LED lighting units, materials, and optical components for white light illumination

1. An LED-based lighting unit comprising:

an LED-based light source that generates blue light;

an optical component through which the blue light passes, the optical component (i) enclosing the LED-based light source and (ii) comprising a phosphor blend;

wherein the phosphor blend comprises at least a yellow phosphor and a red phosphor, the yellow phosphor converting at least a portion of the blue light to yield an emission that includes yellow light as a result of the phosphor coating being excited by the blue light, the red phosphor emitting a red light;

wherein the yellow light, the red light, and an unconverted portion of the blue light produce in combination a visible light (i) comprising an approximately white light and (ii) being characterized by a color saturation index (CSI) value greater than zero; and

wherein the CSI value is configured based on a defined combination of relative amounts of the yellow phosphor and the red phosphor in the phosphor blend, the relative amounts including a yellow phosphor: red phosphor ratio of 1:2 to 2:1 by spectral weight.

2. The LED-based lighting unit according to claim 1 , wherein the phosphor blend is present as a coating on the optical component.

3. The LED-based lighting unit according to claim 1 , wherein the visible light is characterized by a spectral power distribution containing curves and peaks corresponding to each of the blue light, the yellow light, the red light, and the white light,

wherein an intensity for the peak of the white light is lower than an intensity for the peaks of the yellow and red lights.

4. The LED-based lighting unit according to claim 3 ,

wherein the peak of the white light is at a wavelength of greater than about 530 nm.

5. The LED-based lighting unit according to claim 3 ,

wherein the peak of the white light is within a wavelength range of from about 550 nm to about 610 nm.

6. The LED-based lighting unit according to claim 3 , wherein the curve for the spectral power distribution of the white light comprises an inflection point at a wavelength between the peaks of the blue light and the yellow light.

7. The LED-based lighting unit according to claim 1 , wherein at least a portion of the optical component comprises a composite material comprising a polymeric material and an inorganic particulate material, the inorganic particulate material comprising a Nd—O—F compound.

8. The LED-based lighting unit according to claim 7 , wherein the Nd—O—F compound formally comprises about 0.1 to about 99 molar percent NdF3, with the balance essentially Nd2O3.

9. The LED-based lighting unit according to claim 7 , wherein the Nd—O—F compound is NdOF.

10. The LED-based lighting unit according to claim 7 , wherein the Nd—O—F compound and the polymeric material have refractive indices within 0.1 of each other in the visible light region.

11. The LED-based lighting unit according to claim 7 , wherein the Nd—O—F compound and the polymeric material have refractive indices that differ by more than 0.1 of each other in the visible light region.

12. The LED-based lighting unit according to claim 1 , wherein the optical component is an enclosure or dome or encapsulant for the LED-based light source.

13. The LED-based lighting unit according to claim 1 , wherein the optical component is a diffuser of the lighting unit.

14. An LED-based lighting unit comprising:

an LED-based light source that generates blue light:

an optical component through which the blue light passes, the optical component (i) comprising a phosphor blend and (ii) being an enclosure or dome or encapsulant for the LED-based light source;

wherein the phosphor blend comprises at least a yellow phosphor and a red phosphor, the yellow phosphor converting at least a portion of the blue light to yield an emission that includes yellow light as a result of the phosphor coating being excited by the blue light, the red phosphor emitting a red light;

wherein at least a portion of the optical component comprises an inorganic particulate material comprises a Nd—O—F compound;

wherein the yellow light, the red light, and an unconverted portion of the blue light produce in combination a visible light (i) comprising an approximately white light and (ii) being characterized by a color saturation index (CSI) value greater than zero; and

wherein the CSI value is configured based on a defined combination of relative amounts of the yellow phosphor and the red phosphor in the phosphor blend, the relative amounts including a yellow phosphor: red phosphor ratio of 1:2 to 2:1 by spectral weight.

15. An LED-based lighting unit comprising:

an LED-based light source that generates blue light:

an optical component through which the blue light passes, the optical component (i) enclosing the LED-based light source (ii) comprising a phosphor blend and (iii) being a diffuser of the lighting unit;

wherein the phosphor blend comprises at least a yellow phosphor and a red phosphor, the yellow phosphor converting at least a portion of the blue light to yield an emission that includes yellow light as a result of the phosphor coating being excited by the blue light, the red phosphor emitting a red light;

wherein at least a portion of the optical component comprises an inorganic particulate material comprises a Nd—O—F compound;

wherein the yellow light, the red light, and an unconverted portion of the blue light produce in combination a visible light (i) comprising an approximately white light and (ii) being characterized by a color saturation index (CSI) value greater than zero; and

wherein the CSI value is configured based on a defined combination of relative amounts of the yellow phosphor and the red phosphor in the phosphor blend, the relative amounts including a yellow phosphor: red phosphor ratio of 1:2 to 2:1 by spectral weight.