Anode slurry for secondary battery for improving dispersibility and reducing resistance, and anode comprising same
View Patent ↗The present invention provides an anode slurry for a secondary battery and an anode comprising the same, in which the dispersibility of an anode active material is improved by increasing the adsorption amount of CMC with respect to the anode active material by adjusting the degree of substitution or physical properties such as molecular weight, and a CMC blend amount is reduced so as to increase the slurry solid content and reduce the resistance of a battery.
1. An anode slurry for a secondary battery comprising an anode active material and a thickening agent,
wherein the anode active material has a tap density of 1.0 g/cc or less and a slurry solid content of 48% by weight or more based on the total weight of the slurry,
wherein the thickening agent is carboxymethyl cellulose (CMC),
wherein the CMC has a degree of substitution of 0.73 to 0.78,
wherein the CMC comprises low molecular weight CMC having a weight average molecular weight of 1,000,000 or less and high molecular weight CMC having a weight average molecular weight of 2,000,000 or more,
the low molecular weight CMC and the high molecular weight CMC are blended in a weight ratio of 1:3 to 3:1, and
wherein the CMC has a weight average molecular weight of 1,800,000 to 3,200,000.
2. The anode slurry of claim 1 , wherein the CMC has an adsorption amount of 0.8 to 0.9% by weight with respect to the anode active material.
3. The anode slurry of claim 1 , wherein the CMC is present at a content of 1% by weight, based on the total weight of the anode slurry.
4. The anode slurry of claim 3 , wherein a slurry precipitation rate of the anode slurry for a secondary battery is less than or equal to 7%.
5. An anode for a secondary battery formed from the anode slurry for a secondary battery defined in claim 1 .
6. A lithium secondary battery comprising a cathode, the anode of claim 5 , an electrolyte, and a separator.