Syntactic foam
A fire resistant syntactic foam material, the material comprising the reaction product of a reaction mixture including a resole cold curing phenolic resin and incorporating a plurality of hollow spheres, the reaction mixture also including a solution of a partial phosphate ester, a low viscosity phosphate plasticiser, a reinforcing filler and a particulate filler.
1. A fire resistant syntactic foam material, the material comprising the reaction product of a reaction mixture including a resole cold curing phenolic resin and incorporating a plurality of hollow spheres, the reaction mixture also including a solution of a partial phosphate ester, a phosphate plasticiser, a reinforcing filler and a particulate filler, wherein the particulate filler is any of cork, graphite or vermiculite, and wherein the reaction mixture includes 2-8.24% by weight of the particulate filler.
2. A fire resistant foam material according to claim 1 , wherein the phosphate plasticiser is present in an amount up to 8.5% by weight of the phenolic resin.
3. A fire resistant foam material according to claim 1 , wherein the proportion by weight of the partial phosphate ester to the phenolic resin in the reaction mixture is in the range of 5% to 15%.
4. A fire resistant foam material according to claim 1 , wherein the reaction mixture includes sulphonic acid.
5. A fire resistant foam material according to claim 4 , wherein the amount of sulphonic acid in the reaction mixture is up to 6% of the weight of the partial phosphate ester.
6. A fire resistant foam material according to claim 1 , wherein the reaction mixture includes trifluoromethanesulfonic acid in an amount up to 6% of the weight of the partial phosphate ester.
7. A fire resistant foam material according to claim 1 , wherein the concentration of the hollow spheres is such that the effective specific gravity of the material is between 0.2 and 0.6.
8. A fire resistant foam material according to claim 1 , wherein the hollow spheres are formed from a material selected from glass, thermoplastic copolymers of polyacrylonitrile, a refractory material, or a ceramic material.
9. A fire resistant foam material according to claim 1 , wherein the reinforcing filler is selected from basalt fibres, ceramic fibres, glass fibres and glass flake.
10. A fire resistant foam material according to claim 1 , wherein the reaction mixture includes a surfactant.
11. A fire resistant foam material according to claim 10 , wherein the surfactant is a fluorinated surfactant.
12. A fire resistant foam material according to claim 10 , wherein the surfactant is acid resistant.
13. A fire resistant foam material according to claim 1 , wherein the reaction mixture includes an accelerator.
14. A fire resistant foam material according to claim 13 , wherein the accelerator is para-toluene sulfonic acid.
15. A fire resistant component or structure, the surface thereof being coated with a fire resistant syntactic foam material according to claim 1 .