconut shell powder is included in the reinforced polymer composite in the amount of about 5.0 wt %.

12. The polymer composite material of claim 10 , wherein the natural fiber is a bast fiber included in the amount of about 20.0 wt % and the coconut shell powder is included in the reinforced polymer composite in the amount of about 10.0 wt %.

13. The polymer composite material of claim 10 , wherein the low aspect ratio of the coconut fiber is between 1 and 3.

14. The polymer composite material of claim 13 , wherein the first aspect ratio is between 6 and 12.

15. A method for manufacturing a reinforced polymer composite part, the method including the steps of:

providing and cleaning a natural fiber strengthening agent having an aspect ratio between 6 and 12;

providing, milling, and cleaning a dispersing agent having an aspect ratio between 1 and 3;

drying the cleaned natural fiber strengthening agent and milled and cleaned dispersing agent;

providing and combining a polymer resin with the natural fiber strengthening agent, the dispersing agent, and a solid phase grafted MAPP in the amount up to 3.0 wt % in an extruder; and

injecting the combined polymer resin, natural fiber, and dispersing agent mixture into a die to form the part.

16. The method of claim 15 , wherein the natural fiber strengthening agent is provided in the amount of about 25.0 wt % and the dispersing agent is provided in the amount of about 5.0 wt %.

17. The method of claim 15 , wherein the natural fiber strengthening agent is provided in the amount of about 20.0 wt % and the dispersing agent is provided in the amount of about 10.0 wt %.

18. The method of claim 15 , wherein the dispersing agent is a coconut shell powder, the coconut shell powder is provided in the amount between 5.0 wt % and 10.0 wt %, the natural fiber is a bast fiber, and the bast fiber is provided in the amount between 20.0 wt % and 25.0 wt %.

19. A reinforced polymer composite, the reinforced polymer composite comprising:

a polymer matrix;

a strengthening agent, the strengthening agent including a natural fiber having a first aspect ratio;

a dispersing agent, the dispersing agent including a coconut shell powder wherein the coconut shell powder has a low aspect ratio as compared to the first aspect ratio of the natural fiber; and

a scrubbing agent in the amount up to 2.0 wt. %,

wherein the strengthening agent is homogenously dispersed in the polymer matrix.

20. The reinforced polymer composite material of claim 19 , wherein the natural fiber is a bast fiber included in the reinforced polymer composite in an amount up to about 40.0 wt %.

21. The polymer composite material of claim 20 , wherein the bast fiber is included in the amount of about 25.0 wt %.

22. The polymer composite material of claim 20 , wherein the bast fiber is included in the amount of about 20.0 wt %.

23. The reinforced polymer composite material of claim 19 , wherein the coconut shell powder is included in the reinforced polymer composite in the amount up to 10.0 wt %.

24. The polymer composite material of claim 23 , wherein the coconut shell powder is included in the reinforced polymer composite in the amount of about 5.0 wt %.

25. The reinforced polymer composite material of claim 19 , wherein the low aspect ratio of the coconut shell powder is between 1 and 3.

26. The reinforced polymer composite material of claim 19 , wherein the first aspect ratio of the natural fiber is between 6 and 12.

27. A method for manufacturing a reinforced polymer composite part, the method including the steps of:

providing and cleaning a natural fiber strengthening agent having an aspect ratio between 6 and 12;

providing, milling, and cleaning a dispersing agent having an aspect ratio between 1 and 3;

drying the cleaned natural fiber strengthening agent and milled and cleaned dispersing agent;

providing and combining a polymer resin with the natural fiber strengthening agent, the dispersing agent, and a scrubbing agent in an extruder, wherein the scrubbing agent is provided in an amount up to 2.0 wt. %; and

injecting the combined polymer resin, natural fiber, and dispersing agent mixture into a die to form the part.

28. The method of claim 27 , wherein the natural fiber strengthening agent is provided in the amount of about 25.0 wt % and the dispersing agent is provided in the amount of about 5.0 wt %.

29. The method of claim 27 , wherein the natural fiber strengthening agent is provided in the amount of about 20.0 wt % and the dispersing agent is provided in the amount of about 10.0 wt %.

30. The method of claim 27 , wherein the dispersing agent is a coconut shell powder, the coconut shell powder is provided in the amount between 5.0 wt % and 10.0 wt %, the natural fiber is a bast fiber, and the bast fiber is provided in the amount between 20.0 wt % and 25.0 wt %.

Assignments (12)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 17, 2025
From: NEXA3D INC.; NXT FACTORY, INC.
To: STRATASYS, INC.
Reel/Frame 071657/0111 →
RELEASE OF SECURITY INTEREST Recorded Jun 10, 2025
From: U.S. BANK TRUST COMPANY
To: NEXA3D INC.; NXT FACTORY INC.; NEXA3D APS
Reel/Frame 071534/0581 →
SECURITY INTEREST Recorded Nov 15, 2024
From: NEXA3D INC.; NXT FACTORY INC.; NEXA3D APS
To: U.S. BANK TRUST COMPANY
Reel/Frame 069381/0694 →
RELEASE OF SECURITY INTEREST Recorded Jan 17, 2024
From: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION
To: ESSENTIUM, INC.; ESSENTIUM IPHOLDCO, LLC; ESSENTIUM IPCO, LLC
Reel/Frame 066339/0087 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 17, 2024
From: ESSENTIUM IPCO, LLC.
To: NEXA3D INC.
Reel/Frame 066339/0185 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 16, 2022
From: ESSENTIUM, INC.
To: ESSENTIUM IPCO, LLC
Reel/Frame 061950/0803 →
RELEASE OF SECURITY INTEREST Recorded Jul 18, 2022
From: SILICON VALLEY BANK
To: ESSENTIUM, INC.
Reel/Frame 060682/0613 →
SECURITY INTEREST Recorded Jun 27, 2022
From: ESSENTIUM, INC.; ESSENTIUM IPHOLDCO, LLC; ESSENTIUM IPCO, LLC
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS THE COLLATERAL AGENT
Reel/Frame 060445/0808 →
SECURITY INTEREST Recorded Sep 20, 2021
From: ESSENTIUM, INC.
To: QSHGP, INC.
Reel/Frame 057545/0005 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 18, 2021
From: ESSENTIUM MATERIALS, LLC
To: ESSENTIUM, INC.
Reel/Frame 054943/0185 →
SECURITY INTEREST Recorded Oct 27, 2020
From: ESSENTIUM, INC.
To: SILICON VALLEY BANK
Reel/Frame 054198/0663 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 12, 2018
From: TEIPEL, BLAKE; TEIPEL, ELISA; KIRBY, MATT; VANO, RYAN
To: ESSENTIUM MATERIALS, LLC
Reel/Frame 044893/0353 →