Lithium-ion battery and its electrolyte
The present invention discloses a Lithium ion battery and an electrolyte thereof, the electrolyte comprising an organic solvent, a lithium salt and an additive. The additive comprises a cyclic fluoro carbonate (A), a cyclic phosphazene (B), a cyclic sulfate and a lithium fluoro oxalate borate (D). The lithium fluoro oxalate borate (D) has following formula: Compared with the prior art, the electrolyte of the present invention may form a stable CEI and SEI film on the surface of positive and negative electrodes, protect the interface between positive and negative electrodes, improve the acidic atmosphere of Lithium ion battery electrolyte, and reduce the damage effect of HF on the interface between positive and negative electrodes, while reducing low temperature resistance of lithium-ion battery, improving cycle life, high temperature storage performance, safety performance and rate capability of lithium-ion battery.
1. A Lithium ion battery electrolyte comprising an organic solvent, a lithium salt, and an additive, wherein the said additive comprises a cyclic fluoro carbonate (A), a cyclic phosphazene (B), a cyclic sulfate (C) and a lithium fluoro oxalate borate (D),
wherein the cyclic fluoro carbonate (A) is
wherein the cyclic phosphazene (B) is
wherein the cyclic sulfate (C) is
wherein the lithium fluoro oxalato borate (D) is
and wherein the cyclic fluoro carbonate is present in an amount of 15 to 25%, based on the total weight of the electrolyte.
2. The Lithium ion battery electrolyte according to claim 1 , wherein the lithium fluoro oxalate borate is present in an amount of 0.1 to 8%, based on the total weight of the electrolyte.
3. The Lithium ion battery electrolyte according to claim 1 , wherein the cyclic phosphazene is present in an amount of 0.1 to 12%, based on the total weight of the electrolyte.
4. The Lithium ion battery electrolyte according to claim 1 , wherein the cyclic sulfate is present in an amount of 0.1 to 8%, based on the total weight of the electrolyte.
5. The Lithium ion battery electrolyte according to claim 1 , wherein the additive further comprises at least one of lithium difluorophosphate (LiPO 2 F 2 ) and lithium bis(fluorosulfonyl)imide (LiFSI).
6. The Lithium ion battery electrolyte according to claim 5 , wherein the lithium bis(fluorosulfonyl)imide (LiFSI) is present in an amount of 0.1 to 5% based on the total weight of the electrolyte.
7. A Lithium ion battery comprising: a positive electrode, a negative electrode, a separator between the positive electrode and the negative electrode, and an electrolyte, wherein the electrolyte is the Lithium ion battery electrolyte according to claim 1 .
8. The Lithium ion battery according to claim 7 , wherein the negative electrode comprises a silicon-carbon composite.
9. The Lithium ion battery electrolyte according to claim 1 , wherein the cyclic phosphazene is present in an amount of 1 to 5%, based on the total weight of the electrolyte.
10. The Lithium ion battery electrolyte according to claim 1 , wherein the cyclic sulfate is present in an amount of 1 to 3%, based on the total weight of the electrolyte.
11. The Lithium ion battery electrolyte according to claim 5 , wherein the lithium difluorophosphate (LiPO 2 F 2 ) is present in an amount of 0.1 to 5% based on the total weight of the electrolyte.