Anode for secondary battery and secondary battery including the same
An anode for a secondary battery in which Sn metal powder particles function as a conductive material in combination with a carbonaceous conductive material, and a secondary battery including the anode and having improved electroconductivity are provided. The secondary battery including the anode has improved electroconductivity and reduced resistance, and thus can show excellent output performance.
1. An anode for a secondary battery comprising:
an anode current collector and
a carbonaceous anode active material layer formed on at least one surface of the anode current collector,
wherein the active material layer comprises a mixture of an active material, a carbonaceous conductive material and Sn metal powder particles,
wherein the Sn metal powder particles function as a conductive material in combination with the carbonaceous conductive material, and
wherein the active material is a carbonaceous active material and the active material does not include silicon,
wherein the Sn metal powder particles have a particle diameter corresponding to 10% or less of the particle diameter of the active material,
wherein the active material is different than the carbonaceous conductive material.
2. The anode for a secondary battery according to claim 1 , wherein the Sn metal powder particles are bound to the active material through a binder polymer.
3. The anode for a secondary battery according to claim 1 , wherein the Sn metal powder particles and the carbonaceous conductive material are included at a ratio of 1:1-5:1 on the weight basis.
4. The anode for a secondary battery according to claim 1 , wherein the Sn metal powder particle are present in an amount of 1-5 wt % based on 100 wt % of the active material.
5. The anode for a secondary battery according to claim 1 , wherein the Sn metal powder particles have an average diameter of 0.01-1 μm.
6. The anode for a secondary battery according to claim 1 , wherein the carbonaceous conductive material is carbon black primary particles having a spherical shape with an average particle diameter of 10-50 nm.
7. The anode for a secondary battery according to claim 1 , wherein the carbonaceous conductive material is fibrous graphite capable of point contact with at least two active materials that are not adjacent to each other.
8. The anode for a secondary battery according to claim 2 , wherein the binder polymer is a binder polymer dispersed in water.
9. The anode for a secondary battery according to claim 2 , wherein the binder polymer is styrene-butadiene rubber (SBR).
10. The anode for a secondary battery according to claim 1 , wherein the Sn metal powder particles are derived from SnO 2 .
11. A secondary battery comprising an anode, a cathode, a separator interposed between the anode and the cathode and an electrolyte, wherein the anode is the anode as defined in claim 1 and the electrolyte contains a lithium salt.