Reinforced poly(phenylene ether) compositions, and articles prepared therefrom
A composition includes specific amounts of a poly(phenylene ether), a poly(phenylene ether)-polysiloxane block copolymer, a homopolystyrene, a flame retardant, and a reinforcing filler. The composition exhibits a desirable balance of flame retardancy, heat resistance, stiffness, and melt flow. Articles that can be prepared from the composition include frames and chassis of office equipment, fuser module parts for printers, copiers, and facsimile machines, cooling fan blades, cooling fan housings, parts for automotive kinetic energy recovery systems, and parts for electric vehicle junction boxes.
1. A composition comprising, based on the total weight of polymers and fillers:
0.5 to 91 weight percent of a poly(phenylene ether)-polysiloxane block copolymer reaction product comprising a first poly(phenylene ether) and a poly(phenylene ether)-polysiloxane block copolymer;
5 to 90.5 weight percent of a second poly(phenylene ether);
1 to 50 weight percent of homopolystyrene;
3 to 25 weight percent of a flame retardant comprising an organophosphate ester, a phosphazene, or a combination thereof; and
5 to 40 weight percent of reinforcing filler.
2. The composition of claim 1 , comprising 2 to 20 weight percent of the poly(phenylene ether)-polysiloxane block copolymer reaction product, and 10 to 60 weight percent of the second poly(phenylene ether).
3. The composition of claim 1 , excluding impact modifiers.
4. The composition of claim 1 , wherein the homopolystyrene comprises an atactic homopolystyrene.
5. The composition of claim 1 , wherein the flame retardant comprises the organophosphate ester.
6. The composition of claim 1 , wherein the reinforcing filler is selected from the group consisting of glass fibers, carbon fibers, wollastonite, halloysite, clays, talcs, micas, glass flakes, solid glass beads, hollow glass beads, solid ceramic beads, hollow ceramic beads, and combinations thereof.
7. The composition of claim 1 , wherein the reinforcing filler comprises glass fibers.
8. The composition of claim 1 , wherein the reinforcing filler comprises mica.
9. The composition of claim 1 ,
wherein the poly(phenylene ether)-polysiloxane block copolymer reaction product has an intrinsic viscosity of 0.3 to 0.5 deciliter per gram measured at 25° C. in chloroform;
wherein the first poly(phenylene ether) comprises repeat units selected from the group consisting of 2,6-dimethyl-1,4-phenylene ether, 2,3,6-trimethyl-1,4-phenylene ether, and combinations thereof;
wherein the poly(phenylene ether)-polysiloxane block copolymer comprises
a poly(phenylene ether) block comprising repeat units selected from the group consisting of 2,6-dimethyl-1,4-phenylene ether, 2,3,6-trimethyl-1,4-phenylene ether, and combinations thereof; and
a polysiloxane block having the structure
wherein n is, on average, 20 to 60;
wherein the second poly(phenylene ether) comprises repeat units selected from the group consisting of 2,6-dimethyl-1,4-phenylene ether, 2,3,6-trimethyl-1,4-phenylene ether, and combinations thereof;
wherein the homopolystyrene is an atactic homopolystyrene;
wherein the flame retardant is selected from the group consisting of resorcinol bis(diphenyl phosphate), bisphenol A bis(diphenyl phosphate), and combinations thereof;
wherein the reinforcing filler comprises glass fibers and mica; and
wherein the composition comprises
2 to 10 weight percent of the poly(phenylene ether)-polysiloxane block copolymer reaction product,
25 to 45 weight percent of the second poly(phenylene ether),
15 to 40 weight percent of the homopolystyrene,
4 to 12 weight percent of the flame retardant, and
20 to 40 weight percent of the reinforcing filler comprising 10 to 35 weight percent of the glass fibers and 5 to 30 weight percent of the mica.
10. An article comprising a composition comprising, based on the total weight of polymers and fillers:
0.5 to 91 weight percent of a poly(phenylene ether)-polysiloxane block copolymer reaction product comprising a first poly(phenylene ether) and a poly(phenylene ether)-polysiloxane block copolymer;
5 to 90.5 weight percent of a second poly(phenylene ether);
1 to 50 weight percent of homopolystyrene;
3 to 25 weight percent of a flame retardant comprising an organophosphate ester, a phosphazene, or a combination thereof; and
5 to 40 weight percent of reinforcing filler.
11. The article of claim 10 , selected from the group consisting of frames and chassis of office equipment, fuser module parts for printers, copiers, and facsimile machines, cooling fan blades, cooling fan housings, parts for automotive kinetic energy recovery systems, and parts for electric vehicle junction boxes.
12. The article of claim 10 , wherein the composition excludes impact modifiers.
13. The article of claim 10 , wherein the homopolystyrene comprises an atactic homopolystyrene.
14. The article of claim 10 , wherein the flame retardant comprises the organophosphate ester.
15. The article of claim 10 , wherein the reinforcing filler is selected from the group consisting of glass fibers, carbon fibers, wollastonite, halloysite, clays, talcs, micas, glass flakes, solid glass beads, hollow glass beads, solid ceramic beads, hollow ceramic beads, and combinations thereof.
16. The article of claim 10 , wherein the reinforcing filler comprises glass fibers.
17. The article of claim 10 , wherein the reinforcing filler comprises mica.
18. The article of claim 10 ,
wherein the poly(phenylene ether)-polysiloxane block copolymer reaction product has an intrinsic viscosity of 0.3 to 0.5 deciliter per gram measured at 25° C. in chloroform;
wherein the first poly(phenylene ether) comprises repeat units selected from the group consisting of 2,6-dimethyl-1,4-phenylene ether, 2,3,6-trimethyl-1,4-phenylene ether, and combinations thereof;
wherein the poly(phenylene ether)-polysiloxane block copolymer comprises
a poly(phenylene ether) block comprising repeat units selected from the group consisting of 2,6-dimethyl-1,4-phenylene ether, 2,3,6-trimethyl-1,4-phenylene ether, and combinations thereof; and
a polysiloxane block having the structure
wherein n is, on average, 20 to 60;
wherein the second poly(phenylene ether) comprises repeat units selected from the group consisting of 2,6-dimethyl-1,4-phenylene ether, 2,3,6-trimethyl-1,4-phenylene ether, and combinations thereof;
wherein the homopolystyrene is an atactic homopolystyrene;
wherein the flame retardant is selected from the group consisting of resorcinol bis(diphenyl phosphate), bisphenol A bis(diphenyl phosphate), and combinations thereof;
wherein the reinforcing filler comprises glass fibers and mica; and
wherein the composition comprises
2 to 10 weight percent of the poly(phenylene ether)-polysiloxane block copolymer reaction product,
25 to 45 weight percent of the second poly(phenylene ether),
15 to 40 weight percent of the homopolystyrene,
4 to 12 weight percent of the flame retardant, and
20 to 40 weight percent of the reinforcing filler comprising 10 to 35 weight percent of the glass fibers and 5 to 30 weight percent of the mica.