Methods for operating a polymerization reactor
Methods for olefin polymerization are described. The methods include a) forming a first polyolefin under a first set of polymerization conditions in the presence of a first catalyst composition and a first concentration of at least a first continuity additive composition, the first polyolefin composition having a target density, 1, and a target Flow Index, FI1; and b) forming a second polyolefin composition under a second set of polymerization conditions in the presence of a second catalyst composition and a second concentration of a second continuity additive composition, the second polyolefin composition having a target density, 2, and a target Flow Index, FI2; wherein the process is essentially free of providing a polymerization neutralizing composition between steps a) and b).
1. A method for olefin polymerization, comprising:
a) forming a first polyolefin under a first set of polymerization conditions in the presence of a first catalyst composition and a first concentration of at least a first continuity additive composition, the first polyolefin composition having a target density, ρ 1 , and a target Flow Index, FI 1 ; and
b) forming a second polyolefin composition under a second set of polymerization conditions in the presence of a second catalyst composition and a second concentration of a second continuity additive composition, the second polyolefin composition having a target density, ρ 2 , and a target Flow Index, FI 2 ;
wherein the process is essentially free of providing a polymerization neutralizing composition between steps a) and b), and wherein the first catalyst composition comprises a bimodal catalyst composition and the second catalyst composition comprises a unimodal catalyst composition; or wherein the first catalyst composition comprises a unimodal catalyst composition and the second catalyst composition comprises a bimodal catalyst composition.
2. The method of claim 1 , wherein the first and second continuity additive compositions each comprise aluminum distearate, zinc distearate, or mixtures thereof.
3. The method of claim 1 , wherein the first and second continuity additive compositions are essentially the same and the method further comprises adjusting the first concentration of the first continuity additive composition to the second concentration of the second continuity additive composition.
4. The method of claim 1 , further comprising:
c) forming a third polyolefin composition under a third set of polymerization conditions in the presence of the first catalyst composition and a third concentration of a third continuity additive composition, the third polyolefin composition having a target density, ρ 3 , and target Flow Index, FI 3 .
5. The method of claim 4 , wherein the third catalyst composition comprises a bimodal catalyst composition.
6. The method of claim 4 , wherein the third catalyst composition comprises a unimodal catalyst composition.
7. The method of claim 4 , wherein the second and third continuity additive compositions each comprise aluminum distearate, zinc disterate, or mixtures thereof.
8. The method of claim 4 , wherein the first and second continuity additive compositions are essentially the same and the method further comprises adjusting the first concentration of the first continuity additive composition to the second concentration of the second continuity additive composition.
9. The method of claim 4 , wherein the difference between the densities of the first and third polyolefin compositions is ≤0.005 g/cm 3 .
10. The method of claim 4 , wherein the difference between the Flow Indexes, I 21 , of the first and third polyolefin compositions is ≤1.0 g/10 min.
11. The method of claim 1 , wherein the target density, ρ 1 , is 0.870 g/cm 3 to about 0.970 g/cm 3 and the target density, ρ 2 , is about 0.870 g/cm 3 to about 0.970 g/cm 3 , and wherein the difference between the target densities of the first and second polyolefin compositions is ≤0.005 g/cm 3 .
12. The method of claim 1 , wherein the target flow index, FI 1 , is about 1.0 to about 1000.0 g/10 min. and the target flow index, FI 2 , is about 1.0 to about 1000.0 g/10 min., and wherein the difference in the target flow indexes of the first and second polyolefin compositions is ≥about 10.0 g/10 min.
13. The method of claim 1 , wherein the first catalyst composition is selected from the group consisting of [(2,4,6-Me 3 C 6 H 2 )NCH 2 CH 2 ] 2 NHHfBz 2 , [(2,4,6-Me 3 C 6 H 2 )NCH 2 CH 2 ] 2 NHZrBz 2 or [(2,3,4,5,6-Me 5 C 6 )NCH 2 CH 2 ] 2 NHZrBz 2 , where Bz is a benzyl group and bis(n-propylcyclopentadienyl)hafnium dichloride.
14. The method of claim 13 , wherein the first catalyst composition further includes at least a metallocene catalyst selected from the group consisting of bis(indenyl)zirconium dichloride, (pentamethylcyclopentadienyl)(n-propylcyclopentadienyl)zirconium dichloride, or (tetramethylcyclopentadienyl)(n-propylcyclopentadienyl)zirconium dichloride.
15. The method of claim 1 wherein the second catalyst composition is selected from the group consisting of [(2,4,6-Me 3 C 6 H 2 )NCH 2 CH 2 ] 2 NHHfBz 2 or [(2,4,6-Me 3 C 6 H 2 )NCH 2 CH 2 ] 2 NHZrBz 2 or [(2,3,4,5,6-Me 5 C 6 )NCH 2 CH 2 ] 2 NHZrBz 2 , where Bz is a benzyl group selected from the group consisting of [(2,4,6-Me 3 C 6 H 2 )NCH 2 CH 2 ] 2 NHHfBz 2 , [(2,4,6-Me 3 C 6 H 2 )NCH 2 CH 2 ] 2 NHZrBz 2 or [(2,3,4,5,6-Me 5 C 6 )NCH 2 CH 2 ] 2 NHZrBz 2 , where Bz is a benzyl group.
16. The method of claim 15 , wherein the second catalyst composition further includes at least a metallocene catalyst selected from the group consisting of bis(indenyl)zirconium dichloride, (pentamethylcyclopentadienyl)(n-propylcyclopentadienyl)zirconium dichloride, or (tetramethylcyclopentadienyl)(n-propylcyclopentadienyl)zirconium dichloride.