IP Library Granted Patent US 10,738,266
Granted Patent B2
US 10,738,266 · App. 15/572,223 · Granted Aug 11, 2020

Structured liquid compositions comprising colloidal dispersions of poly alpha-1,3-glucan

Inventors: Rakesh Nambiar (West Chester, PA); Jayme L. Paullin (Exton, PA); Ji Yeon Huh (Newark, DE); Natnael Behabtu (Wilmington, DE)
Assignee: DUPONT INDUSTRIAL BIOSCIENCES USA, LLC
C11D3/222A61K8/04A61K8/73A61Q5/02A61Q11/00A61Q19/10C08B37/0009C11D3/0021C11D3/0036C11D3/3715C11D11/0017C11D11/0023C11D17/003C11D17/0013C11D17/0026A61K2800/10A61K2800/594A61K2800/596
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Quick Facts
Patent No.
US 10,738,266
App. No.
15/572,223
Granted
Aug 11, 2020
Kind
B2
Abstract

Polysaccharides can be used to provide a liquid composition with desirable rheological properties while being compatible with other ingredients, such as enzymes, that may be used in formulating the liquid composition. The polysaccharides can be i) a colloidal dispersion of poly alpha-1,3-glucan, ii) poly alpha-1,3-glucan fibrids, iii) soy polysaccharide; or iv) a combination thereof.

Claims (49)

1. A liquid composition comprising:

(a) at least one surfactant; and

(b) at least one polysaccharide structurant;

wherein the polysaccharide structurant is:

(i) a colloidal dispersion of poly alpha-1,3-glucan;

(ii) poly alpha-1,3-glucan fibrids; or

(iii) a combination thereof.

2. The liquid composition of claim 1 , wherein the surfactant is selected from the group consisting of: anionic surfactant, nonionic surfactant, cationic surfactant, and mixtures thereof.

3. The liquid composition of claim 1 , wherein the liquid composition comprises 0.5wt % to 40 wt % of the surfactant.

4. The liquid composition of claim 1 , wherein the liquid composition comprises 0.1 wt % to 15 wt % of the polysaccharide structurant.

5. The liquid composition of claim 1 , wherein the liquid composition further comprises at least one enzyme.

6. The liquid composition of claim 1 , wherein the liquid composition further comprises a suspended insoluble material.

7. The liquid composition of claim 1 , wherein the liquid composition further comprises a water-soluble polymer.

8. The liquid composition of claim 7 , wherein the water-soluble polymer is a carboxylate polymer, polyethylene glycol polymer, polyester soil release polymer, amine polymer, cellulosic polymer, dye transfer inhibition polymer, dye lock polymer, hexamethylenediamine derivative polymer, or combination thereof.

9. A process to manufacture a liquid composition comprising at least one surfactant and a polysaccharide structurant, the process comprising the steps of:

(a) providing a liquid premix comprising the surfactant;

(b) providing a structuring premix comprising the polysaccharide structurant; and

(c) incorporating the structuring premix into the liquid premix using high shear mixing, wherein the polysaccharide structurant is:

i) a colloidal dispersion of poly alpha-1,3-glucan;

ii) poly alpha-1,3-glucan fibrids; or

iii) combination thereof.

10. The process of claim 9 , wherein the structuring premix comprises a surfactant.

11. A method for treating a substrate by contacting the substrate with a liquid composition according to claim 1 .

12. The method of claim 11 , wherein the substrate is a fabric, dish, or hard surface.

13. The liquid composition of claim 1 , wherein at least 80% of the glycosidic linkages of the poly alpha-1,3-glucan of the colloidal dispersion or the fibrids are alpha-1,3 glycosidic linkages.

14. The liquid composition of claim 1 , wherein the polysaccharide structurant is said colloidal dispersion.

15. The liquid composition of claim 1 , wherein the polysaccharide structurant is said poly alpha-1,3-glucan fibrids.

16. The liquid composition of claim 5 , wherein the enzyme is a cellulase, or an endoglucanase with activity towards xyloglucan.

17. The liquid composition of claim 5 , wherein the enzyme is a protease, amylase, mannanase, or pectate lyase.

18. A liquid composition comprising:

(a) at least one surfactant;

(b) water; and

(c) at least one polysaccharide structurant;

wherein the polysaccharide structurant is:

(i) a colloidal dispersion of poly alpha-1,3-glucan;

(ii) poly alpha-1,3-glucan fibrids; or

(iii) a combination thereof.

19. The liquid composition of claim 18 , wherein the surfactant is selected from the group consisting of: anionic surfactant, nonionic surfactant, cationic surfactant, and mixtures thereof.

20. The liquid composition of claim 18 , wherein the liquid composition further comprises at least one enzyme.

21. The liquid composition of claim 18 , wherein the enzyme is a protease, amylase, mannanase, pectate lyase, or cellulase, or an endoglucanase with activity towards xyloglucan.

22. The liquid composition of claim 18 , wherein the liquid composition further comprises a suspended insoluble material.

23. The liquid composition of claim 18 , wherein the liquid composition further comprises a water-soluble polymer.

24. The liquid composition of claim 23 , wherein the water-soluble polymer is a carboxylate polymer, polyethylene glycol polymer, polyester soil release polymer, amine polymer, cellulosic polymer, dye transfer inhibition polymer, dye lock polymer, hexamethylenediamine derivative polymer, or combination thereof.

25. The liquid composition of claim 18 , wherein at least 80% of the glycosidic linkages of the poly alpha-1,3-glucan of the colloidal dispersion or the fibrids are alpha- 1,3 glycosidic linkages.

26. The liquid composition of claim 18 , wherein the polysaccharide structurant is said colloidal dispersion.

27. The liquid composition of claim 18 , wherein the polysaccharide structurant is said poly alpha-1,3-glucan fibrids.

28. A method for treating a substrate by contacting the substrate with a liquid composition according to claim 18 .

29. The method of claim 28 , wherein the substrate is a fabric, dish, or hard surface.

30. The process of claim 9 , wherein the liquid premix and/or the structuring premix further comprise water.

Assignments (6)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 28, 2020
From: DUPONT INDUSTRIAL BIOSCIENCES USA, LLC
To: NUTRITION & BIOSCIENCES USA 4, INC.
Reel/Frame 055028/0496 →
CORRECTIVE ASSIGNMENT TO CORRECT THE ENTITY TYPE PREVIOUSLY RECORDED AT REEL: 049879 FRAME: 0043. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Sep 6, 2019
From: E. I. DU PONT DE NEMOURS AND COMPANY
To: DUPONT INDUSTRIAL BIOSCIENCES USA, LLC
Reel/Frame 050300/0408 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 26, 2019
From: E. I. DU PONT DE NEMOURS AND COMPANY
To: DUPONT INDUSTRIAL BIOSCIENCES USA, LLC
Reel/Frame 049879/0043 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 19, 2019
From: PAULLIN, JAYME L
To: E. I. DU PONT DE NEMOURS AND COMPANY
Reel/Frame 049521/0605 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 19, 2019
From: BEHABTU, NATNAEL
To: DUPONT INDUSTRIAL BIOSCIENCES USA, LLC
Reel/Frame 049522/0085 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 19, 2019
From: NAMBIAR, RAKESH; HUH, JI YEON
To: DUPONT SPECIALTY PRODUCTS USA, LLC
Reel/Frame 049522/0329 →
Continuity (4)
Provisional Application 62169134 · Jun 1, 2015
Provisional Application 62169118 · Jun 1, 2015
Provisional Application 62169103 · Jun 1, 2015
Related Publication 20180127682A1 · May 10, 2018