Amphiphilic polymers for filtrate control
The present invention relates to the use of amphiphilic sequenced copolymers as an agent for controlling the filtrate in a fluid (F) injected under pressure into an underground formation, comprising—at least one chain (C) soluble in the fluid (F); and—at least one block (B) that is insoluble in the fluid (F).
1. A process for controlling fluid loss in a fluid (F) injected under pressure into a subterranean formation, the process comprising forming fluid (F) with solid particles (p) in suspension and amphiphilic sequential copolymers (P) comprising:
at least one chain (C) soluble in the fluid (F) comprising hydrophilic and hydrophobic units, wherein the chain (C) is obtained by micellar polymerization; and
at least one block (B) insoluble in the fluid (F); and
injecting the fluid (F) under pressure into the subterranean formation, thereby controlling fluid loss in the fluid (F) where the fluid (F) which comprises the copolymers (P) as additive also comprises cement particles as the solid particles (p).
2. The process according to claim 1 , wherein chain (C) is obtained by a process comprising a stage (e) of micellar radical polymerization in which the following are brought into contact, within an aqueous medium (M):
hydrophilic monomers, dissolved or dispersed in said aqueous medium (M);
hydrophobic monomers in the form of a micellar solution, namely a solution containing, in the dispersed state within said aqueous medium (M), micelles comprising these hydrophobic monomers; and
at least one radical polymerization initiator.
3. The process according to claim 1 , wherein chain (C) is obtained by a process comprising a stage (E) of micellar radical polymerization in which the following are brought into contact, within an aqueous medium (M):
hydrophilic monomers, dissolved or dispersed in said aqueous medium (M);
hydrophobic monomers in the form of a micellar solution, namely a solution containing, in the dispersed state within said aqueous medium (M), micelles comprising these hydrophobic monomers;
at least one radical polymerization initiator; and
at least one radical polymerization control agent.
4. The process according to claim 3 , wherein the radical polymerization control agent is a compound which comprises a thiocarbonylthio—S(C═S)—group.
5. The process according to claim 1 , wherein the fluid (F) is an aqueous fluid.
6. The process according to claim 2 , wherein said aqueous medium (M) is water or a water/alcohol mixture.
7. The process according to claim 2 , wherein the dispersed state is obtained using at least one surfactant.
8. The process according to claim 2 , wherein the at least one radical polymerization initiator is water-soluble or water-dispersible.
9. The process according to claim 3 , wherein said aqueous medium (M) is water or a water/alcohol mixture.
10. The process according to claim 3 , wherein the dispersed state is obtained using at least one surfactant.
11. The process according to claim 3 , wherein the at least one radical polymerization initiator is water-soluble or water-dispersible.
12. The process according to claim 4 , wherein the radical polymerization control agent is a xanthate.