Steel sheet and method for production thereof
The present invention provides steel sheet excellent in cold formability and ductility after heat treatment and a method for production thereof. The steel sheet of the present invention is steel sheet which has a chemical composition containing, by mass %, C: 0.10 to 0.40%, Si: 0.30 to 1.00%, Mn: 0.30 to 1.00%, Al: 0.001 to 0.10%, P: 0.0001 to 0.02%, and S: 0.0001 to 0.01% and having a balance of Fe and impurities, which steel sheet characterized in that a ratio (B/A) of the number of carbides at the ferrite grain boundaries (B) to the number of carbides inside the ferrite grains (A) is over 1, a ferrite grain size is 5 μm to 50 μm, an average grain size of carbides is 0.4 μm to 2.0 μm, a pearlite area ratio is 6% or less, and a Vicker's hardness is 120 HV to 170 HV.
1. A steel sheet comprising, by mass %:
C: 0.10 to 0.40%,
Si: 0.30 to 1.00%,
Mn: 0.30 to 1,00%,
Al: 0.001 to 0.10%,
P: 0,02% or less, and
S: 0.01% or less and
having a balance of Fe and impurities,
wherein a ratio (B/A) of a number of carbides at ferrite grain boundaries (B) with respect to a number of carbides inside ferrite grains (A) is over 1,
wherein a ferrite grain size is 5 μm to 50 μm,
wherein an average grain size of carbides is 0.4 μm to 2.0 μm,
wherein a pearlite area ratio is 6% or less, and
wherein a Vicker's hardness is 120 HV to 170 HV.
2. The steel sheet according to claim 1 , wherein said steel sheet further comprises, by mass %, one or more of:
Ti: 0.10% or less,
Cr: 0.50% or less,
Mo: 0.50% or less,
B: 0.01% or less,
Nb: 0.10% or less,
V: 0.10% or less,
Cu: 0.10% or less,
W: 0.10% or less,
Ta: 0.10% or less,
N i: 0.10% or less,
Sn: 0.05% or less,
Sb: 0.05% or less,
As: 0.05% or less,
Mg: 0.05% or less,
Ca: 0.05% or less,
Y: 0.05% or less,
Zr: 0.05% or less,
La: 0.05% or less,
Ce: 0.05% or less,
N: 0.01% or less and
O: 0.02% or less.
3. A method for producing the steel sheet according to claim 1 , the method for producing the steel sheet comprising:
(i) hot rolling a steel slab of a chemical composition according to claim 1 ; finishing the hot rolling in a temperature range of 800° C. to 900° C.; and coiling the hot rolled steel sheet at 400° C. to 550° C.,
(ii) paying out the hot rolled steel sheet; pickling the hot rolled steel sheet; then holding the hot rolled steel sheet in a temperature range of 650° C. to 720° C. for 3 hours to 60 hours as first stage annealing and further holding the hot rolled steel sheet in a temperature range of 725° C. to 790° C. for 3 hours to 50 hours as second stage annealing, and
(iii) cooling the hot rolled steel sheet after annealing, at cooling rate of 1° C./hour to 30° C./hour down to 650° C.; and then cooling the hot rolled steel sheet down to room temperature.
4. The method for producing the steel sheet according to claim 3 , wherein that the temperature of the steel slab used for the hot rolling is 1000 to 1250° C.
5. A method for producing the steel sheet according to claim 4 , the method for producing the steel sheet comprising:
(i) hot rolling a steel slab of a chemical composition according to claim 4 ; finishing the hot rolling in a temperature range of 800° C. to 900° C.; and coiling the hot-rolled steel sheet at 400° C. to 550° C.,
(ii) paying out the hot-rolled steel sheet; pickling the hot-rolled steel sheet; then holding the hot-rolled steel sheet in a temperature range of 650° C. to 720° C. for 3 hours to 60 hours as first stage annealing and further holding the hot-rolled steel sheet in a temperature range of 725° C. to 790° C. for 3 hours to 50 hours as second stage annealing, and
(iii) cooling the hot-rolled steel sheet after annealing, at a cooling rate of 1° C./hour to 30° C./hour down to 650° C.; and then cooling the hot-rolled steel sheet down to room temperature.
6. The method for producing the steel sheet according to claim 4 , wherein the temperature of the steel slab used for the hot rolling is 1000 to 1250° C.